A model for atomic and molecular interstellar gas: The Meudon PDR code

We present the revised ``Meudon'' model of Photon Dominated Region (PDR code), presently available on the web under the Gnu Public Licence at: http://aristote.obspm.fr/MIS. General organisation of the code is described down to a level that should allow most observers to use it as an interpretation tool with minimal help from our part. Two grids of models, one for low excitation diffuse clouds and one for dense highly illuminated clouds, are discussed, and some new results on PDR modelisation highlighted.Comment: accepted in ApJ sup

Photodissociation of interstellar ArH+

Aims. Following the recent detection of 36ArH+ in the Crab nebula spectrum, we have computed the photodissociation rate of ArH+ in order to constrain the physical processes at work in this environment. Methods. Photodissociation cross sections of ArH+ are computed in an ab initio approach including explicit account of spin-orbit coupling. Results. We report the photodissociation cross section of ArH+ as a function of wavelength. Photodissociation probabilities are derived for different impinging radiation fields.The photodissociation probability of for a very small unshielded cloud surrounded on all sides by the unshielded InterStellar Radiation Field (ISRF) model described by Draine (1978) is equal to 9.9e-12 s-1 and 1.9e-9 s-1 in the Crab nebula conditions. The dependence on the visual extinction is obtained by using the Meudon Photon Dominated Region (PDR) code and corresponding analytical fits are provided. Conclusions. These data will help to produce a realistic chemical network to interpret the observations. Photodissociation of ArH+ is found to be moderate and the presence of this molecular ion is mainly dependent on the molecular fractionComment: 11 pages, 6 Figures, Accepted in Astronomy Astrophysic

The ionization fraction gradient across the Horsehead edge: An archetype for molecular clouds

The ionization fraction plays a key role in the chemistry and dynamics of molecular clouds. We study the H13CO+, DCO+ and HOC+ line emission towards the Horsehead, from the shielded core to the UV irradiated cloud edge, i.e., the Photodissociation Region (PDR), as a template to investigate the ionization fraction gradient in molecular clouds. We analyze a PdBI map of the H13CO+ J=1-0 line, complemented with IRAM-30m H13CO+ and DCO+ higher-J line maps and new HOC+ and CO+ observations. We compare self-consistently the observed spatial distribution and line intensities with detailed depth-dependent predictions of a PDR model coupled with a nonlocal radiative transfer calculation. The chemical network includes deuterated species, 13C fractionation reactions and HCO+/HOC+ isomerization reactions. The role of neutral and charged PAHs in the cloud chemistry and ionization balance is investigated. The detection of HOC+ reactive ion towards the Horsehead PDR proves the high ionization fraction of the outer UV irradiated regions, where we derive a low [HCO+]/[HOC+]~75-200 abundance ratio. In the absence of PAHs, we reproduce the observations with gas-phase metal abundances, [Fe+Mg+...], lower than 4x10(-9) (with respect to H) and a cosmic-rays ionization rate of zeta=(5+/-3)x10(-17) s(-1). The inclusion of PAHs modifies the ionization fraction gradient and increases the required metal abundance. The ionization fraction in the Horsehead edge follows a steep gradient, with a scale length of ~0.05 pc (or ~25''), from [e-]~10(-4) (or n_e ~ 1-5 cm(-3)) in the PDR to a few times ~10(-9) in the core. PAH^- anions play a role in the charge balance of the cold and neutral gas if substantial amounts of free PAHs are present ([PAH] >10(-8)).Comment: 13 pages, 7 figures, 6 tables. Accepted for publication in A&A (english not edited

HerschelHerschel SPIRE-FTS observations of RCW 120

The expansion of Galactic HII regions can trigger the formation of a new generation of stars. However, little is know about the physical conditions that prevail in these regions. We study the physical conditions that prevail in specific zones towards expanding HII regions that trace representative media such as the photodissociation region, the ionized region, and condensations with and without ongoing star formation. We use the SPIRE Fourier Transform Spectrometer (FTS) on board $Herschel$ to observe the HII region RCW 120. Continuum and lines are observed in the $190-670\,\mu$m range. Line intensities and line ratios are obtained and used as physical diagnostics of the gas. We used the Meudon PDR code and the RADEX code to derive the gas density and the radiation field at nine distinct positions including the PDR surface and regions with and without star-formation activity. For the different regions we detect the atomic lines [NII] at $205\,\mu$m and [CI] at $370$ and $609\,\mu$m, the $^{12}{\rm CO}$ ladder between the $J=4$ and $J=13$ levels and the $^{13}{\rm CO}$ ladder between the $J=5$ and $J=14$ levels, as well as CH$^{+}$ in absorption. We find gas temperatures in the range $45-250\,$K for densities of $10^4-10^6\,{\rm cm}^{-3}$, and a high column density on the order of $N_{{\rm H}}\sim10^{22}\,{\rm cm}^{-2}$ that is in agreement with dust analysis. The ubiquitousness of the atomic and CH$^{+}$ emission suggests the presence of a low-density PDR throughout RCW 120. High-excitation lines of CO indicate the presence of irradiated dense structures or small dense clumps containing young stellar objects, while we also find a less dense medium ($N_{{\rm H}}\sim10^{20}\,{\rm cm}^{-2}$) with high temperatures ($80-200\,$K).Comment: 11 pages, 11 figures, accepted by A&

Detection of CO+ in the nucleus of M82

We present the detection of the reactive ion CO+ towards the prototypical starburst galaxy M82. This is the first secure detection of this short-lived ion in an external galaxy. Values of [CO+]/[HCO+]>0.04 are measured across the inner 650pc of the nuclear disk of M82. Such high values of the [CO+]/[HCO+] ratio had only been previously measured towards the atomic peak in the reflection nebula NGC7023. This detection corroborates that the molecular gas reservoir in the M82 disk is heavily affected by the UV radiation from the recently formed stars. Comparing the column densities measured in M82 with those found in prototypical Galactic photon-dominated regions (PDRs), we need \~20 clouds along the line of sight to explain our observations. We have completed our model of the molecular gas chemistry in the M82 nucleus. Our PDR chemical model successfully explains the [CO+]/[HCO+] ratios measured in the M~82 nucleus but fails by one order of magnitude to explain the large measured CO+ column densities (~1--4x10^{13} cm^{-2}). We explore possible routes to reconcile the chemical model and the observations.Comment: 12 pages, 2 figure

The IRAM-30m line survey of the Horsehead PDR: IV. Comparative chemistry of H2CO and CH3OH

Aims. We investigate the dominant formation mechanism of H2CO and CH3OH in the Horsehead PDR and its associated dense core. Methods. We performed deep integrations of several H2CO and CH3OH lines at two positions in the Horsehead, namely the PDR and dense core, with the IRAM-30m telescope. In addition, we observed one H2CO higher frequency line with the CSO telescope at both positions. We determine the H2CO and CH3OH column densities and abundances from the single-dish observations complemented with IRAM-PdBI high-angular resolution maps (6") of both species. We compare the observed abundances with PDR models including either pure gas-phase chemistry or both gas-phase and grain surface chemistry. Results. We derive CH3OH abundances relative to total number of hydrogen atoms of ~1.2e-10 and ~2.3e-10 in the PDR and dense core positions, respectively. These abundances are similar to the inferred H2CO abundance in both positions (~2e-10). We find an abundance ratio H2CO/CH3OH of ~2 in the PDR and ~1 in the dense core. Pure gas-phase models cannot reproduce the observed abundances of either H2CO or CH3OH at the PDR position. Both species are therefore formed on the surface of dust grains and are subsequently photodesorbed into the gas-phase at this position. At the dense core, on the other hand, photodesorption of ices is needed to explain the observed abundance of CH3OH, while a pure gas-phase model can reproduce the observed H2CO abundance. The high-resolution observations show that CH3OH is depleted onto grains at the dense core. CH3OH is thus present in an envelope around this position, while H2CO is present in both the envelope and the dense core itself. Conclusions. Photodesorption is an efficient mechanism to release complex molecules in low FUV-illuminated PDRs, where thermal desorption of ice mantles is ineffective.Comment: 12 pages, 5 tables, 7 figures; Accepted for publication in A&

The role of carbon grains in the deuteration of H2

Aims: The production of molecular hydrogen and its deuterated forms onto carbonaceous dust grains is investigated in detail. The goal of this study is to estimate the importance of the chemistry occuring on grain surfaces for the deuteration of H2. Furthermore, we aim to find a robust and general surface chemical model which can be used in different astrophysical environments. Methods: Surface processes are described for the cases of graphitic and amorphous--carbon grains, where laboratory work is available. Langmuir--Hinshelwood as well as Eley--Rideal surface chemistries are included in the model and their relative contributions are highlighted. Analytic expressions are derived for H2, HD, and D2 formation efficiencies for both type of grains. Rate equations are tested against stochastic methods. Results: As expected, rate equations and stochastic methods diverge for grain sizes lower than a critical value acrit. For grain sizes below this critical value, D2 formation decreases to favour HD formation. The formation efficiencies of H2 and D2 can be calculated by adding a correction factor to the rate equations methods. We found that because of the presence of chemisorbed sites, which can store atoms to form molecules up to high grain temperatures, the formation efficiency of HD and D2 is very high compared to models where only physisorption sites are taken into account. When considering a realistic distribution of dust grains, we found that the formation rate of H2 and HD is enhanced by an order of magnitude if small grains are taken into account. The processes described in this paper, that allow a strong enhancement of the deuterated forms of molecular hydrogen, could explain the high degree of deuterium fractionation observed in protostellar environments.Comment: 17 pages 25 figure

The IRAM-30m line survey of the Horsehead PDR: II. First detection of the l-C3H+ hydrocarbon cation

We present the first detection of the l-C3H+ hydrocarbon in the interstellar medium. The Horsehead WHISPER project, a millimeter unbiased line survey at two positions, namely the photo-dissociation region (PDR) and the nearby shielded core, revealed a consistent set of eight unidentified lines toward the PDR position. Six of them are detected with a signal-to-noise ratio from 6 to 19, while the two last ones are tentatively detected. Mostly noise appears at the same frequency toward the dense core, located less than 40" away. We simultaneously fit 1) the rotational and centrifugal distortion constants of a linear rotor, and 2) the Gaussian line shapes located at the eight predicted frequencies. The observed lines can be accurately fitted with a linear rotor model, implying a 1Sigma ground electronic state. The deduced rotational constant value is Be= 11244.9512 +/- 0.0015 MHz, close to that of l-C3H. We thus associate the lines to the l-C3H+ hydrocarbon cation, which enables us to constrain the chemistry of small hydrocarbons. A rotational diagram is then used to infer the excitation temperature and the column density. We finally compare the abundance to the results of the Meudon PDR photochemical model.Comment: 9 pages, 7 PostScript figures. Accepted for publication in Astronomy \& Astrophysics. Uses aa LaTeX macro

Sensitivity analyses of dense cloud chemical models

Because of new telescopes that will dramatically improve our knowledge of the interstellar medium, chemical models will have to be used to simulate the chemistry of many regions with diverse properties. To make these models more robust, it is important to understand their sensitivity to a variety of parameters. In this article, we report a study of the sensitivity of a chemical model of a cold dense core, with homogeneous and time-independent physical conditions, to variations in the following parameters: initial chemical inventory, gas temperature and density, cosmic-ray ionization rate, chemical reaction rate coefficients, and elemental abundances. From the results of the parameter variations, we can quantify the sensitivity of the model to each parameter as a function of time. Our results can be used in principle with observations to constrain some parameters for different cold clouds. We also attempted to use the Monte Carlo approach with all parameters varied collectively. Within the parameter ranges studied, the most critical parameters turn out to be the reaction rate coefficients at times up to 4e5 yr and elemental abundances at later times. At typical times of best agreement with observation, models are sensitive to both of these parameters. The models are less sensitive to other parameters such as the gas density and temperature. The improvement of models will require that the uncertainties in rate coefficients of important reactions be reduced. As the chemistry becomes better understood and more robust, it should be possible to use model sensitivities concerning other parameters, such as the elemental abundances and the cosmic ray ionization rate, to yield detailed information on cloud properties and history. Nevertheless, at the current stage, we cannot determine the best values of all the parameters simultaneously based on purely observational constraints.Comment: Accepted for publication in Astronomy & Astrophysic