INVESTIGATION OF THE MECHANISMS OF HEAT EXCHANGER CORROSION IN A MUNICIPAL WASTE INCINERATION PLANT BY ANALYSIS OF THE RAW GAS AND VARIATION OF OPERATING PARAMETERS

The detailed mechanism of high temperature chlorine corrosion, the dominant cause of corrosion in a municipal solid waste incinerator (MSI), has still to be clarified (Schroer, 2002). Upon its way through the boiler the raw gas is subject to various physical and chemical processes and interactions. Of these, sulphation of chlorides is supposed to have the major impact on chlorine corrosion (Neumann, 1997). The physical and chemical mechanisms of corrosion were investigated at a municipal solid waste incinerator. Both, the particulate and gas phase of the flue gas, were chemically and physically analyzed during their way through the boiler, at temperatures from close to 1000 °C down to 200 °C. The raw gas composition was analyzed during normal operation and soot blowing cleaning routine. Additionally, operating parameters of the plant were varied, and deposition processes were evaluated with the aim to find out primary measures to reduce corrosion rates. The particle mass concentration exhibits a bimodal size distribution with maxima at approximately 0.5 μm – growing by duration of travel – and 100 μm. First results show that sulphation of the particles can be observed upon travel through the boiler and on the fouling. Sulphur containing additives increased the sulphation of the particles during flight though not to completion

Particle Collection Efficiency and Particle Re-entrainment of an Electrostatic Precipitator in a Sewage Sludge Incineration Plant.

In several recent studies it was shown that high atmospheric loads of submicrometer particles in the size range below 500 nm have strong impact on human health. Therefore, extensive research concerning the reduction of fine particle emissions is needed to further improve air quality. Regarding health effects, especially the emission characteristics of fine and ultrafine particles emerging from anthropogenic sources such as combustion processes are of special interest. This study shows that the emission characteristic of an electrostatic precipitator (ESP) due to re-entrainment of fine particles and their subsequent release into the atmosphere can be significantly lowered by application of different operating conditions. For this purpose the particle collection efficiency of an ESP was studied in a municipal sewage sludge incineration plant. Particles were sampled under different operating conditions upstream and downstream from the ESP, and the particle number concentrations were measured simultaneously with aerodynamic particle sizers. In addition, the size distribution of the particles downstream from the ESP was measured with high time resolution by an electrical low-pressure impactor to investigate the particle re-entrainment into the flue gas. To determine the influence of operating conditions, different rapping cycles were investigated regarding their impact on the collection efficiency and the subsequent particle re-entrainment

Input of pesticides by atmospheric deposition.

Sampling and analytical methods were developed to examine the input of various pesticides on noncultivated areas of the FAM (Research Network on Agroecosystems) Research Station Scheyern. Off-target drift from pesticide application on nearby cultivated land, as well as input due to long-range atmospheric transport, were measured. The wet deposition was determined by a cooled wet-only sampler. Bulk samplers and specially designed samplers with glass-fiber surface were used for total deposition measurements. Analysis of pesticides was carried out using liquid/liquid or solid-phase extraction and high performance liquid chromatography-UV (HPLC-UV) or gas chromatography-nitrogen/phosphorus-sensitive detector/MS (GC-NPD/MS) detection. Obtained results demonstrated that for several compounds, total deposition, i.e. the sum of wet and dry deposition, was marginally higher than wet deposition alone. In contrast, total deposition data of pesticides having been applied near the sampling site exceeded wet deposition values by orders of magnitude. In addition to direct drift, determined as droplets depositing near pesticide application areas, an indirect drift represented by particle-associated or gaseous transport was observed, both of which contributed considerably to total deposition. Therefore, to determine the input of pesticides to nontarget areas in the close vicinity of pesticide application, direct and indirect drift, and background deposition must be considered

Particle collection efficiency and particle rRe-entrainment of an electrostatic precipitator in a sewage sludge incineration plant

Particle collection efficiency and particle rRe-entrainment of an electrostatic precipitator in a sewage sludge incineration plant / R. Zimmermann ... - In: Environmental science & technology. 38. 2004. S. 1545-155

On-line Analysis of the Size Distribution of Fine and Ultrafine Aerosol Particles in Flue and Stack Gas of a Municipal Waste Incineration Plant : Effects of Dynamic Process Control Measures and Emission Reduction Devices.

The size distribution of particles in the waste gas of a municipal waste incineration plant (23 MW) was measured on-line at two sampling points in the flue-gas duct (700 and 300 °C) as well as in the stack gas (80 °C). The measurements were performed during both stable combustion conditions and transient operating conditions. The particle measurements were carried out by a mobile system consisting of a home-designed sampling system with dilution device and a scanning mobility particle sizer (SMPS) for the particle size range 17−600 nm as well as an aerodynamic particle sizer (APS) for the size range 500 nm−30 μm. The APS and SMPS data were combined using a special method and a home written software tool. The maximum of the particle-size distribution in the flue gas of the incinerator shifts from about 90 nm at the 700 °C sampling point to about 140 nm at the 300 °C point, showing the particle growth by coagulation processes and condensation of inorganic and organic gaseous species with decreasing temperature. This finding is consistent with the measured concentration profiles of gaseous organic chemical species in the flue gas. While at flue-gas temperatures of 600−800 °C a rich pattern of polycyclic aromatic hydrocarbon species (PAH) is observable, the PAH concentrations are considerably reduced further downstream of the flue-gas channel, where the temperature drops below 500 °C. Condensation and reactive bonding of gaseous chemicals onto particulate matter is, among other reasons, responsible for the depletion of gas-phase species. Process control measures, such as firing the back-up burners or cleaning of the grate with pressurized air, can cause dynamic changes of the particle-size distribution. Furthermore the flue-gas cleaning measures have great impact onto both the particle concentration and the size distribution. For this reason the impact of one particular emission reduction device, the wet electrostatic dust precipitator (wet-ESP), is evaluated. The wet-ESP reduces considerably the particle concentration over the whole size range. Behind the flue-gas processing units a broad maximum in the particle-size distribution occurs at about 70 nm, but no pronounced particle-size distribution could be observed. The particle concentration level at this maximum is about 3 magnitudes lower than in the raw flue gas. However, intermittent periods lasting for several minutes of high emissions of ultrafine particles with d < 40 nm were observed. These particles are most likely formed by nucleation processes behind the wet-ESP from gas-phase constituents of the stack gas