Evolution Of Galaxies .4. Highly Flattened Disks

NSF GP-18335, GP-32051Astronom

Evolution Of Galaxies .2. Chemical Evolution Coefficients

NSF GP-18355, GP-32051Astronom

Research opportunities on immunocompetence in space

The most significant of the available data on the effects of space flight on immunocompetences and the potential operational and clinical significance of reported changes are as follows: (1) reduced postflight blastogenic response of peripheral lymphocytes from space crew members; (2) postflight neutrophilia persisting up to 7 days; (3) gingival inflammation of the Skylab astronauts; (4) postflight lymphocytopenia, eosinopenia, and monocytopenia; (5) modifications and shifts in the microflora of space crews and spacecraft; and (6) microbial contamination of cabin air and drinking water. These responses and data disclose numerous gaps in the knowledge that is essential for an adequate understanding of space-related changes in immunocompetence

Air-snow exchange of HNO3 and NOy at Summit, Greenland

Ice core records of NO3− deposition to polar glaciers could provide unrivaled information on past photochemical status and N cycling dynamics of the troposphere, if the ice core records could be inverted to yield concentrations of reactive N oxides in the atmosphere at past times. Limited previous investigations at Summit, Greenland, have suggested that this inversion may be difficult, since the levels of HNO3 and aerosol-associated NO3− over the snow are very low in comparison with those of NO3− in the snow. In addition, it appears that some fraction of the NO3− in snow may be reemitted to the atmosphere after deposition. Here we report on extensive measurements of HNO3, including vertical gradients between 1.5 and 7 m above the snow, made during the summers of 1994 and 1995 at Summit. These HNO3 data are compared with NO3− concentrations in surface snow and the first measurements of the concentrations and fluxes of total reactive nitrogen oxides (Ny) on a polar glacier. Our results confirm that HNO3 concentrations are quite low (mean 0.5 nmol m−3) during the summer, while NO3− is the dominant ion in snow. Daytime peaks in HNO3− appear to be due at least partly to emissions from the snow, an assertion supported by gradients indicating a surface source for HNO3− on many days. Observed short-term increases in NO3− inventory in the snow can be too large to be readily attributed to deposition of HNO3− suggesting that deposition of one or more other N oxides must be considered. We found that the apparent fluxes of HNO3 and NOy were in opposite directions during about half the intervals when both were measured, with more cases of HNO3 leaving the snow, against an NOy flux into the snow, than the reverse. The concentrations of NOy are generally about 2 orders of magnitude greater than those of HNO3; hence deposition of only a small, non-HNO3, fraction of this pool could dominate NO3− in snow, if the depositing species converted to NO3−, either in the snowpack or upon melting for analysis

Deviations from ozone photostationary state during the International Consortium for Atmospheric Research on Transport and Transformation 2004 campaign: Use of measurements and photochemical modeling to assess potential causes

Nitric oxide (NO) and nitrogen dioxide (NO2) were monitored at the University of New Hampshire Atmospheric Observing Station at Thompson Farm (TF) during the ICARTT campaign of summer 2004. Simultaneous measurement of ozone (O3), temperature, and the photolysis rate of NO2 (jNO2) allow for assessment of the O3 photostationary state (Leighton ratio, Φ). Leighton ratios that are significantly greater than unity indicate that peroxy radicals (PO2), halogen monoxides, nitrate radicals, or some unidentified species convert NO to NO2 in excess of the reaction between NO and O3. Deviations from photostationary state occurred regularly at TF (1.0 ≤ Φ ≤ 5.9), particularly during times of low NOx (NOx = NO + NO2). Such deviations were not controlled by dynamics, as indicated by regressions between Φ and several meteorological parameters. Correlation with jNO2 was moderate, indicating that sunlight probably controls nonlinear processes that affect Φ values. Formation of PO2 likely is dominated by oxidation of biogenic hydrocarbons, particularly isoprene, the emission of which is driven by photosynthetically active radiation. Halogen atoms are believed to form via photolysis of halogenated methane compounds. Nitrate radicals are believed to be insignificant. Higher Φ values are associated with lower mixing ratios of isoprene and chloroiodomethane and lower ratios of NOx to total active nitrogen, indicating that photochemical aging may very well lead to increased Φ values. PO2 levels calculated using a zero‐dimensional model constrained by measurements from TF can account for 71% of the observed deviations on average. The remainder is assumed to be associated with halogen atoms, most likely iodine, with necessary mixing ratios up to 0.6 or 1.2 pptv, for chlorine and iodine, respectively

Large-scale distributions of tropospheric nitric, formic, and acetic acids over the western Pacific basin during wintertime

We report here measurements of the acidic gases nitric (HNO3), formic (HCOOH), and acetic (CH3COOH) over the western Pacific basin during the February-March 1994 Pacific Exploratory Mission-West (PEM-West B). These data were obtained aboard the NASA DC-8 research aircraft as it flew missions in the altitude range of 0.3–12.5 km over equatorial regions near Guam and then further westward encompassing the entire Pacific Rim arc. Aged marine air over the equatorial Pacific generally exhibited mixing ratios of acidic gases \u3c100 parts per trillion by volume (pptv). Near the Asian continent, discrete plumes encountered below 6 km altitude contained up to 8 parts per billion by volume (ppbv) HNO3 and 10 ppbv HCOOH and CH3COOH. Overall there was a general correlation between mixing ratios of acidic gases with those of CO, C2H2, and C2Cl4, indicative of emissions from combustion and industrial sources. The latitudinal distributions of HNO3 and CO showed that the largest mixing ratios were centered around 15°N, while HCOOH, CH3COOH, and C2Cl4 peaked at 25°N. The mixing ratios of HCOOH and CH3COOH were highly correlated (r2 = 0.87) below 6 km altitude, with a slope (0.89) characteristic of the nongrowing season at midlatitudes in the northern hemisphere. Above 6 km altitude, HCOOH and CH3COOH were marginally correlated (r2 = 0.50), and plumes well defined by CO, C2H2, and C2Cl4 were depleted in acidic gases, most likely due to scavenging during vertical transport of air masses through convective cloud systems over the Asian continent. In stratospheric air masses, HNO3 mixing ratios were several parts per billion by volume (ppbv), yielding relationships with O3 and N2O consistent with those previously reported for NOy

A major regional air pollution event in the northeastern United States caused by extensive forest fires in Quebec, Canada

During early July 2002, wildfires burned ∼1 × 106 ha of forest in Quebec, Canada. The resultant smoke plume was seen in satellite images blanketing the U.S. east coast. Concurrently, extremely high CO mixing ratios were observed at the Atmospheric Investigation, Regional Modeling, Analysis and Prediction (AIRMAP) network sites in New Hampshire and at the Harvard Forest Environmental Measurement Site (HFEMS) in Massachusetts. The CO enhancements were on the order of 525–1025 ppbv above low mixing ratio conditions on surrounding days. A biomass burning source for the event was confirmed by concomitant enhancements in aerosol K+, NH4+, NO3−, and C2O42− mixing ratios at the AIRMAP sites. Additional data for aerosol K, organic carbon, and elemental carbon from the Interagency Monitoring of Protected Visual Environments network and CO data from Environmental Protection Agency sites indicated that the smoke plume impacted much of the U.S. east coast, from Maine to Virginia. CO mixing ratios and K concentrations at stations with 10-year or longer records suggested that this was the largest biomass burning plume to impact the U.S. east coast in over a decade. Furthermore, CO mixing ratios and aerosol particles with diameters 2.5) mass and scattering coefficients from the AIRMAP network and HFEMS indicated that this event was comparable to the large anthropogenic combustion and haze events which intermittently impact rural New England. The degree of enhancement of O3, NOy, NO3−, NH4+, and SO42− in the biomass plume showed significant variation with elevation and latitude that is attributed to variations in transport and surface depositional processes

Application of the Gillespie algorithm to a granular intruder particle

We show how the Gillespie algorithm, originally developed to describe coupled chemical reactions, can be used to perform numerical simulations of a granular intruder particle colliding with thermalized bath particles. The algorithm generates a sequence of collision ``events'' separated by variable time intervals. As input, it requires the position-dependent flux of bath particles at each point on the surface of the intruder particle. We validate the method by applying it to a one-dimensional system for which the exact solution of the homogeneous Boltzmann equation is known and investigate the case where the bath particle velocity distribution has algebraic tails. We also present an application to a granular needle in bath of point particles where we demonstrate the presence of correlations between the translational and rotational degrees of freedom of the intruder particle. The relationship between the Gillespie algorithm and the commonly used Direct Simulation Monte Carlo (DSMC) method is also discussed.Comment: 13 pages, 8 figures, to be published in J. Phys. A Math. Ge