Determination of Trace Elements in Wine by Atomic Spectroscopy and Electroanalytical Methods

The chapter will outline the basic theory, advantages and disadvantages, experimental considerations and set up of various atomic spectroscopy, and electroanalytical quantification methods and their specific application to trace element determination in wines. The reader will gain an introduction to most popular elemental analysis methods used in beverage analysis. Copper, iron, manganese, and zinc will be used as examples of essential trace elements throughout the chapter that at high levels may affect the properties of wine as well as the sensory experience of the consumer. Furthermore, special considerations that should be given to wine as a sample matrix for quantitative analysis of inorganic elements and the use of standard addition methods will be described

Enzyme-Based Electrochemical Glutamate Biosensors

Glutamate, a major excitatory neurotransmitter in the mammalian central nervous system, plays a vital role in many physiological processes and is one of the key neurotransmitters of interest in psychopharmacology. It is involved in many normal and abnormal behaviors related to neurological and psychiatric disorders. The glutamate system has been proposed to play a significant role in various neurological and psychiatric disorders such as Alzheimer’s disease, autism, schizophrenia, depression, drug addiction, and more. The design, construction, and optimization of enzyme-based electrochemical biosensors for in vivo and in vitro detection of glutamate are active areas of interdisciplinary research. For example, various glutamate biosensors have been developed for monitoring dynamic levels of extracellular glutamate in the living brain tissue adding to the current medical knowledge of these complex neurotransmitter systems and ultimately impacting treatment plans. In addition to biological sciences and clinical medicine, glutamate biosensors have been used in environmental monitoring, in the fermentation industry, and in the food industry for determination of monosodium glutamate (MSG), a common flavor-enhancing food additive

Multichannel optical sensor for oil film pressure measurement in engine main bearing

An optical sensor has been developed for experimental determination of oil film pressure in journal bearings. The non-intrusive fibre optic sensor is integrated in the sliding surface of the bearing to measure the actual oil film pressure under load without disturbing the actual tribological contact conditions. The sensors with a multichannel system also allowed the use of several optical sensors simultaneously. Four optical sensors were integrated in a hydrodynamic journal bearing of a large scale diesel engine and the engine tests were carried out with different loads to study the sensor operation in demanding operating conditions. The oil film pressure was successfully measured and the results showed differences in bearing pressure depending on the position of the sensor and on the operating cycle of the cylinders. The optical sensor was capable to measure the oil film pressure in journal bearing with a good sensitivity and repeatability during the tests. &nbsp

‘School, family and then hockey!’ Coaches’ views on dual career in ice hockey

Despite the extensive research into coaches’ roles in supporting athletic development and motivation for sport, few studies have examined coaches’ attitudes and practices towards athletes’ dual careers. The present study extends European research into athletes’ dual careers by examining Finnish ice hockey coaches’ attitudes and practices surrounding players’ education. Ten male coaches aged 27–52 participated in semi-structured interviews. The data were analysed with an existential-narrative theoretical framework and with thematic and structural narrative analysis. Three composite vignettes were created entitled ‘supporting athletic development and players in reaching their own goals’, ‘enjoyment and physically active lifestyle’ and ‘developing good persons’. The analysis revealed that although all coaches embraced the official rhetoric where school is a priority over ice hockey, most of them had few practical examples of how this view had informed their coaching practice. It is concluded that young players may be easily lured into dreams of professionalism, whereas coaches’ dominant narrative of education as a back-up may be ineffective to spark athletes’ interest and engagement with education. © 2017, © The Author(s) 2017

Sonically-enhanced widgets: comments on Brewster and Clarke, ICAD 1997

This paper presents a review of the research surrounding the paper “The Design and Evaluation of a Sonically Enhanced Tool Palette” by Brewster and Clarke from ICAD 1997. A historical perspective is given followed by a discussion of how this work has fed into current developments in the area

Work-related stress and well-being in association with epigenetic age acceleration: a Northern Finland Birth Cohort 1966 Study

Recent evidence indicates consistent association of low socioeconomic status with epigenetic age acceleration, measured from DNA methylation. As work characteristics and job stressors are crucial components of socioeconomic status, we investigated their association with various measures of epigenetic age acceleration. The study population included employed and unemployed men and women (n=604) from the Northern Finland Birth Cohort 1966. We investigated the association of job strain, effort-reward imbalance and work characteristics with five biomarkers of epigenetic aging (Hannum, Horvath, PhenoAge, GrimAge, and DunedinPoAm). Our results indicate few significant associations between work stress indicators and epigenetic age acceleration, limited to a range of ±2 years, and smoking recording the highest effect on GrimAge age acceleration biomarker between current and no smokers (median difference 4.73 years (IQR 1.18, 8.41). PhenoAgeAA was associated with job strain active work (β=-1.301 95%CI -2.391, -0.212), slowing aging of less than 1.5 years, and working as white-collar slowed aging six months (GrimAgeAA β=-0.683, 95%CI -1.264, -0.102) when compared to blue collars. Association was found for working for more than 40 hours per week that increased the aging over 1.5 years, (HorvathAA β =2.058 95%CI 0.517,3.599, HannumAA β=1.567, 95%CI 0.415,2.719). The pattern of associations was different between women and men and some of the estimated effects are inconsistent with current literature. Our results provide the first evidence of association of work conditions with epigenetic aging biomarkers. However, further epidemiological research is needed to fully understand how work-related stress affects epigenetic age acceleration in men and women in different societies

Acute compartment syndrome of the hand in Henoch-Schonlein Purpura

An eight year old boy with Henoch-Schonlein Purpura (HSP) presented with acute compartment syndrome (ACS) of his left hand following arterial cannulation of his radial artery in intensive care unit. Emergency decompression and fasciotomy were performed. The authors report this first case in literature and discuss how HSP can be complicated by ACS and ways to prevent the latter from happening

Interannual sea ice thickness variability in the Bay of Bothnia

While variations of Baltic Sea ice extent and thickness have been extensively studied, there is little information about drift ice thickness, distribution, and its variability. In our study, we quantify the interannual variability of sea ice thickness in the Bay of Bothnia during the years 2003–2016. We use various different data sets: official ice charts, drilling data from the regular monitoring stations in the coastal fast ice zone, and helicopter and shipborne electromagnetic soundings. We analyze the different data sets and compare them to each other to characterize the interannual variability, to discuss the ratio of level and deformed ice, and to derive ice thickness distributions in the drift ice zone. In the fast ice zone the average ice thickness is 0.58±0.13&thinsp;m. Deformed ice increases the variability of ice conditions in the drift ice zone, where the average ice thickness is 0.92±0.33&thinsp;m. On average, the fraction of deformed ice is 50&thinsp;% to 70&thinsp;% of the total volume. In heavily ridged ice regions near the coast, mean ice thickness is approximately half a meter thicker than that of pure thermodynamically grown fast ice. Drift ice exhibits larger interannual variability than fast ice.</p

Extremes on the discounted aggregate claims in a time dependent risk model

This paper presents an extension of the classical compound Poisson risk model for which the inter-claim time and the forthcoming claim amount are no longer independent random variables (rv's). Asymptotic tail probabilities for the discounted aggregate claims are presented when the force of interest is constant and the claim amounts are heavy tail distributed rv's. Furthermore, we derive asymptotic finite time ruin probabilities, as well as asymptotic approximations for some common risk measures associated with the discounted aggregate claims. A simulation study is performed in order to validate the results obtained in the free interest risk model