2,389 research outputs found
Optical diode based on the chirality of guided photons
Photons are nonchiral particles: their handedness can be both left and right.
However, when light is transversely confined, it can locally exhibit a
transverse spin whose orientation is fixed by the propagation direction of the
photons. Confined photons thus have chiral character. Here, we employ this to
demonstrate nonreciprocal transmission of light at the single-photon level
through a silica nanofibre in two experimental schemes. We either use an
ensemble of spin-polarised atoms that is weakly coupled to the nanofibre-guided
mode or a single spin-polarised atom strongly coupled to the nanofibre via a
whispering-gallery-mode resonator. We simultaneously achieve high optical
isolation and high forward transmission. Both are controlled by the internal
atomic state. The resulting optical diode is the first example of a new class
of nonreciprocal nanophotonic devices which exploit the chirality of confined
photons and which are, in principle, suitable for quantum information
processing and future quantum optical networks
Time-resolved oxygen production by PSII: chasing chemical intermediates
AbstractPhotosystem II (PSII) produces dioxygen from water in a four-stepped process, which is driven by four quanta of light and catalysed by a Mn-cluster and tyrosine Z. Oxygen is liberated during one step, coined S3⇒S0. Chemical intermediates on the way from reversibly bound water to dioxygen have not yet been tracked, however, a break in the Arrhenius plot of the oxygen-evolving step has been taken as evidence for its existence.We scrutinised the temperature dependence of (i) UV-absorption transients attributable to the reduction of the Mn-cluster and tyrosine Z by water, and (ii) polarographic transients attributable to the release of dioxygen. Using a centrifugatable and kinetically competent Pt-electrode, we observed no deviation from a linear Arrhenius plot of oxygen release in the temperature range from −2 to 32 °C, and hence no evidence, by this approach, for a sufficiently long-lived chemical intermediate. The half-rise times of oxygen release differed between Synechocystis WT* (at 20 °C: 1.35 ms) and a point mutant (D1–D61N: 13.1 ms), and the activation energies differed between species (Spinacia oleracea, 30 kJ/mol versus Synechocystis, 41 kJ/mol) and preparations (PSII membranes, 41 kJ/mol versus core complexes, 33 kJ/mol, Synechocystis).Correction for polarographic artefacts revealed, for the first time, a temperature-dependent lag-phase of the polarographic transient (duration at 20 °C: 0.45 ms, activation energy: 31 kJ/mol), which was indicative of a short-lived intermediate. It was, however, not apparent in the UV-transients. Thus the “intermediate” was probably newly formed and transiently bound oxygen
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