2,297 research outputs found

    Effect of extrusion conditions and postextrusion techniques on the morphology and thermal/mechanical properties of polycaprolactone/clay nanocomposites

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    The effect of extrusion conditions on the performance of polycaprolactone /organo-modified clay nanocomposites was studied. It was demonstrated that the extrusion parameters have negligible effect on the molecular weight of polycaprolactone, on the morphology of the nanocomposites and on the final thermal/mechanical properties of the materials. This result was a consequence of the previous optimization of both polymer/clay compatibility and clay processing stability. Finally, the molten-polycaprolactone/clay mixtures were post-processed by different techniques submitting the mixtures to extensional flow. Clay platelets alignment was observed as a function of the extensional flow intensity which further improved the mechanical properties of the nanocomposites.Fil: Ludueña, Leandro Nicolas. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingenieria; ArgentinaFil: Kenny, J. M.. Università di Perugia; ItaliaFil: Vazquez, Analia. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Oficina de Coordinacion Administrativa Houssay. Instituto D/tec.y Cs.de la Ing.;Fil: Alvarez, Vera Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina. Universidad Nacional de Mar del Plata. Facultad de Ingenieria; Argentin

    Fighting against plant saline stress: Development of a novel bioactive composite based on bentonite and L-proline

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    Soil salinity is one of the most critical environmental stresses that affects crop productivity. In a context in which world demand for food is growing continuously, this problem requires urgent attention. Actions that go beyond traditional agricultural practices are needed. The objective of the current study was to develop a bioactive, economic, and sustainable compound that can increase the tolerance of cultivated plants in saline-stress situations by combining the hosting capacity of natural bentonite nanoclay (Bent) with a phytoactive osmoprotective compound, L-Proline (Pro). The Bent-Pro nanocomposite synthesis method, its final chemical structure, and in vitro bioactivity were addressed here. The results indicated that Bent can retain a maximum of 14.4% (w/w) of Pro. The (001) X-ray diffraction (XRD) peak of Bent shifted to smaller angles in the pattern of Bent-Pro, indicating that Pro has a monolayer arrangement between the Bent layers. The results of transmission electron microscopy (TEM) also supported this result. Pro was also retained on the edges or external surfaces of Bent, as indicated by thermogravimetric analysis (TGA) and scanning electron microscopy (SEM). In addition, Pro functional groups identified by Fourier-transform infrared (FTIR) spectroscopy indicated that it was present in its zwitterionic form. The role of Bent-Pro as a protector against plant saline stress was assayed using Arabidopsis thaliana (A. thaliana) as a model, demonstrating that it mitigates the detrimental effects of NaCl-mediated salt stress on seed germination and the leaf chlorophyll level, thus highlighting the relevance of this contribution and the versatility and broad applicability of clays.Fil: Merino, Danila. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Iglesias, María J.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones Biológicas. Universidad Nacional de Mar del Plata. Facultad de Ciencias Exactas y Naturales. Instituto de Investigaciones Biológicas; ArgentinaFil: Mansilla, Andrea Yamila. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones Biológicas. Universidad Nacional de Mar del Plata. Facultad de Ciencias Exactas y Naturales. Instituto de Investigaciones Biológicas; ArgentinaFil: Casalongué, Claudia A.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones Biológicas. Universidad Nacional de Mar del Plata. Facultad de Ciencias Exactas y Naturales. Instituto de Investigaciones Biológicas; ArgentinaFil: Alvarez, Vera A.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentin

    Environmental reprogramming of the expression of protein kinase CK2β subunit in fish

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    Indexación: Scopus.The dramatic segregation of the nucleolar components in winter-acclimatized carp is the most striking cellular-phenotypical feature observed during the seasonal adaptation of this fish toward the circannual changes in its habitat. Our studies also show that the carp habitat temperature and photoperiod winter conditions provoke a remarkable reduction of both rRNA transcription and the processing of their precursors. To gain knowledge on the mechanisms involved in the regulation of nucleolar activity during the seasonal adaptation process, we studied the behavior of some genes, specifically snoRNA U3 and protein kinase CK2. Consistent with the reduction in the synthesis and processing of pre-rRNA observed during the cold season, the level of CK2β expression decreases in winter when compared to that attained in summer. Similarly, in winter, liver and kidney cells contain lower levels of CK2β subunit protein compared to summer. CK2 is associated with or modifies different factors and enzymes involved in the nucleolar activity; therefore, its higher or lower content could be part of the molecular mechanisms underlying the nucleolar seasonal changes that occur during the compensatory acclimatization process.https://link-springer-com.recursosbiblioteca.unab.cl/article/10.1023%2FA%3A101313761236

    Evaluación de competencias digitales de egreso en programas educativos en computación y tecnologías de información bajo el paradigma de la sociedad 5.0

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    The objective of this work is to define means of assessing the educational programs of Information Technology through the achievement of digital graduation competences, both soft skills and specific (competences of the different disciplines of the specialties) within the paradigm Industry 4.0. A model of assessment of graduation competences is presented considering three important moments of the process: 1. Planning, 2. Execution and 3. Assessment. A case study is presented to demonstrate the application of the proposer assessment model, in which the fulfilment of graduation competencies for an educational program can be observed

    Effect of cooling rate during solidification on the hard phases of M23C6-type of cast CoCrMo alloy

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    Microstructural morphology of CoCrMo alloy by control of the cooling rate during the solidification was investigated. Samples were obtained using both an induction furnace for slow cooling rate and electric arc furnace for fast cooling rate. Microstructural characterizations were performed with metallographic techniques. It was found that the difference between the formation temperature of hard secondary phases of M23C6-type carbides determine the reduction of carbide size by increasing the cooling rate

    Behaviour of uranium along Jucar River (Eastern Spain) Determination of 234U/238U and 235U/238U ratios

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    The uranium concentration and the U-234/U-238, U-235/U-238 activity ratios were studied in water samples from Jucar River, using low-level alpha-spectrometry. The effects of pH, temperature and salinity were considered and more detailed sampling was done in the neighbourhood of Cofrentes Nuclear plant (Valencia, Spain). Changes were observed in the uranium concentration with the salinity and the U-234/U-238 activity ratio was found to vary with pH. Leaching and dilution, which depend on pH and salinity, are the probable mechanisms for these changes in the concentration of uranium and the activity ratios.Rodríguez Álvarez, MJ.; Sanchez, F. (1995). Behaviour of uranium along Jucar River (Eastern Spain) Determination of 234U/238U and 235U/238U ratios. Journal of Radioanalytical and Nuclear Chemistry. 190(1):113-120. doi:10.1007/BF02035642S1131201901M. J. RORDÍGUEZ-AALVAREZ, F. SÁNCHEZ, E. NAVARRO, Proc. 3nd Intern. Summer School, Huelva Spain, M. GARCÍA-LEÓN, G. MADURGA (Eds), World Scientific, Singapore, 1994.M. IVANOVICH, R. S. HARMON (Eds), Uranium Disequilibrium Series: Applications to Environmental Problems, Clarendon Press, Oxford, 1982.K. OSMOND, J. B. COWART, At. Energy Rev., 14 (1976) 621.B. L. DICKSON, R. L. MEAKINS, Nucl. Instrum. Methods Phys. Res., 223 (1983) 593.J. L. GASCÓN, MURILLO, PhD Thesis, University of Zaragoza, Spain, 1990.M. C. MORÓN, A. MARTINEZ-AGUIRRE, M. GARCÍA-LEÓN, Intern. Conf. on Environmental Radioactivity in the Mediterranean Area, Barcelona 10–13 May 1988, SNE-ENS, Barcelona, 1988, p. 111.R. BOJANOWSKI, R. FUKAI, S. BALLESTRA, H. ASARI, Determination of natural radioactive elements in marine environmental materials by ion-exchange and α-spectrometry. Proc. 4th Symp. on the Determination of Radionuclides in Environmental and Biological Materials, April 1983, London, Ed-Rd Press.R. GARCÍA-TENORIO, M. GARCÍA-LEÓN, G. PIAZZA, Anal. Física B, 82 (1986) 238.L. HALLSTADIUS, Nucl. Instrum. Methods Phys. Res., 223 (1984) 266.F. VERA, A. MARTIN, Nucl. Instrum. Methods Phys. Res., A276 (1989) 289.A. MARTINEZ-AGUIRRE, M. GARCÍA-LEÓN, J. Radioanal. Nucl. Chem., 155 (1991) 97.J. R. DOOLEY, H. C. ROSHOLT, Econ. Geol., 61 (1996) 326.A. MARTINEZ-AGUIRRE, M. GARCÍA-LEÓN, Radiat. Prot. Dosim., 45 (1992) 249.J. TOOLE, M. S. BAXTER, J. THOMSON, Estuarine, Coastal and Shelf Sci., 25 (1987) 283.S. G. BHAT, S. KRISHANASWAMI, Proc. Indian Acad. Sci., A LXX, (1969).K. K. TUREKIAN, J. K. COCHRAN, in: Chemical Oceanography, Vol. 7, J. P. RILEY and R. CHESTER (Eds), 2nd ed., Academic Press, New York, 1978.D. LANGMUIR, Geochim. Cosmochim. Acta, 42 (1978) 547.J. M. MARTIN, M. MEYBECK, Mar. Chem., 7 (1979) 173.Radionuclide Transformations, Annals of the ICRP, ICRP Publication 38, Vol. 11–13, Pergamon Press, 1983.A. MANGINI, G. SONNTAG, G. BERTSCH, E. MÜLLER, Nature, 278 (1979) 337.M. R. SCOTT, in: M. IVANOVICH, R. S. HARMON (Eds), Uranium Disequilibrium Series: Applications to Environmental Problems, Clarendon Press, Oxford, 1982.J. K. OSMOND, J. B. COWART, in: M. IVANOVICH, R. S. HARMON (Eds), Uranium Disequilibrium Series: Applications to Environmental Problems, Clarendon Press, Oxford, 1982.R. BOWEN (Eds), Isotopes in the Earth Sciences, Elsevier Applied Science, 1988.F. VERA, PhD Thesis, University Extremadura, Spain, 1988.F. VERA, A. MARTIN, J. Radioanal. Nucl. Chem., 134 (1988) 73

    Effectiveness of individualized inhaler technique training on low adherence (LowAd) in ambulatory patients with COPD and asthma

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    © 2022. This document is made available under the CC-BY 4.0 license http://creativecommons.org/licenses/by /4.0/ This document is the published version of a published work that appeared in final form in npj primary care respiratory medicineTo analyze whether there is improvement in adherence to inhaled treatment in patients with COPD and asthma after an educational intervention based on the teach-to-goal method. This is a prospective, non-randomized, single-group study, with intervention and before-after evaluation. The study population included 120 patients (67 females and 53 males) diagnosed with asthma (70.8%) and COPD (29.1%). The level of adherence (low and optimal) and the noncompliance behavior pattern (erratic, deliberate and unwitting) were determined by the Test of the adherence to Inhalers (TAI). This questionnaire allows you to determine the level of adherence and the types of noncompliance. Low Adherence (LowAd) was defined as a score less than 49 points. All patients received individualized educational inhaler technique intervention (IEITI). Before the IEITI, 67.5% of the patients had LowAd. Following IEITI, on week 24, LowAd was 55% (p = 0.024). Each patient can present one or more types of noncompliance. The most frequent type was forgetting to use the inhaler (erratic), 65.8%. The other types were deliberate: 43.3%, and unwitting: 57.5%. All of them had decreased on the final visit: 51.7% (p = 0.009), 25.8% (p = 0.002), 39.2% (p = 0.002). There were no significant differences in adherence between asthma and COPD patients at the start of the study. The only predicting factor of LowAd was the female gender. An individualized educational intervention, in ambulatory patients with COPD and asthma, in real-world clinical practice conditions, improves adherence to the inhaled treatment

    Characterization of Microstructural and Mechanical Properties of 17-4 PH Stainless Steel by Cold Rolled and Machining vs. DMLS Additive Manufacturing

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    The 17-4 PH stainless steel is widely used in the aerospace, petrochemical, chemical, food, and general metallurgical industries. The present study was conducted to analyze the mechanical properties of two types of 17-4 PH stainless steel—commercial cold-rolled and direct metal laser sintering (DMLS) manufactured. This study employed linear and nonlinear tensile FEM simulations, combined with various materials characterization techniques such as tensile testing and nanoindentation. Moreover, microstructural analysis was performed using metallographic techniques, optical microscopy, scanning electron microscopy (SEM) with energy dispersive spectroscopy (EDS), and X-ray diffraction (XRD). The results on the microstructure for 17-4 PH DMLS stainless steel reveal the layers of melting due to the laser process characterized by complex directional columnar structures parallel to the DMLS build direction. The mechanical properties obtained from the simple tension test decreased by 17% for the elastic modulus, 7.8% for the yield strength, and 7% for the ultimate strength for 17-4 PH DMLS compared with rolled 17-4 PH stainless steel. The FEM simulation using the experimental tension test data revealed that the 17-4 PH DMLS stainless steel experienced a decrease in the yield strength of ~8% and in the ultimate strength of ~11%. A reduction of the yield strength of the material was obtained as the grain size increased
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