Generalised Marcus Theory for Multi-Molecular Delocalised Charge Transfer

Although Marcus theory is widely used to describe charge transfer in molecular systems, in its usual form it is restricted to transfer from one molecule to another. If a charge is delocalised across multiple donor molecules, this approach requires us to treat the entire donor aggregate as a unified supermolecule, leading to potentially expensive quantum-chemical calculations and making it more difficult to understand how the aggregate components contribute to the overall transfer. Here, we show that it is possible to describe charge transfer between groups of molecules in terms of the properties of the constituent molecules and couplings between them, obviating the need for expensive supermolecular calculations. We use the resulting theory to show that charge delocalisation between molecules in either the donor or acceptor aggregates can enhance the rate of charge transfer through a process we call supertransfer (or suppress it through subtransfer). The rate can also be enhanced above what is possible with a single molecule by judiciously tuning energy levels and reorganisation energies. We also describe bridge-mediated charge transfer between delocalised molecular aggregates. The equations of generalised Marcus theory are in closed form, providing qualitative insight into the impact of delocalisation on charge dynamics in molecular systems

Generalized parton distributions from neutrino experiments

The analysis of deeply virtual meson production is extended to neutrino-production of the pseudo-Goldstone mesons (pions, kaons, eta-mesons) on nucleons, with the flavor content of the recoil baryon either preserved, or changed to a hyperon from the same SU(3) octet. We rely on the SU(3) relations and express all the cross-sections in terms of the proton generalized parton distributions (GPDs). The corresponding amplitudes are calculated at the leading twist level and in the leading order in \alpha_{s}, using a phenomenological parametrization of GPDs. We also included in the analysis the electromagnetic O(alpha_{em})-corrections to neutrino-induced deeply virtual meson production (\nuDVMP). We found that such electromagnetic corrections decrease with Q^2 in the Bjorken regime less than the standard \nuDVMP handbag contribution, so the electromagnetic mechanism dominates at large Q^2. The electromagnetic corrections give rise to an angular correlation between the lepton and hadron scattering planes with harmonics sensitive to the real and imaginary parts of the DVMP amplitude. These corrections constitute a few percent effect in the kinematics of the forthcoming MINERvA experiment at Fermilab and should be taken into account in precise tests of GPD parametrizations. For virtualities Q^2~100 GeV^2 these corrections become on a par with \nuDVMP handbag contributions.Comment: 5 pages, 3 figures, to appear in the proceedings of the DIS 2013 Workshop, Marseille, France, 22-26 April 201

Key Generation in Wireless Sensor Networks Based on Frequency-selective Channels - Design, Implementation, and Analysis

Key management in wireless sensor networks faces several new challenges. The scale, resource limitations, and new threats such as node capture necessitate the use of an on-line key generation by the nodes themselves. However, the cost of such schemes is high since their secrecy is based on computational complexity. Recently, several research contributions justified that the wireless channel itself can be used to generate information-theoretic secure keys. By exchanging sampling messages during movement, a bit string can be derived that is only known to the involved entities. Yet, movement is not the only possibility to generate randomness. The channel response is also strongly dependent on the frequency of the transmitted signal. In our work, we introduce a protocol for key generation based on the frequency-selectivity of channel fading. The practical advantage of this approach is that we do not require node movement. Thus, the frequent case of a sensor network with static motes is supported. Furthermore, the error correction property of the protocol mitigates the effects of measurement errors and other temporal effects, giving rise to an agreement rate of over 97%. We show the applicability of our protocol by implementing it on MICAz motes, and evaluate its robustness and secrecy through experiments and analysis.Comment: Submitted to IEEE Transactions on Dependable and Secure Computin