539 research outputs found

    The Impact of Molecular Polarization on the Electronic Properties of Molecular Semiconductors

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    In a molecular semiconductor, the carrier is dressed with a polarization cloud that we treat as a quantum field of Frenkel excitons coupled to it. The consequences of the existence of this electronic polaron on the dynamics of an extra charge in a material like pentacene can thus be evaluated.Comment: 7 pages, 1 figure, LaTe

    Phase diagram of the fully frustrated transverse-field Ising model on the honeycomb lattice

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    Motivated by the current interest in the quantum dimer model on the triangular lattice, we investigate the phase diagram of the closely related fully-frustrated transverse field Ising model on the honeycomb lattice using classical and semi-classical approximations. We show that, in addition to the fully polarized phase at large field, the classical model possesses a multitude of phases that break the translational symmetry which in the dimer language, correspond to a plaquette phase and a columnar phase separated by an infinite cascade of mixed phases. The modification of the phase diagram by quantum fluctuations has been investigated in the context of linear spin-wave theory. The extrapolation of the semiclassical energies suggests that the plaquette phase extends down to zero field for spin 1/2, in agreement with the 12Ă—12\sqrt{12}\times\sqrt{12} phase of the quantum dimer model on the triangular lattice with only kinetic energy.Comment: 15 Pages, 11 Figures, Accepted for PR

    Polarization effects in the channel of an organic field-effect transistor

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    We present the results of our calculation of the effects of dynamical coupling of a charge-carrier to the electronic polarization and the field-induced lattice displacements at the gate-interface of an organic field-effect transistor (OFET). We find that these interactions reduce the effective bandwidth of the charge-carrier in the quasi-two dimensional channel of a pentacene transistor by a factor of two from its bulk value when the gate is a high-permittivity dielectric such as (Ta2O5)(\textrm{Ta}_{2}\textrm{O}_{5}) while this reduction essentially vanishes using a polymer gate-insulator. These results demonstrate that carrier mass renormalization triggers the dielectric effects on the mobility reported recently in OFETs.Comment: 19 pages, 3 figure

    General conditions for scale-invariant perturbations in an expanding universe

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    We investigate the general properties of expanding cosmological models which generate scale-invariant curvature perturbations in the presence of a variable speed of sound. We show that in an expanding universe, generation of a super-Hubble, nearly scale-invariant spectrum of perturbations over a range of wavelengths consistent with observation requires at least one of three conditions: (1) accelerating expansion, (2) a speed of sound faster than the speed of light, or (3) super-Planckian energy density.Comment: 4 pages, RevTe

    Near Scale Invariance with Modified Dispersion Relations

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    We describe a novel mechanism to seed a nearly scale invariant spectrum of adiabatic perturbations during a non-inflationary stage. It relies on a modified dispersion relation that contains higher powers of the spatial momentum of matter perturbations. We implement this idea in the context of a massless scalar field in an otherwise perfectly homogeneous universe. The couplings of the field to background scalars and tensors give rise to the required modification of its dispersion relation, and the couplings of the scalar to matter result in an adiabatic primordial spectrum. This work is meant to explicitly illustrate that it is possible to seed nearly scale invariant primordial spectra without inflation, within a conventional expansion history.Comment: 7 pages and no figures. Uses RevTeX

    Supersolid phase with cold polar molecules on a triangular lattice

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    We study a system of heteronuclear molecules on a triangular lattice and analyze the potential of this system for the experimental realization of a supersolid phase. The ground state phase diagram contains superfluid, solid and supersolid phases. At finite temperatures and strong interactions there is an additional emulsion region, in contrast to similar models with short-range interactions. We derive the maximal critical temperature TcT_c and the corresponding entropy S/N=0.04(1)S/N = 0.04(1) for supersolidity and find feasible experimental conditions for its realization.Comment: 4 pages, 4 figure

    Unconventional magnetization plateaus in a Shastry-Sutherland spin tube

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    Using density matrix renormalization group (DMRG) and perturbative continuous unitary transformations (PCUTs), we study the magnetization process in a magnetic field for all coupling strengths of a quasi-1D version of the 2D Shastry-Sutherland lattice, a frustrated spin tube made of two orthogonal dimer chains. At small inter-dimer coupling, plateaus in the magnetization appear at 1/6, 1/4, 1/3, 3/8, and 1/2. As in 2D, they correspond to a Wigner crystal of triplons. However, close to the boundary of the product singlet phase, plateaus of a new type appear at 1/5 and 3/4. They are stabilized by the localization of {\it bound states} of triplons. Their magnetization profile differs significantly from that of single triplon plateaus and leads to specific NMR signatures. We address the possibility to stabilize such plateaus in further geometries by analyzing small finite clusters using exact diagonalizations and the PCUTs.Comment: Final version as published in EP

    A Dynamical Solution to the Problem of a Small Cosmological Constant and Late-time Cosmic Acceleration

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    Increasing evidence suggests that most of the energy density of the universe consists of a dark energy component with negative pressure, a ``cosmological constant" that causes the cosmic expansion to accelerate. In this paper, we address the puzzle of why this component comes to dominate the universe only recently rather than at some much earlier epoch. We present a class of theories based on an evolving scalar field where the explanation is based entirely on internal dynamical properties of the solutions. In the theories we consider, the dynamics causes the scalar field to lock automatically into a negative pressure state at the onset of matter-domination such that the present epoch is the earliest possible time, consistent with nucleosynthesis restrictions, when it can start to dominate.Comment: 5 pages, 3 figure

    Quantum coherence and carriers mobility in organic semiconductors

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    We present a model of charge transport in organic molecular semiconductors based on the effects of lattice fluctuations on the quantum coherence of the electronic state of the charge carrier. Thermal intermolecular phonons and librations tend to localize pure coherent states and to assist the motion of less coherent ones. Decoherence is thus the primary mechanism by which conduction occurs. It is driven by the coupling of the carrier to the molecular lattice through polarization and transfer integral fluctuations as described by the hamiltonian of Gosar and Choi. Localization effects in the quantum coherent regime are modeled via the Anderson hamiltonian with correlated diagonal and non-diagonal disorder leading to the determination of the carrier localization length. This length defines the coherent extension of the ground state and determines, in turn, the diffusion range in the incoherent regime and thus the mobility. The transfer integral disorder of Troisi and Orlandi can also be incorporated. This model, based on the idea of decoherence, allowed us to predict the value and temperature dependence of the carrier mobility in prototypical organic semiconductors that are in qualitative accord with experiments
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