Satellite Remote Sensing of Atmospheric SO_2: Volcanic Eruptions and Anthropogenic Emissions

In this article, we present satellite data analysis of atmospheric Sulfur Dioxide (SO_2) from volcanic eruptions and anthropogenic activities. Data from Global Ozone Monitoring Experiment (GOME) on board ERS-2 for the years 1996 to 2002 is analyzed using a DOAS based algorithm with the aim of retrieving SO_2 Slant Column Densities (SCDs). Difficulties in the retrieval of SO_2 SCDs due to instrumental effects are investigated in detail and significantly improved. The retrieved SCDs can be used to identify and monitor several volcanic eruptions. A brief introduction of different volcanic eruptions around the globe is presented Also informations about the anthropogenic SO_2 emissions can be easily achieved from the retrieved data set. A time series of anthropogenic SO_2 emissions over Eastern Europe is presented in this study. The time series showed high SO_2 SCDs over Eastern Europe during the winter months. The results demonstrate a high sensitivity of GOME instrument towards SO_2 emissions

Monitoring and Modeling of the Reaction Dynamics in the Valine/Leucine Synthesis Pathway in Corynebacterium glutamicum

The intracellular concentrations of the valine and leucine pathway intermediates in a Corynebacterium glutamicum strain were measured during a transient state. The data were obtained by performing a glucose stimulus-response experiment with the use of a rapid sampling device and advanced mass spectrometry. The glucose stimulus resulted in a 3-fold increase in the intracellular pyruvate concentration within less than a second, demonstrating the very fast interactions in metabolic networks. The samples were taken at subsecond intervals for a time period of 25 s. The time courses of the metabolite concentrations formed the experimental basis of a mathematical model simulating the fluxes and concentrations in the valine/leucine pathway. The implementation of a model selection criterion based on the second law of thermodynamics is demonstrated to be essential for the identification of realistic and unique models. Large differences between the enzyme properties determined in vitro and those determined in vivo by the model were observed with the in vivo maximal rates being almost an order of magnitude larger than the in vitro maximal rates. The transamination of ketoisovalerate (KIV) to valine is carried out mainly by the transaminase B enzyme, with the transaminase C enzyme playing a minor role. The availability of the cofactors NADP and NADPH only has modest influence on the flux through the valine pathway, while the influence of NAD and NADH on the flux through the leucine pathway is negligible

Bioindicators of climate and trophic state in lowland and highland aquatic ecosystems of the Northern Neotropics

Chironomids, diatoms and microcrustaceans that inhabit aquatic ecosystems of the Northern Neotropics are abundant and diverse. Some species are highly sensitive to changes in water chemical composition and trophic state. This study was undertaken as a first step in developing transfer functions to infer past environmental conditions in the Northern lowland Neotropics. Bioindicator species abundances were related to multiple environmental variables to exploit their use as environmental and paleoenvironmental indicators. We collected and analyzed water and surface sediment samples from 63 waterbodies located along a broad trophic state gradient and steep gradients of altitude (similar to 0-1 560m.a.s.l.) and precipitation (similar to 400-3 200mm/y), from NW Yucatan Peninsula (Mexico) to southern Guatemala. We related 14 limnological variables to relative abundances of 282 diatom species, 66 chironomid morphospecies, 51 species of cladocerans, 29 non-marine ostracode species and six freshwater calanoid copepods. Multivariate statistics indicated that bicarbonate is the strongest driver of chironomid and copepod distribution. Trophic state is the second most important factor that determines chironomid distribution. Conductivity, which is related to the precipitation gradient and marine influence on the Yucatan Peninsula, is the main variable that shapes diatom, ostracode and cladoceran communities. Diatoms, chironomids and cladocerans displayed higher diversities (H=2.4-2.6) than ostracodes and copepods (H=0.7-1.8). Species richness and diversity were greater at lower elevations (<450m.a.s.l.) than at higher elevations in Guatemala. Distribution and diversity of bioindicators are influenced by multiple factors including altitude, precipitation, water chemistry, trophic state and human impact

Stratospheric chlorine activation in the Arctic winters 1995/96–2001/02 derived from GOME OClO measurements

In this article, we present satellite observations of OClO from the years 1995–2002. The focus is on observations of OClO in the Arctic wintertime stratosphere, which are compared to results of the SLIMCAT model and to observations in the Antarctic. In particular, we investigated the beginning and ending of the chlorine activation in the Arctic stratosphere. The Slant Column Densities (SCDs) of OClO increase significantly, when the temperature falls below the threshold for formation of Polar Stratospheric Clouds. The time for decrease of the OClO-SCDs in the deactivation phase (early spring) varies strongly and is related to the degree of denitrification. In the Arctic, chlorine activation can be further increased when there is strong activity of stratospheric mountain waves