Measurement and transformation of continuously modulated fields using a short-time measurement approach

Near-field measurements, which are performed in-situ, may suffer from the fact that the antenna under test (AUT) cannot be accessed to transmit or receive a specifically tailored test signal. In some scenarios, it might also be desired to test the AUT during its real operation state, especially when it comes to the verification of antenna systems. Therefore, the need to handle time- and space-modulated fields in combination with a time-harmonic near-field to far-field transformation (NFFFT) arises. For the case where unmanned aerial vehicles (UAVs) carry the field probe in in-situ measurement scenarios, long observation times, required for the resolution of the frequency spectra of modulated fields, are detrimental due to the UAV movement resulting in blurred measurement positions. The short-time measurement (STM) approach, presented in this article, offers a way to transform the measured field data using a time-harmonic NFFFT with short observation times for the collection of the individual field samples. Measurements are shown which demonstrate the applicability of the STM approach for the measurement and transformation of continuously time-modulated fields in different measurement scenarios.</p

Towards improved accuracy in chlorine isotope analysis: Synthesis routes for in-house standards and characterization via complementary mass spectrometry methods.

Increasing applications of compound-specific chlorine isotope analysis (CSIA) emphasize the need for chlorine isotope standards that bracket a wider range of isotope values in order to ensure accurate results. With one exception (USGS38), however, all international chlorine isotope reference materials (chloride and perchlorate salts) fall within the narrow range of one per mille. Furthermore, compound-specific working standards are required for chlorine CSIA but are not available for most organic substances. We took advantage of isotope effects in chemical dehalogenation reactions to generate (i) silver chloride (CT16) depleted in 37Cl/35Cl and (ii) compound-specific standards of the herbicides acetochlor and S-metolachlor (Aceto2, Metola2) enriched in 37Cl/35Cl. Calibration against the international reference standards USGS38 (-87.90 ‰) and ISL-354 (+0.05 ‰) by complementary methods (gas chromatography-isotope ratio mass spectrometry, GC-IRMS, versus gas chromatography-multicollector inductively coupled plasma mass spectrometry, GC-MC-ICPMS) gave a consensus value of δ37ClCT16 = -26.82 ± 0.18 ‰. Preliminary GC-MC-ICPMS characterization of commercial Aceto1 and Metola1 versus Aceto2 and Metola2 resulted in tentative values of δ37ClAceto1 = 0.29 ± 0.29 ‰, δ37ClAceto2 = 18.54 ± 0.20 ‰, δ37ClMetola1 = -4.28 ± 0.17 ‰ and δ37ClMetola2 = 5.12 ± 0.27 ‰. The possibility to generate chlorine isotope in-house standards with pronounced shifts in isotope values offers a much-needed basis for accurate chlorine CSIA