135 research outputs found
Subharmonic bifurcation cascade of pattern oscillations caused by winding number increasing entrainment
Convection structures in binary fluid mixtures are investigated for positive
Soret coupling in the driving regime where solutal and thermal contributions to
the buoyancy forces compete. Bifurcation properties of stable and unstable
stationary square, roll, and crossroll (CR) structures and the oscillatory
competition between rolls and squares are determined numerically as a function
of fluid parameters. A novel type of subharmonic bifurcation cascade (SC) where
the oscillation period grows in integer steps as is found
and elucidated to be an entrainment process.Comment: 7 pages, 4 figure
Catalyst-free Hydrophosphinylation of Isocyanates and Isothiocyanates under Low-Added-Solvent Conditions
A catalyst-free, low-solvent method for the hydrophosphinylation of isocyanates and isothiocyanates is reported. A range of phosphorus nucleophiles including secondary phosphine oxides HP(O)R2 (R = Ph, i Pr), phosphites HP(O)(OR)2 (R = Me, Et), and methyl phenylphosphinate are tested. The procedure tolerates isocyanates and isothiocyanates featuring a wide range of substituents and, by using four equivalents of 2-methyltetrahydrofuran (2-MeTHF), solid substrates can be utilized. Twenty-five compounds are prepared, with improved functional group tolerance compared to previous methods and allowing access to new compounds (16 are novel). Facile scale up and simple reaction conditions make this a straightforward and practical methodology for obtaining phosphorus analogues of ureas and thioureas, which are challenging to synthesize by other methods
Catalyst-free hydrophosphinylation of isocyanates and isothiocyanates under low-added-solvent conditions
A catalyst-free, low-solvent method for the hydrophosphinylation of isocyanates and isothiocyanates is reported. A range of phosphorus nucleophiles including secondary phosphine oxides HP(O)R2 (R = Ph, iPr), phosphites HP(O)(OR)2 (R = Me, Et), and methyl phenylphosphinate were tested. The procedure tolerated isocyanates and isothiocyanates featuring a wide range of substituents and, with use of 4 equiv of 2-methyltetrahydrofuran (2-MeTHF), solid substrates can be utilized. Twenty-five compounds were prepared with improved functional group tolerance compared to previous methods allowing access to new compounds (16 are novel). Facile scale up and simple reaction conditions make this a straightforward and practical methodology for obtaining phosphorus analogues of ureas and thioureas, which are challenging to synthesize by other methods
Enhancement of the Deuteron-Fusion Reactions in Metals and its Experimental Implications
Recent measurements of the reaction d(d,p)t in metallic environments at very
low energies performed by different experimental groups point to an enhanced
electron screening effect. However, the resulting screening energies differ
strongly for divers host metals and different experiments. Here, we present new
experimental results and investigations of interfering processes in the
irradiated targets. These measurements inside metals set special challenges and
pitfalls which make them and the data analysis particularly error-prone. There
are multi-parameter collateral effects which are crucial for the correct
interpretation of the observed experimental yields. They mainly originate from
target surface contaminations due to residual gases in the vacuum as well as
from inhomogeneities and instabilities in the deuteron density distribution in
the targets. In order to address these problems an improved differential
analysis method beyond the standard procedures has been implemented. Profound
scrutiny of the other experiments demonstrates that the observed unusual
changes in the reaction yields are mainly due to deuteron density dynamics
simulating the alleged screening energy values. The experimental results are
compared with different theoretical models of the electron screening in metals.
The Debye-H\"{u}ckel model that has been previously proposed to explain the
influence of the electron screening on both nuclear reactions and radioactive
decays could be clearly excluded.Comment: 22 pages, 12 figures, REVTeX4, 2-column format. Submitted to Phys.
Rev. C; accepte
Hydrodynamic interactions in colloidal ferrofluids: A lattice Boltzmann study
We use lattice Boltzmann simulations, in conjunction with Ewald summation
methods, to investigate the role of hydrodynamic interactions in colloidal
suspensions of dipolar particles, such as ferrofluids. Our work addresses
volume fractions of up to 0.20 and dimensionless dipolar interaction
parameters of up to 8. We compare quantitatively with Brownian
dynamics simulations, in which many-body hydrodynamic interactions are absent.
Monte Carlo data are also used to check the accuracy of static properties
measured with the lattice Boltzmann technique. At equilibrium, hydrodynamic
interactions slow down both the long-time and the short-time decays of the
intermediate scattering function , for wavevectors close to the peak of
the static structure factor , by a factor of roughly two. The long-time
slowing is diminished at high interaction strengths whereas the short-time
slowing (quantified via the hydrodynamic factor ) is less affected by the
dipolar interactions, despite their strong effect on the pair distribution
function arising from cluster formation. Cluster formation is also studied in
transient data following a quench from ; hydrodynamic interactions
slow the formation rate, again by a factor of roughly two
Magnetization of ferrofluids with dipolar interactions - a Born--Mayer expansion
For ferrofluids that are described by a system of hard spheres interacting
via dipolar forces we evaluate the magnetization as a function of the internal
magnetic field with a Born--Mayer technique and an expansion in the dipolar
coupling strength. Two different approximations are presented for the
magnetization considering different contributions to a series expansion in
terms of the volume fraction of the particles and the dipolar coupling
strength.Comment: 19 pages, 11 figures submitted to PR
Thermodynamic perturbation theory for dipolar superparamagnets
Thermodynamic perturbation theory is employed to derive analytical
expressions for the equilibrium linear susceptibility and specific heat of
lattices of anisotropic classical spins weakly coupled by the dipole-dipole
interaction. The calculation is carried out to the second order in the coupling
constant over the temperature, while the single-spin anisotropy is treated
exactly. The temperature range of applicability of the results is, for weak
anisotropy (A/kT << 1), similar to that of ordinary high-temperature
expansions, but for moderately and strongly anisotropic spins (A/kT > 1) it can
extend down to the temperatures where the superparamagnetic blocking takes
place (A/kT \sim 25), provided only the interaction strength is weak enough.
Besides, taking exactly the anisotropy into account, the results describe as
particular cases the effects of the interactions on isotropic (A = 0) as well
as strongly anisotropic (A \to \infty) systems (discrete orientation model and
plane rotators).Comment: 15 pages, 3 figure
Anomalous enhancements of low-energy fusion rates in plasmas: the role of ion momentum distributions and inhomogeneous screening
Non-resonant fusion cross-sections significantly higher than corresponding
theoretical predictions are observed in low-energy experiments with deuterated
matrix target. Models based on thermal effects, electron screening, or
quantum-effect dispersion relations have been proposed to explain these
anomalous results: none of them appears to satisfactory reproduce the
experiments. Velocity distributions are fundamental for the reaction rates and
deviations from the Maxwellian limit could play a central role in explaining
the enhancement. We examine two effects: an increase of the tail of the target
Deuteron momentum distribution due to the Galitskii-Yakimets quantum
uncertainty effect, which broadens the energy-momentum relation; and spatial
fluctuations of the Debye-H\"{u}ckel radius leading to an effective increase of
electron screening. Either effect leads to larger reaction rates especially
large at energies below a few keV, reducing the discrepancy between
observations and theoretical expectations.Comment: 6 pages, 3 figure
Magnetic properties of colloidal suspensions of interacting magnetic particles
We review equilibrium thermodynamic properties of systems of magnetic
particles like ferrofluids in which dipolar interactions play an important
role. The review is focussed on two subjects: ({\em i}) the magnetization with
the initial magnetic susceptibility as a special case and ({\em ii}) the phase
transition behavior. Here the condensation ("gas/liquid") transition in the
subsystem of the suspended particles is treated as well as the
isotropic/ferromagnetic transition to a state with spontaneously generated
long--range magnetic order.Comment: Review. 62 pages, 4 figure
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