Modern conditions and recent environmental development of the Muskiz estuary: historical disturbance by the largest oil refinery of Spain

In 1970 the largest oil refinery in Spain was built on the Muskiz estuary and occupies most of its original surface. An integrated high-resolution microfaunal-geochemical study has revealed the evolution and environmental development of this estuary during the last 120 years, mainly by the identification and assessment of natural processes versus anthropogenic impacts. Benthic foraminifera, trace elements and PAHs data from surface sediment samples and sediment cores from the meagre remaining intertidal flat and marsh areas together with short-life radiometric isotope determinations provide a chronology for environmental changes in this estuary. Concentrations of organic and inorganic pollutant, both in modern and recent materials, are generally low and show no significative variations in space or time, except those associated to sedimentological changes in the core records. Natural processes in the middle estuary indicate the change from previous sandy, normal-salinity conditions to a muddy brackish environment around 1914. Anthropogenic impacts are not related to persistent historical pollution on this estuary but merely to the occupation of the estuary and the elimination of its different original ecosystems, so causing a general impoverishment of its environmental quality.En 1970 se construyó en la Ría de Muskiz la mayor refinería de petróleo de España ocupando la mayor parte de los dominios estuarinos originales. Este trabajo utiliza un enfoque integrado geoquímico-micropaleontológico de alta resolución con el fin de examinar la evolución estuarina y el desarrollo ambiental de esta zona costera durante los últimos 120 años, distinguiendo particularmente entre los procesos naturales e impactos antrópicos. Se analizaron foraminíferos bentónicos, elementos traza e hidrocarburo

An Assessment of Anthropogenic Impact in a Nature Reserve: the Santoña Marshes (Northern Spain)

The Santoña Marshes Nature Reserve is one of the most important ecosystems of the Spanish Cantabrian coast due to its ecological value as a wintering area for migratory birds. Since an increase in population and substantial changes in the use of land have been observed in this area during the last century, the aim of this work was to attempt to see if anthropogenic activities are recorded in the accumulating sediments. Two sediment cores (50 cm length) were collected for isotopic dating (210Pb and 137Cs) and geochemical study (heavy metals). The data indicate an increasing trend in sedimentation rates during the last century, probably related to the progressive loss of the estuarine domains and the changes in their original hydrodynamic conditions due to infilling and the construction of dykes. However, no significant anthropogenic inputs of heavy metals have been detected in recent times.La Reserva Natural de las Marismas de Santoña, situada en la costa cantábrica, posee un gran valor ecológico como lugar de invernada de aves migratorias. Dado el importante aumento de la presencia humana en la zona durante el último siglo, este trabajo tiene como objetivo estudiar si estas actividades antrópicas han dejado su huella en los sedimentos acumulados. Para ello se ha abordado la datación isotópica (137Cs y 210Pb) y el estudio geoquímico (metales pesados) de dos sondeos de 50 cm de longitud. Los resultados obtenidos señalan la existencia de un importante incremento en las tasas de sedimentación durante el ultimo siglo, posiblemente relacionado con la pérdida progresiva de la superficie y de las dinámicas estuarinas como consecuencia de los rellenos y de la construcción de diques. Sin embargo, no se han detectado niveles significativos de contaminación en metales pesados en los sedimentos más recientes

La Formación de Utrillas en el borde sur de la cuenca Vasco-Cantábrica: aspectos estratigráficos, mineralógicos y genéticos

The Utrillas formation, located in the southem border of the Basque-Cantabrian basin, is mainly composed of sandy materials deposited in a fluvial environment. Two informal units have been distinguished due to field data: a lower coarse-grained unit, interpreted as braider river channel-fills, and a upper fine-grained unit which suggests a meandering river environment. Mineralogy consists of quartz and phyllosilicates, with minor amounts of feldspars. The analysis of tourmalines has pointed two possible sources for these sediments: granitoids and low grade-metasediments. The identified clay minerals are mica and kaolinite. Texturals observations have pointed out an inherited origin for mica, while kaolinite is partly inherited and partly authigenic. This authigenic origin seems to be associated with the alteration of potassic feldspars during the stage of late diagenesis (telodiagenesis).La Formación de Utrillas, aflorante en el borde sur de la cuenca Vasco-Cantábrica, está formada por materiales mayoritariamente areniscosos depositados en un ambiente fluvial. Los datos de campo han permitido distinguir de una manera informal dos unidades: una inferior de granulometría gruesa, representativa de un relleno de canal de tipo trenzado, y una superior más fina que sugiere un entorno de río meandriforme. La mineralogía está compuesta por cuarzo y filosilicatos, con cantidades menores de feldespatos. Como mineral accesorio aparece la turmalina, cuyo análisis ha permitido identificar dos posibles fuentes para los sedimentos: granitoides y metasedimentos de bajo grado. Los minerales de la arcilla presentes son exclusivamente la mica y la caolinita. A partir de criterios texturales, se ha constatado que la mica es de origen heredado, mientras que la caolinita es en parte heredada o bien autigénica, estando asociada a la alteración de feldespato potásico en una etapa de diagénesis tardía (telodiagénesis)

Waste management under a life cycle approach as a tool for a circular economy in the canned anchovy industry

The anchovy canning industry has high importance in the Cantabria Region (North Spain) from economic, social and touristic points of view. The Cantabrian canned anchovy is world-renowned owing to its handmade and traditional manufacture. The canning process generates huge amounts of several food wastes, whose suitable management can contribute to benefits for both the environment and the economy, closing the loop of the product life cycle. Life cycle assessment methodology was used in this work to assess the environmental performance of two waste management alternatives: Head and spine valorisation to produce fishmeal and fish oil; and anchovy meat valorisation to produce anchovy paste. Fuel oil production has been a hotspot of the valorisation of heads and spines, so several improvements should be applied. With respect to anchovy meat valorisation, the production of polypropylene and glass for packaging was the least environmentally friendly aspect of the process. Furthermore, the environmental characterisation of anchovy waste valorisation was compared with incineration and landfilling alternatives. In both cases, the valorisation management options were the best owing to the avoided burdens associated with the processes. Therefore, it is possible to contribute to the circular economy in the Cantabrian canned anchovy industry.The authors disclosed receipt of the following financial support for the research, authorship, and/or publication of this article: This work was supported by the Ministry of Economy and Competitiveness of Spanish Government through the project called GeSACConserva: Sustainable Management of the Cantabrian Anchovies [CTM2013-43539-R]

In silico evaluation of ultrafiltration and nanofiltration membrane cascades for continuous fractionation of protein hydrolysate from tuna processing byproduct

The present work proposes the design of cascades that integrate ultrafiltration (UF) and nanofiltration (NF) membranes to separate the different protein fractions from the protein hydrolysate obtained after hydrolysis of tuna byproducts. Experimental data (permeate flux and rejection of protein fractions under different applied pressures) previously obtained and published by this research group were fitted to empirical models, which were the basis for a process simulation model. High recovery rates (0.9) in the UF stages implied high process yields by reduced desired fraction losses, while similar recovery rates in the NF stages were required for high product purity. However, the applied pressures were not so influential over the performance of the system. Optimization problems were solved to identify the optimal design and operation conditions to maximize the product purity or the process yield. Maximal purity of the preferred 1-4 kDa fraction (49.3% from 19.0% in feed stream) obtained by the configuration with 3 UF stages and another 3 NF stages implied 2 and 5 bar pressures applied in the UF and NF stages, respectively, while 0.9 was the optimal recovery rate value for all the stages. These maximal purity conditions resulted in 62.6% process yield, defined as the percentage of the 1-4 kDa fraction in the feed stream recovered in the product stream. In addition, multiobjective optimization of the process was also carried out to obtain the Pareto graphs that represent the counterbalance between maximal yields and purities

Recent sediments dating using short-lived radionuclides

Se presentan las características principales del método de datación de sedimentos recientes mediante el radioisótopo natural ²¹⁰Pb y su validación utilizando radionucleidos artificiales tales como ¹³⁷Cs y ²³⁹,²⁴⁰Pu. Se hace una revisión de los principios generales de esta metodología, se aportan recomendaciones prácticas para la recogida de testigos sedimentarios en el campo y su posterior procesamiento en el laboratorio, se describen diferentes técnicas analíticas utilizadas en la determinación de sus concentraciones y se explican brevemente varios modelos para la interpretación de los perfiles obtenidos. Por último, se incluyen ejemplos prácticos de su aplicación en secuencias sedimentarias procedentes de distintos ambientes marinos (estuario, bahía y plataforma continental) en el norte de la Península Ibérica.The main characteristics of the dating method of recent sediments using the natural radioisotope ²¹⁰Pb and its validation with artificial radionuclides such as ¹³⁷Cs and ²³⁹,²⁴⁰Pu are presented. A review of the general principles of this methodology is made, practical recommendations for the collection of sedimentary cores in the field and their subsequent processing in the laboratory are provided, several analytical techniques used to measure their concentrations are described and several models for the interpretation of the profiles are briefly explained. Finally, practical examples of its application in sedimentary sequences from different marine environments (estuary, bay and continental shelf) in the northern Iberian Peninsula are also included.Agradecimientos: Este artículo se ha inspirado en el manual de referencia publicado por Sanchez-Cabeza, J.A., Díaz-Asencio, M., Ruiz-Fernández, A.C., eds. (2012). Radiocronología de sedimentos costeros utilizando 210Pb: Modelos, Validación y Aplicaciones. Organismo Internacional de Energía Atómica, Viena, 105 pp., donde se profundizan diferentes aspectos tratados aquí. Trabajo financiado por los proyectos RTI2018-095678-B-C21, MCIU/AEI/FEDER, UE (MINECO) e IT976-16 (EJ/GV). Dos revisoras/es anónimas/os mejoraron el manuscrito original con sus comentarios y sugerencias. Contribución nº 56 de la Unidad de Investigación Geo-Q Zentroa (Laboratorio Joaquín Gómez de Llarena)

Connecting wastes to resources for clean technologies in the chlor-alkali industry: a life cycle approach

Our current economic model is experiencing increasing demand and increasing pressure on resource utilisation, as valuable materials are lost as waste. Moving towards a circular economy and supporting efficient resource utilisation is essential for protecting the environment. The chlor-alkali industry is one of the largest consumers of salt, and efforts have been made to reduce its electricity use. Furthermore, KCl mining wastes have received increasing attention because they can be transformed into value-added resources. This work studies the influence of using different salt sources on the environmental sustainability of the chlor-alkali industry to identify further improvement opportunities. Rock salt, solar salt, KCl waste salt, vacuum salt and solution-mined salt were studied. Membrane cells in both bipolar and monopolar configurations were studied and compared to the emergent oxygen-depolarised cathode (ODC) technology. Life cycle assessment was applied to estimate the cradle-to-gate environmental impacts. The natural resource (NR) requirements and the environmental burdens (EBs) to the air and water environments were assessed. The total NR and EB requirements were reduced by 20% when vacuum salt was replaced with KCl. Moreover, the environmental impacts estimated for the monopolar membrane using KCl were comparable to those generated for the bipolar membrane using VS. The difference between the monopolar and bipolar scenarios (17%) was slightly higher than that between the bipolar and ODC technologies (12%). This work demonstrates the importance of studying every life cycle stage in a chemical process and the environmental benefit of applying a circular economy, even in energy intensive industries such as the chlor-alkali industry.This work was funded by the Spanish Ministry of Economy and Competitiveness (MINECO), Project CTM2013-43539-R. The authors are grateful for this funding

Energy-water-food nexus in the Spanish greenhouse tomato production

The nexus energy–water–food of the tomato greenhouse production in the Almeria region (Spain) has been studied following a Process Systems Analysis Method connecting the ecosystem services to the market demands with a holistic view based on Life Cycle Assessment. The management of the agri-food subsystem, the industrial subsystem and the urban subsystem plays an important role in the nexus of the E–W–F system, where transport and information technologies connect the three subsystems to the global markets. The local case study of the tomato production in Almeria (Spain) has been developed as an example of the food production under cropland restrictions, semiarid land. After study of the economic and social sustainability in time, the evolution of the ecosystem services supply is the main restriction of the system, where after the land use change in the region, water and energy supply play the mean role with a trade-off between the water quality degradation and the economic cost of the energy for water desalination. Water footprint, Carbon footprint and Chemicals footprint are useful indicators to the environmental sustainability assessment of local alternatives in the E–W–F system under study. As it is shown in the conclusions, the holistic view based on the process analysis method and the life cycle assessment methodology and indicators is an useful tool for decision support

Estimation of PM10-bound As, Cd, Ni and Pb levels by means of statistical modelling: PLSR and ANN approaches

Air quality assessment regarding metals and metalloids using experimental measurements is expensive and time consuming due to the cost and time required for the analytical determination of the levels of these pollutants. According to the European Union (EU) Air Quality Framework Directive (Directive 2008/50/EC), other alternatives, such as objective estimation techniques, can be considered for ambient air quality assessment in zones and agglomerations where the level of pollutants is below a certain concentration value known as the lower assessment threshold. These conditions occur in urban areas in Cantabria (northern Spain). This work aims to estimate the levels of As, Cd, Ni and Pb in airborne PM10 at two urban sites in the Cantabria region (Castro Urdiales and Reinosa) using statistical models as objective estimation techniques. These models were developed based on three different approaches: partial least squares regression (PLSR), artificial neural networks (ANNs) and an alternative approach consisting of principal component analysis (PCA) coupled with ANNs (PCA-ANN). Additionally, these models were externally validated using previously unseen data. The results show that the models developed in this work based on PLSR and ANNs fulfil the EU uncertainty requirements for objective estimation techniques and provide an acceptable estimation of the mean values. As a consequence, they could be considered as an alternative to experimental measurements for air quality assessment regarding the aforementioned pollutants in the study areas while saving time and resources.The authors gratefully acknowledge the financial support from the Spanish Ministry of Economy and Competitiveness through the Project CMT2010-16068. The authors also thank the Regional Environment Ministry of the Cantabria Government for providing the PM10 samples at the Castro Urdiales and Reinosa sites