Graphitized Carbon Xerogels for Lithium-Ion Batteries

Carbon xerogels with different macropore sizes and degrees of graphitization were evaluated as electrodes in lithium-ion batteries. It was found that pore structure of the xerogels has a marked effect on the degree of graphitization of the final carbons. Moreover, the incorporation of graphene oxide to the polymeric structure of the carbon xerogels also leads to a change in their carbonaceous structure and to a remarkable increase in the graphitic phase of the samples studied. The sample with the highest degree of graphitization (i.e., hybrid graphene-carbon xerogel) displayed the highest capacity and stability over 100 cycles, with values even higher than those of the commercial graphite SLP50 used as reference