Flooding-Induced Mobilization of Potentially Toxic Trace Elements from Uncontaminated, Calcareous, Agricultural Soils

Enhanced mobilization of potentially toxic trace elements (PTTE) is well documented for contaminated floodplains, wetlands and rice paddies. Limited information is available on flooding-induced PTTE release from uncontaminated, agricultural soils from temperate regions. We conducted an incubation study with simulated flooding using calcareous, uncontaminated agricultural soils to assess the release dynamics of a few PTTE and identify the controlling factors. Packed soils were flooded, and soil Eh, pH, total dissolved metals and S concentrations in pore water and floodwater were measured for eight weeks. Pore water arsenic (As) and nickel (Ni) concentrations were initially low, but significantly increased with flooding by 12- and 6-fold, respectively. Copper (Cu) concentration declined with flooding, while zinc (Zn) showed no consistent trend. Arsenic and Ni concentrations correlated negatively with Eh, and positively with other redox-sensitive elements, while Cu behaved in a manner opposite to that of As and Ni; however, correlating positively with S. Pore water Zn correlated negatively with pH and Ca, and positively with Al. Principal component analysis confirmed the role of Eh on As, Ni and Cu release from flooded soils and the pH dependency on Zn release. Prolonged flooding released environmentally significant quantities of some PTTE from uncontaminated, agricultural soils.The accepted manuscript in pdf format is listed with the files at the bottom of this page. The presentation of the authors' names and (or) special characters in the title of the manuscript may differ slightly between what is listed on this page and what is listed in the pdf file of the accepted manuscript; that in the pdf file of the accepted manuscript is what was submitted by the author

Cattle manure loadings and legacy effects on Cu and Zn availability under rainfed and irrigated conditions

Long term cattle manure applications build up nutrient pools and can lead to trace element enrichments in soils. The objectives of this study were to evaluate Cu and Zn loadings in the soil during continuous annual cattle manure applications and determine the time required for soil to return to its pre-manure available Cu and Zn levels after manure is discontinued. The manure application rates were 0, 30, 60, and 90 Mg ha-1 for rainfed and 0, 60, 120, and 180 Mg ha-1 (wet weight) for irrigated plots. While manure was applied for 45 years in some plots, applications were terminated in one subset of treatments after 14 years and in another subset after 30 years to study legacy effects after 31 and 15 years, respectively. Soil samples were collected in the fall of 2003, 2008, 2013, and 2018 and analyzed for available Cu and Zn. Crops were grown in all years continuously with Cu and Zn concentrations measured in both silage and grains harvested. The regression model developed using data collected suggests long legacy effects with recovery time to pre-manure levels ranging from 10-20 years for Cu and 23-41 years for Zn at irrigated and 10-24 for Cu and 21-32 years for Zn under rainfed, respectively. Long term applications of cattle manure could lead to accumulation of Cu and Zn, creating long-lasting legacy effects in soils with the increased environmental risk of leaching to groundwaterThe accepted manuscript in pdf format is listed with the files at the bottom of this page. The presentation of the authors' names and (or) special characters in the title of the manuscript may differ slightly between what is listed on this page and what is listed in the pdf file of the accepted manuscript; that in the pdf file of the accepted manuscript is what was submitted by the author

Fertilizer-induced phosphorus dynamics in alkaline-calcareous soils as influenced by soil chemical properties

For proper fertility management, the influence of soil properties on phosphorus (P) dynamics with fertilizer application should be better understood. We examined the influence of soil chemical properties on P dynamics with the application of monoammonium phosphate (MAP) to alkaline-calcareous soils from Manitoba. Non-fertilized and MAP-fertilized soils (at 30 and 60 kg P haThe accepted manuscript in pdf format is listed with the files at the bottom of this page. The presentation of the authors' names and (or) special characters in the title of the manuscript may differ slightly between what is listed on this page and what is listed in the pdf file of the accepted manuscript; that in the pdf file of the accepted manuscript is what was submitted by the author

Nano-oxides immobilize Cd, Pb, and Zn in mine spoils and contaminated soils facilitating plant growth

Nanoparticles with high reactivity can be applied as amendments to remediate soil metal contaminations by immobilizing toxic elements. Nano-oxides of Fe have been studied but Al and Ti nano-oxides have not been tested for their remediation capacity of toxic metals. The potential of synthesized iron (Fe-O), aluminum (Al-O), and titanium (Ti-O) nano-oxides for stabilizing Cd, Pb, and Zn in mine spoil (Chat) and contaminated soil was compared using adsorption studies and a greenhouse experiment. Chat and soil were amended with nano oxides at two rates (25 and 50 g kg-1) and a pot experiment was conducted with sorghum (Sorghum bicolor L. Moench). Leachates were collected twice per week from plant emergence to harvest at maturity and metals were compared against an unamended control. Chat was contaminated with Cd, Pb, and Zn at 84, 1583, and 6154 mg kg-1, and soil at 15, 1260, and 3082 mg kg-1, respectively. Adsorption conformed to the Langmuir linear isotherm and adsorption maxima of metals were in the order of Al-O > Ti-O ≥ Fe-O. Nano-oxides reduced Cd concentration by 28% (Fe-O) to 87% (Ti-O) and Zn concentration by 14% (Fe-O) to 85% (Al-O) in plant tissues compared with unamended Chat. Nano-oxides significantly reduced Cd, Pb, and Zn in leachates and available Cd and Zn in Chat/ soil relative to the respective unamended controls. Nano-oxides can be used to remediate heavy metal contaminated Chat and soil and facilitate plant growth under proper nutrient supplements. Nano-oxides of Al-O and Ti-O remediated metals more effectively than Fe-OThe accepted manuscript in pdf format is listed with the files at the bottom of this page. The presentation of the authors' names and (or) special characters in the title of the manuscript may differ slightly between what is listed on this page and what is listed in the pdf file of the accepted manuscript; that in the pdf file of the accepted manuscript is what was submitted by the author

A laboratory assay of in-situ stabilization of toxic metals in contaminated boreal forest soil using organic and inorganic amendments

Metal-contaminated soils present a great threat to natural ecosystems and human health. Remediation studies focusing on metal-polluted soils with high organic matter (OM > 20%) are limited. This study evaluated the effectiveness of biochar, compost, diammonium phosphate (DAP), and iron oxides (Fe-O), in immobilizing metals from an OM-rich boreal forest soil contaminated with arsenic (As), cadmium (Cd), copper (Cu), lead (Pb), and zinc (Zn). A laboratory incubation study was conducted with soil amended with biochar (5% w w−1), compost (5% w w−1), DAP (0.2% w w−1), or Fe-O (0.2% w w−1), and a control (without amendment) for 6 months at field capacity moisture content. Metal concentrations were determined in pore water collected at 0, 2, 4, and 6 months after incubation. Soil was extracted sequentially for metals after the incubation period. Metal concentrations in pore water were significantly reduced by different amendments as follows: As by biochar and Fe-O, Cd by biochar, compost, and DAP, Cu by biochar, Pb by compost and DAP, and Zn by biochar and compost. Sequential extractions revealed biochar and (or) compost transferred Cd, Cu, Pb, and Zn from the labile pool to the non-labile pool confirming their effectiveness as amendments for remediation of metal-contaminated OM-rich boreal forest soil.The accepted manuscript in pdf format is listed with the files at the bottom of this page. The presentation of the authors' names and (or) special characters in the title of the manuscript may differ slightly between what is listed on this page and what is listed in the pdf file of the accepted manuscript; that in the pdf file of the accepted manuscript is what was submitted by the author

Woodchip biochar with or without synthetic fertilizers affects soil properties and available phosphorus in two alkaline, Chernozemic soils

Fertility enhancement with biochar application is well documented for tropical acidic soils; however, benefits of biochar co-applied with synthetic fertilizers on soil fertility are not well documented, particularly for alkaline chernozems. We examined the short-term interactive effects of woodchip biochar amendment with fertilizers on selected soil properties, available phosphorus (P) and P fractions of two alkaline Chernozems from Manitoba. Treatments were (1) urea and monoammonium phosphate fertilizers, (2) biochar at 10 g kgThe accepted manuscript in pdf format is listed with the files at the bottom of this page. The presentation of the authors' names and (or) special characters in the title of the manuscript may differ slightly between what is listed on this page and what is listed in the pdf file of the accepted manuscript; that in the pdf file of the accepted manuscript is what was submitted by the author