746 research outputs found
Spin dynamics and magnetic interactions of Mn dopants in the topological insulator BiTe
The magnetic and electronic properties of the magnetically doped topological
insulator BiMnTe were studied using electron spin
resonance (ESR) and measurements of static magnetization and electrical
transport. The investigated high quality single crystals of BiMnTe show a ferromagnetic phase transition for
at K. The Hall measurements reveal a p-type finite
charge-carrier density. Measurements of the temperature dependence of the ESR
signal of Mn dopants for different orientations of the external magnetic field
give evidence that the localized Mn moments interact with the mobile charge
carriers leading to a Ruderman-Kittel-Kasuya-Yosida-type ferromagnetic coupling
between the Mn spins of order 2-3 meV. Furthermore, ESR reveals a
low-dimensional character of magnetic correlations that persist far above the
ferromagnetic ordering temperature
Carbon supported CdSe nanocrystals
Insights to the mechanism of CdSe nanoparticle attachment to carbon nanotubes
following the hot injection method are discussed. It was observed that the
presence of water improves the nanotube coverage while Cl containing media are
responsible for the shape transformation of the nanoparticles and further
attachment to the carbon lattice. The experiments also show that the mechanism
taking place involves the right balance of several factors, namely, low
passivated nanoparticle surface, particles with well-defined crystallographic
facets, and interaction with an organics-free sp2 carbon lattice. Furthermore,
this procedure can be extended to cover graphene by quantum dots.Comment: 5 pages, 5 figure
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Red quantum dots under the electron microscope
Cathodoluminescent imaging of the visible light emitted from quantum dots is reported. The shape and uniformity of individual particles is observed in the STEM electron image and the image of the particles created from their visible light collected simultaneously is shown. Visible light images of the 12-13nm sized particles are reported for clusters of just 2 particles. Emission spectra collected from small clusters of around 50 nano-particles are also reported.Technology Strategy Board (TSB) (UK) for substantial financial funding in the form of TSB Technology
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Evidence for the existence of powder sub-populations in micronized materials : Aerodynamic size-fractions of aerosolized powders possess distinct physicochemical properties
This article is distributed under the terms of the Creative Commons Attribution License which permits any use, distribution, and reproduction in any medium, provided the original author(s) and the source are credited.Purpose: To investigate the agglomeration behaviour of the fine ( 12.8 µm) particle fractions of salmeterol xinafoate (SX) and fluticasone propionate (FP) by isolating aerodynamic size fractions and characterising their physicochemical and re-dispersal properties. Methods: Aerodynamic fractionation was conducted using the Next Generation Impactor (NGI). Re-crystallized control particles, unfractionated and fractionated materials were characterized for particle size, morphology, crystallinity and surface energy. Re-dispersal of the particles was assessed using dry dispersion laser diffraction and NGI analysis. Results: Aerosolized SX and FP particles deposited in the NGI as agglomerates of consistent particle/agglomerate morphology. SX particles depositing on Stages 3 and 5 had higher total surface energy than unfractionated SX, with Stage 5 particles showing the greatest surface energy heterogeneity. FP fractions had comparable surface energy distributions and bulk crystallinity but differences in surface chemistry. SX fractions demonstrated higher bulk disorder than unfractionated and re-crystallized particles. Upon aerosolization, the fractions differed in their intrinsic emission and dispersion into a fine particle fraction (< 5.0 µm). Conclusions: Micronized powders consisted of sub-populations of particles displaying distinct physicochemical and powder dispersal properties compared to the unfractionated bulk material. This may have implications for the efficiency of inhaled drug deliveryPeer reviewe
On the Dynamics of the Evolution of the HIV Infection
We use a cellular automata model to study the evolution of HIV infection and
the onset of AIDS. The model takes into account the global features of the
immune response to any pathogen, the fast mutation rate of the HIV and a fair
amount of spatial localization. Our results reproduce quite well the
three-phase pattern observed in T cell and virus counts of infected patients,
namely, the primary response, the clinical latency period and the onset of
AIDS. We have also found that the infected cells may organize themselves into
special spatial structures since the primary infection, leading to a decrease
on the concentration of uninfected cells. Our results suggest that these cell
aggregations, which can be associated to syncytia, leads to AIDS.Comment: 4 pages, 3 postscript figure
Stature and sibship: historical evidence
This paper examines historical evidence for a quality–quantity trade-off between sibship size and height as an indicator of health. The existing literature has focused more on education than on health and it has produced mixed results. Historical evidence is limited by the lack of household-level data with which to link an individual’s height with his or her childhood circumstances. Nevertheless a few recent studies have shed light on this issue. Evidence for children in interwar Britain and for soldiers born in the 1890s who enlisted in the British army at the time of World War I is reviewed in detail. Both studies support the idea of a significant trade-off, partly due to income dilution and partly because, in these settings, large families were a conduit for infection. Evidence from country-level time series is consistent with this view. The fertility decline that began in the late nineteenth century made a modest but nevertheless significant contribution to the overall increase in heights during the following half-century
The geographic mosaic of herbicide resistance evolution in the common morning glory, Ipomoea purpurea: Evidence for resistance hotspots and low genetic differentiation across the landscape
Strong human‐mediated selection via herbicide application in agroecosystems has repeatedly led to the evolution of resistance in weedy plants. Although resistance can occur among separate populations of a species across the landscape, the spatial scale of resistance in many weeds is often left unexamined. We assessed the potential that resistance to the herbicide glyphosate in the agricultural weed Ipomoea purpurea has evolved independently multiple times across its North American range. We examined both adaptive and neutral genetic variations in 44 populations of I. purpurea by pairing a replicated dose–response greenhouse experiment with SSR genotyping of experimental individuals. We uncovered a mosaic pattern of resistance across the landscape, with some populations exhibiting high‐survival postherbicide and other populations showing high death. SSR genotyping revealed little evidence of isolation by distance and very little neutral genetic structure associated with geography. An approximate Bayesian computation (ABC) analysis uncovered evidence for migration and admixture among populations before the widespread use of glyphosate rather than the very recent contemporary gene flow. The pattern of adaptive and neutral genetic variations indicates that resistance in this mixed‐mating weed species appears to have evolved in independent hotspots rather than through transmission of resistance alleles across the landscape.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/113156/1/eva12290_am.pdfhttp://deepblue.lib.umich.edu/bitstream/2027.42/113156/2/eva12290.pd
Enabling low-carbon development in poor countries
The challenges associated with achieving sustainable development goals and stabilizing the world’s climate cannot be solved without significant efforts by developing and newly-emerging countries. With respect to climate change mitigation, the main challenge for developing countries lies in avoiding future emissions and lock-ins into emission-intensive technologies, rather than reducing today’s emissions. While first best policy instruments like carbon prices could prevent increasing carbonization, those policies are often rejected by developing countries out of a concern for negative repercussions on development and long-term growth. In addition, policy environments in developing countries impose particular challenges for regulatory policy aiming to incentivize climate change mitigation and sustainable development. This chapter first discusses how climate policy could potentially interact with sustainable development and economic growth. It focuses, in particular, on the role of industrial sector development. The chapter then continues by discussing how effective policy could be designed, specifically taking developing country circumstances into account
St. Louis Area Earthquake Hazards Mapping Project: Seismic and Liquefaction Hazard Maps
We present probabilistic and deterministic seismic and liquefaction hazard maps for the densely populated St. Louis metropolitan area that account for the expected effects of surficial geology on earthquake ground shaking. Hazard calculations were based on a map grid of 0.005°, or about every 500 m, and are thus higher in resolution than any earlier studies. To estimate ground motions at the surface of the model (e.g., site amplification), we used a new detailed near-surface shear-wave velocity model in a 1D equivalent- linear response analysis. When compared with the 2014 U.S. Geological Survey (USGS) National Seismic Hazard Model, which uses a uniform firm-rock-site condition, the new probabilistic seismic-hazard estimates document much more variability. Hazard levels for upland sites (consisting of bedrock and weathered bedrock overlain by loess-covered till and drift deposits), show up to twice the ground-motion values for peak ground acceleration (PGA), and similar ground-motion values for 1.0 s spectral acceleration (SA). Probabilistic ground-motion levels for lowland alluvial floodplain sites (generally the 20-40-m-thick modern Mississippi and Missouri River floodplain deposits overlying bedrock) exhibit up to twice the ground-motion levels for PGA, and up to three times the ground-motion levels for 1.0 s SA. Liquefaction probability curves were developed from available standard penetration test data assuming typical lowland and upland water table levels. A simplified liquefaction hazard map was created from the 5%-in-50-year probabilistic ground-shaking model. The liquefaction hazard ranges from low (\u3c40% of area expected to liquefy) in the uplands to severe (\u3e60% of area expected to liquefy) in the lowlands. Because many transportation routes, power and gas transmission lines, and population centers exist in or on the highly susceptible lowland alluvium, these areas in the St. Louis region are at significant potential risk from seismically induced liquefaction and associated ground deformation
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