623 research outputs found
Evidence for phase formation in potassium intercalated 1,2;8,9-dibenzopentacene
We have prepared potassium intercalated 1,2;8,9-dibenzopentacene films under
vacuum conditions. The evolution of the electronic excitation spectra upon
potassium addition as measured using electron energy-loss spectroscopy clearly
indicate the formation of particular doped phases with compositions
Kdibenzopentacene ( = 1,2,3). Moreover, the stability of these phases as
a function of temperature has been explored. Finally, the electronic excitation
spectra also give insight into the electronic ground state of the potassium
doped 1,2;8,9-dibenzopentacene films.Comment: 6 pages, 5 figures. arXiv admin note: text overlap with
arXiv:1201.200
Signatures of electronic polarons in LaSrMnO observed by electron energy-loss spectroscopy
The dielectric properties of LaSrMnO single crystals with
x = 0, 0.125, 0.25, and 0.5 were studied by means of electron energy-loss
spectroscopy as a function of temperature and momentum transfer. A clear
signature of the doped holes is observed around 1.65 eV energy loss, where
spectral weight emerges with increasing x. For all , this
doping-induced excitation can propagate within the ab-plane, as revealed by a
clear upward dispersion of the corresponding loss peak with increasing momentum
transfer. The hole-induced excitation also shifts to higher energies with the
onset of magnetic correlations for x = 0.5, implying a strong coupling of
charge and spin dynamics. We conclude that (i) the loss feature at 1.65 eV is a
signature of electronic polarons, which are created around doped holes, and
that (ii) this low-energy excitation involves the charge transfer between
manganese and oxygen. The finite dispersion of these excitations further
indicates significant polaron-polaron interactions.Comment: 7 pages, 4 figure
Plasmons and Interband Transitions of CaSrCuO investigated by Electron Energy-Loss Spectroscopy
Electron energy-loss spectroscopy studies have been performed in order to get
a deeper insight into the electronic structure and elementary excitations of
the two-leg ladder system CaSrCuO. We find a strong
anisotropy of the loss function for momentum transfers along the a and
c-crystallographic axis, and a remarkable linear plasmon dispersion for a
momentum transfer parallel to the legs of the ladders. The investigated
spectral features are attributed to localized and delocalized charge-transfer
excitations and the charge carrier plasmon. The charge carrier plasmon position
and dispersion in the long wave-length limit agree well with expectations based
upon the band structure of the two-leg ladder, while the observed quasi-linear
plasmon dispersion might be related to the peculiar properties of underdoped
cuprates in general.Comment: 16 pages, 8 figure
Fine-tuning the functional properties of carbon nanotubes via the interconversion of encapsulated molecules
Tweaking the properties of carbon nanotubes is a prerequisite for their
practical applications. Here we demonstrate fine-tuning the electronic
properties of single-wall carbon nanotubes via filling with ferrocene
molecules. The evolution of the bonding and charge transfer within the tube is
demonstrated via chemical reaction of the ferrocene filler ending up as
secondary inner tube. The charge transfer nature is interpreted well within
density functional theory. This work gives the first direct observation of a
fine-tuned continuous amphoteric doping of single-wall carbon nanotubes
Transition from a Tomonaga-Luttinger liquid to a Fermi liquid in potassium intercalated bundles of single wall carbon nanotubes
We report on the first direct observation of a transition from a
Tomonaga-Luttinger liquid to a Fermi liquid behavior in potassium intercalated
mats of single wall carbon nanotubes (SWCNT). Using high resolution
photoemission spectroscopy an analysis of the spectral shape near the Fermi
level reveals a Tomonaga-Luttinger liquid power law scaling in the density of
states for the pristine sample and for low dopant concentration. As soon as the
doping is high enough to fill bands of the semiconducting tubes a distinct
transition to a bundle of only metallic SWCNT with a scaling behavior of a
normal Fermi liquid occurs. This can be explained by a strong screening of the
Coulomb interaction between charge carriers and/or an increased hopping matrix
element between the tubes.Comment: 5 pages, 4 figure
Manifestation of spin-charge separation in the dynamic dielectric response of one--dimensional Sr2CuO3
We have determined the dynamical dielectric response of a one-dimensional,
correlated insulator by carrying out electron energy-loss spectroscopy on
Sr2CuO3 single crystals. The observed momentum and energy dependence of the
low-energy features, which correspond to collective transitions across the gap,
are well described by an extended one-band Hubbard model with moderate nearest
neighbor Coulomb interaction strength. An exciton-like peak appears with
increasing momentum transfer. These observations provide experimental evidence
for spin-charge separation in the relevant excitations of this compound, as
theoretically expected for the one-dimensional Hubbard model.Comment: RevTex, 4 pages+2 figures, to appear in PRL (July 13
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