Liquid Engine Test Facilities Assessment

The John C. Stennis Space Center (SSC) requested The Aerospace Corporation to examine the current testing capability of all existing large liquid engine test facilities located in the United States. That information along with projected liquid rocket engine development was used to examine future liquid rocket engine testing facilities needs in the coming decade. Current domestic liquid engine test facilities capabilities, when examined against engine concepts for the coming decade, indicate there are ample facilities offering altitude simulation during test. In addition, it was observed that many contractor facilities have limited ambient test capability of larger thrust engines under current consideration. Finally, it was concluded that diminished contractor participation engine development testing will drive this activity to the government sector. Only three facilities are seen as key contributors to engine testing in the coming decade, namely John C. Stennis Space Center (SSC), Marshall Space Flight Center (MSFC), and Air Force Research Laboratory (AFRL). Past rocket engine test experience was evaluated as a possible resource for projecting future engine test needs. A database comprised of various engine models and the level of testing performed to flight qualify those systems for their first flight was constructed. For comparison purposes in this study, development and qualification efforts were totaled and treated as one test program. Based on experience with past Air Force programs, the time on the test stand accounts for typically 50% or more of the total program time. Historical data show that the time to design and develop new engines has increased over the last 40 years, most likely due to scarcer resources in today's funding environment

Isomer-Specific Product Detection of Gas-Phase Xylyl Radical Rearrangement and Decomposition Using VUV Synchrotron Photoionization

Xylyl radicals are intermediates in combustion processes since their parent molecules, xylenes, are present as fuel additives. In this study we report on the photoelectron spectra of the three isomeric xylyl radicals and the subsequent decomposition reactions of the o-xylyl radical, generated in a tubular reactor and probed by mass selected threshold photoelectron spectroscopy and VUV synchrotron radiation. Franck-Condon simulations are applied to augment the assignment of elusive species. Below 1000 K, o-xylyl radicals decompose by hydrogen atom loss to form closed-shell o-xylylene, which equilibrates with benzocyclobutene. At higher temperatures relevant to combustion engines, o-xylylene generates styrene in a multistep rearrangement, whereas the p-xylylene isomer is thermally stable, a key point of difference in the combustion of these two isomeric fuels. Another striking result is that all three xylyl isomers can generate p-xylylene upon decomposition. In addition to C8H8 isomers, phenylacetylene and traces of benzocyclobutadiene are observed and identified as further reaction products of o-xylylene, while there is also some preliminary evidence for benzene and benzyne formation. The experimental results reported here are complemented by a comprehensive theoretical C8H8 potential energy surface, which together with the spectroscopic assignments can explain the complex high-temperature chemistry of o-xylyl radicals