149 research outputs found
Comparison of the effects of puroindoline genotypes on grain and flour properties using near isogenic lines
Strong valence fluctuation in the quantum critical heavy fermion superconductor beta-YbAlB4: A hard x-ray photoemission study
Electronic structures of the quantum critical superconductor beta-YbAlB4 and
its polymorph alpha-YbAlB4 are investigated by using bulk-sensitive hard x-ray
photoemission spectroscopy. From the Yb 3d core level spectra, the values of
the Yb valence are estimated to be ~2.73 and ~2.75 for alpha- and beta-YbAlB4,
respectively, thus providing clear evidence for valence fluctuations. The
valence band spectra of these compounds also show Yb2+ peaks at the Fermi
level. These observations establish an unambiguous case of a strong mixed
valence at quantum criticality for the first time among heavy fermion systems,
calling for a novel scheme for a quantum critical model beyond the conventional
Doniach picture in beta-YbAlB4.Comment: 4 pages, 3 figures, revised version accepted for publication in PR
Recoil effects of photoelectrons in a solid
High energy resolution C 1 photoelectron spectra of graphite were measured
at the excitation energy of 340, 870, 5950 and 7940eV using synchrotron
radiation. On increasing the excitation energy, i.e., increasing kinetic energy
of the photoelectron, the bulk origin C 1 peak position shifts to higher
binding energies. This systematic shift is due to the kinetic energy loss of
the high-energy photoelectron by kicking the atom, and is clear evidence of the
recoil effect in photoelectron emission. It is also observed that the
asymmetric broadening increases for the higher energy photoelectrons. All these
recoil effects can be quantified in the same manner as the M\"ossbauer effect
for -ray emission from nuclei embedded in crystals.Comment: 4 pages, 2 figure
Photoemission evidence for a Mott-Hubbard metal-insulator transition in VO
The temperature () dependent metal-insulator transition (MIT) in VO is
investigated using bulk sensitive hard x-ray ( 8 keV) valence band, core
level, and V 2 resonant photoemission spectroscopy (PES). The valence
band and core level spectra are compared with full-multiplet cluster model
calculations including a coherent screening channel. Across the MIT, V 3
spectral weight transfer from the coherent ( final)
states at Fermi level to the incoherent ( final)
states, corresponding to the lower Hubbard band, lead to gap-formation. The
spectral shape changes in V 1 and V 2 core levels as well as the valence
band are nicely reproduced from a cluster model calculations, providing
electronic structure parameters. Resonant-PES finds that the
states resonate across the V 2 threshold in
addition to the and states. The results support
a Mott-Hubbard transition picture for the first order MIT in VO.Comment: 6 pages, 3 figures. to be published in Phys. Rev.
Revisiting the valence-band and core-level photoemission spectra of NiO
We have re-examined the valence-band (VB) and core-level electronic structure
of NiO by means of hard and soft x-ray photoemission spectroscopy (PES). The
spectral weight of the lowest energy state found to be enhanced in the bulk
sensitive Ni 2p core-level PES. A configuration-interaction model including the
bound state screening has shown significant agreement with the core-level
spectra, and the off and on-resonance VB spectra. These results identify the
lowest energy state in core-level and VB-PES as the Zhang-Rice doublet bound
state, consistent with the spin-fermion model and recent ab initio calculation
with dynamical mean-field theory (LDA + DMFT).Comment: 4 pages, 3 figure
Evidence for a correlated insulator to antiferromagnetic metal transition in CrN
We investigate the electronic structure of Chromium Nitride (CrN) across the
first-order magneto-structural transition at T_N ~ 286 K. Resonant
photoemission spectroscopy shows a gap in the 3d partial density of states at
the Fermi level and an On-site Coulomb energy U ~ 4.5 eV, indicating strong
electron-electron correlations. Bulk-sensitive high resolution (6 meV) laser
photoemission reveals a clear Fermi edge indicating an antiferromagnetic metal
below T_N. Hard x-ray Cr 2p core-level spectra show T-dependent changes across
T_N which originate from screening due to coherent states as substantiated by
cluster model calculations using the experimentally observed U. The electrical
resistivity confirms an insulator above T_N (E_g ~ 70 meV) which becomes a
disordered metal below T_N. The results indicate CrN transforms from a
correlated insulator to an antiferromagnetic metal, coupled to the
magneto-structural transition.Comment: Submitted to Physical Review Letters (February 2010) 11 pages, 3
figures in the main text, 1 Supplementary Informatio
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