1,008 research outputs found

    Electromagnetic field in matter. Surface enhanced Raman scattering

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    The polarization and magnetization degrees of freedom are included in the general treatment of the electromagnetic field in matter, and their governing equations are given. Particular cases of solutions are discussed for polarizable, non-magnetic matter, including quasi-static fields, surface plasmons, propagation, zero-point fluctuations of the eigenmodes, especially for a semi-infinite homogeneous body (half-space). The van der Waals London-Casimir force acting between a neutral nano-particle and a half-space is computed and the response of this electromagnetically coupled system to an external field is given, with relevance for the surface enhanced Raman scattering

    Force and energy dissipation variations in non-contact atomic force spectroscopy on composite carbon nanotube systems

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    UHV dynamic force and energy dissipation spectroscopy in non-contact atomic force microscopy were used to probe specific interactions with composite systems formed by encapsulating inorganic compounds inside single-walled carbon nanotubes. It is found that forces due to nano-scale van der Waals interaction can be made to decrease by combining an Ag core and a carbon nanotube shell in the Ag@SWNT system. This specific behaviour was attributed to a significantly different effective dielectric function compared to the individual constituents, evaluated using a simple core-shell optical model. Energy dissipation measurements showed that by filling dissipation increases, explained here by softening of C-C bonds resulting in a more deformable nanotube cage. Thus, filled and unfilled nanotubes can be discriminated based on force and dissipation measurements. These findings have two different implications for potential applications: tuning the effective optical properties and tuning the interaction force for molecular absorption by appropriately choosing the filling with respect to the nanotube.Comment: 22 pages, 6 figure

    Evaluation of phenotypic diversity in Anacamptis coriophora (Orchidaceae) populations from South Romania

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    Romanian flora includes a high diversity of orchids, any with a high conservationist interest, but many 0f themnot yet sufficiently investigated from an ecological, phytosociological or genetic point of view. Phenotypically analysis is also scarce and only a few data have been published in relation to the effects of site factors on the morphological and anatomical characteristics of the family Orchidaceae. This study analyses the variability of two populations of Anacamptis coriophora, based on their coenological affiliations, morphological observations and biometrical measurements. The data were collected from two grassland areas in Romania Stoenesti, VĂąlcea County and Cobia, DĂąmbovița County. The results showed that both populations are influenced by temperature, light and humidity and develop normally under optimal conditions. In the most favorable conditions encountered in VĂąlcea county, orchids offer the splendor of flowers for a long time. Orchids in our country usually bloom in March, sometimes lasting until August, they have a delicate appearance, varied colors and the most diverse perfumes. The information obtained regarding the morphological diversity of the two populations could be suitable for designing strategies for their conservation in both locations

    Seeds for effective oligonucleotide design

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    Background: DNA oligonucleotides are a very useful tool in biology. The best algorithms for designing good DNA oligonucleotides are filtering out unsuitable regions using a seeding approach. Determining the quality of the seeds is crucial for the performance of these algorithms.\ud Results: We present a sound framework for evaluating the quality of seeds for oligonucleotide design. The F-score is used to measure the accuracy of each seed. A number of natural candidates are tested: contiguous (BLAST-like), spaced, transitions-constrained, and multiple spaced seeds. Multiple spaced seeds are the best, with more seeds providing better accuracy. Single spaced and transition seeds are very close whereas, as expected, contiguous seeds come last. Increased accuracy comes at the price of reduced efficiency. An exception is that single spaced and transitions-constrained seeds are both more accurate and more efficient than contiguous ones.\ud Conclusions: Our work confirms another application where multiple spaced seeds perform the best. It will be useful in improving the algorithms for oligonucleotide desig

    Testing the magnetotail configuration based on observations of low‐altitude isotropic boundaries during quiet times

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    We investigate the configuration of the geomagnetic field on the nightside magnetosphere during a quiet time interval based on National Oceanic and Atmospheric Administration Polar Orbiting Environment Satellites Medium Energy Proton and Electron Detector (NOAA/POES MEPED) measurements in combination with numerical simulations of the global terrestrial magnetosphere using the Space Weather Modeling Framework. Measurements from the NOAA/POES MEPED low‐altitude data sets provide the locations of isotropic boundaries; those are used to extract information regarding the field structure in the source regions in the magnetosphere. In order to evaluate adiabaticity and mapping accuracy, which is mainly controlled by the ratio between the radius of curvature and the particle’s Larmor radius, we tested the threshold condition for strong pitch angle scattering based on the MHD magnetic field solution. The magnetic field configuration is represented by the model with high accuracy, as suggested by the high correlation coefficients and very low normalized root‐mean‐square errors between the observed and the modeled magnetic field. The scattering criterion, based on the values of k=Rcρ ratio at the crossings of magnetic field lines, associated with isotropic boundaries, with the minimum B surface, predicts a critical value of kCR∌33. This means that, in the absence of other scattering mechanisms, the strong pitch angle scattering takes place whenever the Larmor radius is ∌33 times smaller than the radius of curvature of the magnetic field, as predicted by the Space Weather Modeling Framework.Key PointsWe tested the threshold condition for strong pitch angle scattering based on the MHD magnetic fieldSWMF model suggests a threshold condition for strong pitch angle scattering of k = 33For quiet time, the k parameter varies within 2 orders of magnitudePeer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/135070/1/jgra52310.pdfhttp://deepblue.lib.umich.edu/bitstream/2027.42/135070/2/jgra52310_am.pd

    Thermomechanical and Microstructural Analysis of the Influence of B- and Ti-Content on the Hot Ductility Behavior of Microalloyed Steels

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    The effects of the combined addition of B and Ti, as well as the influence of different strain rates on the hot ductility behavior of low carbon, continuously cast, microalloyed steels were investigated in this work. Tensile tests, microstructure analyses, and thermokinetic simulations were performed with in situ melted samples. Furthermore, prior austenite grain evaluations were carried out for the two different microalloyed steels. Increasing the strain rate brought improvements to the ductility, which was more significant in the steel with the leanest composition. The steel containing more B and Ti presented a better hot ductility behavior under all conditions tested. The main causes for the improvements rely on the precipitation behavior and the austenite–ferrite phase transformation. The preferential formation of TiN instead of fine BN and AlN was seen to be beneficial to the ductility, as well as the absence of MnS. Grain boundary segregation of free B that did not form BN retarded the ferrite formation, avoiding the brittleness brought by the thin ferrite films at the austenite grain boundaries. Furthermore, it was revealed that for the steels in question, the prior austenite grains have less influence on the hot ductility behavior than the precipitates and ferrite formation

    On Maximal Unbordered Factors

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    Given a string SS of length nn, its maximal unbordered factor is the longest factor which does not have a border. In this work we investigate the relationship between nn and the length of the maximal unbordered factor of SS. We prove that for the alphabet of size σ≄5\sigma \ge 5 the expected length of the maximal unbordered factor of a string of length~nn is at least 0.99n0.99 n (for sufficiently large values of nn). As an application of this result, we propose a new algorithm for computing the maximal unbordered factor of a string.Comment: Accepted to the 26th Annual Symposium on Combinatorial Pattern Matching (CPM 2015
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