Synchroscan streak camera imaging at a 15-MeV photoinjector with emittance exchange

At the Fermilab A0 photoinjector facility, bunch-length measurements of the laser micropulse and the e-beam micropulse have been done in the past with a fast single-sweep module of the Hamamatsu C5680 streak camera with an intrinsic shot-to-shot trigger jitter of 10-20ps. We have upgraded the camera system with the synchroscan module tuned to 81.25MHz to provide synchronous summing capability with less than 1.5ps FWHM trigger jitter and a phase-locked delay box to provide phase stability of ~1ps over 10s of minutes. These steps allowed us to measure both the UV laser pulse train at 263nm and the e-beam via optical transition radiation (OTR). Due to the low electron beam energies and OTR signals, we typically summed over 50 micropulses with 0.25-1nC per micropulse. The phase-locked delay box allowed us to assess chromatic temporal effects and instigated another upgrade to an all-mirror input optics barrel. In addition, we added a slow sweep horizontal deflection plug-in unit to provide dual-sweep capability for the streak camera. We report on a series of measurements made during the commissioning of these upgrades including bunch-length and phase effects using the emittance exchange beamline and simultaneous imaging of a UV drive laser component, OTR, and the 800nm diagnostics laser.Comment: 26 p

Insight on Shallow Trap States-Introduced Photocathodic Performance in n-Type Polymer Photocatalysts

Graphitic carbon nitride (g-C3N4) is a robust organic semiconductor photocatalyst with proven H2 evolution ability. However, its application in a photoelectrochemical system as a photocathode for H2 production is extremely challenging with the majority of reports representing it as a photoanode. Despite research into constructing g-C3N4 photocathodes in recent years, factors affecting an n-type semiconductor’s properties as a photocathode are still not well-understood. The current work demonstrates an effective strategy to transform an n-type g-C3N4 photoanode material into an efficient photocathode through introducing electron trap states associated with both N-defects and C–OH terminal groups. As compared to the g-C3N4 photoelectrode, this strategy develops 2 orders of magnitude higher conductivity and 3 orders of magnitude longer-lived shallow-trapped charges. Furthermore, the average OCVD lifetime observed for def-g-C3N4 is 5 times longer than that observed for g-C3N4. Thus, clear photocathode behavior has been observed with negative photocurrent densities of around −10 μA/cm2 at 0 V vs RHE. Open circuit photovoltage decay (OCVD), Mott–Schottky (MS) plot, and transient absorption spectroscopy (TAS) provide consistent evidence that long-lived shallow-trapped electrons that exist at about the microsecond time scale after photoexcitation are key to the photocathode behavior observed for defect-rich g-C3N4, thus further demonstrating g-C3N4 can be both a photoanode and a photocathode candidate

Joint Iterative Optimization Based Low-Complexity Adaptive Hybrid Beamforming for Massive MU-MIMO Systems

IEEE This paper proposes a joint iterative optimization based hybrid beamforming technique for massive MU-MIMO systems. The proposed technique jointly and iteratively optimizes the transmitter precoders and combiners, aiming to approach the global optimum solution for the system sum-rate maximization problem. The proposed technique develops an adaptive algorithm exploiting the stochastic gradients (SG) of the local beamformers and provides low-complexity closed-form solutions. Furthermore, an efficient adaptive scheme is developed based on the proposed adaptive algorithm and the closed-form solutions. The proposed algorithm requires the signal-to-interference-plus-noise ratio (SINR) feedback from each user and a limited size transition vector to be exchanged between the transmitter and receivers at each step to update beamformers locally. Analytic result shows that the proposed adaptive algorithm achieves low-complexity when the array size is large and is able to converge within a small number of iterations. Simulation result shows that the proposed technique is able to achieve superior performance comparing to the existing state-of-art techniques. In addition, the knowledge of instantaneous channel state information (CSI) is not required as the channels are also adaptively estimated with each coherence time which is a practical assumption since the CSI is usually unavailable or have time-varying nature in real-time applications

Ru and RuOx decorated carbon nitride for efficient ammonia photosynthesis

Photocatalytic ammonia synthesis is a promising strategy for sustainable development compared to the energy-intensive industrial Haber-Bosch approach. Herein, a ternary heterostructure that consists of ruthenium species and carbon nitride (C3N4) was rationally explored for ammonia photosynthesis. Compared to the small ammonia yield from the g-C3N4 and Ru/g-C3N4 system, the Ru/RuO2/g-C3N4 system represents 6 times higher activity with excellent stability under full-spectrum irradiation. Such an enhancement is not only due to efficient transfer of electrons and holes to Ru and RuO2, respectively, facilitating both the reduction and oxidation reaction, but also taking advantage of Ru for N[triple bond, length as m-dash]N activation