8,948 research outputs found
Optical Yagi-Uda nanoantennas
Conventional antennas, which are widely employed to transmit radio and TV
signals, can be used at optical frequencies as long as they are shrunk to
nanometer-size dimensions. Optical nanoantennas made of metallic or
high-permittivity dielectric nanoparticles allow for enhancing and manipulating
light on the scale much smaller than wavelength of light. Based on this
ability, optical nanoantennas offer unique opportunities regarding key
applications such as optical communications, photovoltaics, non-classical light
emission, and sensing. From a multitude of suggested nanoantenna concepts the
Yagi-Uda nanoantenna, an optical analogue of the well-established
radio-frequency Yagi-Uda antenna, stands out by its efficient unidirectional
light emission and enhancement. Following a brief introduction to the emerging
field of optical nanoantennas, here we review recent theoretical and
experimental activities on optical Yagi-Uda nanoantennas, including their
design, fabrication, and applications. We also discuss several extensions of
the conventional Yagi-Uda antenna design for broadband and tunable operation,
for applications in nanophotonic circuits and photovoltaic devices
Anion receptor chemistry: highlights from 2011 and 2012
This review covers advances in anion complexation in the years 2011 and 2012. The review covers both organic and inorganic systems and also highlights the applications to which anion receptors can be applied such as self-assembly and molecular architecture, sensing, catalysis and anion transport
How the Medical Model has Influenced United Nations Policies on Refugees with Disabilities
Medical model perspectives have consistently influenced United Nations policies regarding disability, particularly in terms of refugees with disabilities. Refugees with disabilities are classified in the same category as refugees with medical needs, giving them an unequal chance of being resettled into a third country. Although the United Nations has moved away from medical model rhetoric in the past 15 years, this has not yet proven to have translated into resettlement policy for refugees with disabilities. This paper analyzes how the United Nations has shifted from a medical model of disability to a social model in various declarations, resolutions, and policies, and the impact this has had on refugees with disabilities. However, it is impossible to know the full extent of this impact, given a significant gap in research on the topic of this specific population
11,12-EET stimulates the association of BK channel α and β(1) subunits in mitochondria to induce pulmonary vasoconstriction
In the systemic circulation, 11,12-epoxyeicosatrienoic acid (11,12-EET) elicits nitric oxide (NO)- and prostacyclin-independent vascular relaxation, partially through the activation of large conductance Ca2+-activated potassium (BK) channels. However, in the lung 11,12-EET contributes to hypoxia-induced pulmonary vasoconstriction. Since pulmonary artery smooth muscle cells also express BK channels, we assessed the consequences of BKβ1 subunit deletion on pulmonary responsiveness to 11,12-EET as well as to acute hypoxia. In buffer-perfused mouse lungs, hypoxia increased pulmonary artery pressure and this was significantly enhanced in the presence of NO synthase (NOS) and cyclooxygenase (COX) inhibitors. Under these conditions the elevation of tissue EET levels using an inhibitor of the soluble epoxide hydrolase (sEH-I), further increased the hypoxic contraction. Direct administration of 11,12-EET also increased pulmonary artery pressure, and both the sEH-I and 11,12-EET effects were prevented by iberiotoxin and absent in BKβ1−/− mice. In pulmonary artery smooth muscle cells treated with NOS and COX inhibitors and loaded with the potentiometric dye, di-8-ANEPPS, 11,12-EET induced depolarization while the BK channel opener NS1619 elicited hyperpolarization indicating there was no effect of the EET on classical plasma membrane BK channels. In pulmonary artery smooth muscle cells a subpopulation of BK channels is localized in mitochondria. In these cells, 11,12-EET elicited an iberiotoxin-sensitive loss of mitochondrial membrane potential (JC-1 fluorescence) leading to plasma membrane depolarization, an effect not observed in BKβ1−/− cells. Mechanistically, stimulation with 11,12-EET time-dependently induced the association of the BK α and β1 subunits. Our data indicate that in the absence of NO and prostacyclin 11,12-EET contributes to pulmonary vasoconstriction by stimulating the association of the α and β1 subunits of mitochondrial BK channels. The 11,12-EET-induced activation of BK channels results in loss of the mitochondrial membrane potential and depolarization of the pulmonary artery smooth muscle cells
Agriculture, meteorology and water quality in Ireland: a regional evaluation of pressures and pathways of nutrient loss to water
peer-reviewedThe main environmental impact of Irish agriculture on surface and ground water quality is the potential transfer of nutrients to water. Soil water dynamics mediate the transport of nutrients to water, and these dynamics in turn depend on agro-meteorological conditions, which show large variations between regions, seasons and years. In this paper we quantify and map the spatio-temporal variability of agro-meteorological factors that control nutrient pressures and pathways of nutrient loss. Subsequently, we evaluate their impact on the water quality of Irish rivers. For nitrogen, pressure and pathways factors coincide in eastern and southern areas, which is reflected in higher nitrate levels of the rivers in these regions. For phosphorus, pathway factors are most pronounced in north-western parts of the country. In south-eastern parts, high pressure factors result in reduced biological water quality. These regional differences require that farm practices be customised to reflect the local risk of nutrient loss to water. Where pathways for phosphorus loss are present almost year-round—as is the case in most of the north-western part of the country—build-up of pressures should be prevented, or ameliorated where already high. In south-eastern areas, spatio-temporal coincidence of nutrient pressures and pathways should be prevented, which poses challenges to grassland management
Highly effective yet simple transmembrane anion transporters based upon ortho-phenylenediamine bis-ureas
Simple, highly fluorinated receptors are shown to function as highly effective transmembrane anion antiporters with the most active transporters rivalling the transport efficacy of natural anion transporter prodigiosin for bicarbonate
Influence of Fluid-Structure Interaction on Microcantilever Vibrations: Applications to Rheological Fluid Measurement and Chemical Detection
At the microscale, cantilever vibrations depend not only on the microstructure’s properties and geometry but also on the properties of the surrounding medium. In fact, when a microcantilever vibrates in a fluid, the fluid offers resistance to the motion of the beam. The study of the influence of the hydrodynamic force on the microcantilever’s vibrational spectrum can be used to either (1) optimize the use of microcantilevers for chemical detection in liquid media or (2) extract the mechanical properties of the fluid. The classical method for application (1) in gas is to operate the microcantilever in the dynamic transverse bending mode for chemical detection. However, the performance of microcantilevers excited in this standard out-of-plane dynamic mode drastically decreases in viscous liquid media. When immersed in liquids, in order to limit the decrease of both the resonant frequency and the quality factor, alternative vibration modes that primarily shear the fluid (rather than involving motion normal to the fluid/beam interface) have been studied and tested: these include inplane vibration modes (lateral bending mode and elongation mode). For application (2), the classical method to measure the rheological properties of fluids is to use a rheometer. To overcome the limitations of this classical method, an alternative method based on the use of silicon microcantilevers is presented. The method, which is based on the use of analytical equations for the hydrodynamic force, permits the measurement of the complex shear modulus of viscoelastic fluids over a wide frequency range
Symmetries of differential-difference dynamical systems in a two-dimensional lattice
Classification of differential-difference equation of the form
are considered
according to their Lie point symmetry groups. The set represents the
point and its six nearest neighbors in a two-dimensional triangular
lattice. It is shown that the symmetry group can be at most 12-dimensional for
abelian symmetry algebras and 13-dimensional for nonsolvable symmetry algebras.Comment: 24 pages, 1 figur
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