Numerical modelling of air pollutant dispersion in complex urban areas: investigation of city parts from downtowns Hanover and Frankfurt

Hazardous gas dispersion within a complex urban environment in 1:1 scaled geometry of German cities, Hanover and Frankfurt, is predicted using an advanced turbulence model. The investigation involves a large group of real buildings with a high level of details. For this purpose, Computer Aided Design (CAD) of two configurations are cleaned, then fine grids meshed in. Weather conditions are introduced using power law velocity profiles at inlets boundary. The investigation focused on the effects of release locations and material properties of the contaminants (e.g., densities) on the convection/diffusion of pollutants within complex urban area. Two geometries demonstrating different topologies and boundaries conditions are investigated. Pollutants are introduced into the computational domain through chimney and/or pipe leakages in various locations. Simulations are carried out using Large Eddy Simulation (LES) turbulence model and species transport for the pollutants. The weather conditions are accounted for using a logarithmic velocity profile at inlets. CH₄ and CO₂ distributions, as well as turbulence quantities and velocity profiles, show important influences on the dispersion behavior of the hazardous gas

Numerical Modelling of Air Pollutant Dispersion in Complex Urban Areas: Investigation of City Parts from Downtowns Hanover and Frankfurt

Hazardous gas dispersion within a complex urban environment in 1:1 scaled geometry of German cities, Hanover and Frankfurt, is predicted using an advanced turbulence model. The investigation involves a large group of real buildings with a high level of details. For this purpose, Computer Aided Design (CAD) of two configurations are cleaned, then fine grids meshed in. Weather conditions are introduced using power law velocity profiles at inlets boundary. The investigation focused on the effects of release locations and material properties of the contaminants (e.g., densities) on the convection/diffusion of pollutants within complex urban area. Two geometries demonstrating different topologies and boundaries conditions are investigated. Pollutants are introduced into the computational domain through chimney and/or pipe leakages in various locations. Simulations are carried out using Large Eddy Simulation (LES) turbulence model and species transport for the pollutants. The weather conditions are accounted for using a logarithmic velocity profile at inlets. CH₄ and CO₂ distributions, as well as turbulence quantities and velocity profiles, show important influences on the dispersion behavior of the hazardous gas

COMPARATIVE STUDY OF ORGANIC MATTER DEGRADATION OF COMPOSTED SLUDGE AND SLUDGE LANDFILLED / ETUDE COMPARATIVE DE LA DEGRADATION DE LA MATIERE ORGANIQUE DES BOUES COMPOSTEES ET BOUES MISES EN DECHARGE

The results of the biotransformation of organic matter for three trials A (500 kg sludge + 400 kg turf + 100 kg of straw), B (1000 kg sludge composted alone), and C (1000 kg sludge landfilled) after six months show a good degradation rate for trial A, compared to B, and C. C/N ratio decrease from 30 to 12 for mixture A, from 32 to 19 for B, and from 32 to 24 for C. An important decomposition rate, about 74 %, for mixture A has been reached after six months. The final compost for mixture A exhibited a high concentration (151.7 g·kg-1) of humic substance and a low concentration of heavy metal contents, compared to the AFNOR standard (NF U 44-041). The efficiency of the composting is confirmed by the germination index (GI), which exceeds 90 % for the trial A. However, phytotoxicity for trials B and C remains less important (GI does not exceed 40 %). The results of trial A will open the way for the agricultural use of sludge

MONITORING OF ORGANIC POLLUTION AND MATURITY OF ORGANIC MATTER FROM SLUDGE LANDFILLING

The biotransformation during the 3 years of sludge landfilling was evaluated by physicochemical analysis and phytotoxicity test. The final product exhibited a high degree of decomposition rate (51.06 %) than the controls as shown by a decrease of C/N ratio of about 19.67. The results showed that the lipid, surfactant and polyphenol as main compound of the sludge were breakdown over time. The concentrations decreased from 29.9 to 11.8 mg·g-1 and 3.4 to 0.6 mg·g-1, respectively for surfactant and polyphenols after 3 years of landfilling. This corresponds to a reduction of 80.2 % for polyphenols and 60.4 % for surfactant, due to the microorganisms activity. Total lipids decrease from 16.5 to 6.27 mg·g-1 of dry matter, representing an abatement rate of about 62 %. The evolution of organic matter reflects the progress of the humification process, which judging by the increase in the polymerization degree, is about 20 %. The landfilling efficiency to reduce phytotoxicity of sludge was confirmed by the germination index, which reached 52 and 59 %, respectively for alfalfa and cress after 3 years of landfilling. These results are promising and pave the way for agricultural spreading of sludge

Impact of Spray Cone Angle on the Performances of Methane/Diesel RCCI Engine Combustion under Low Load Operating Conditions

The behaviors of spray, in Reactivity Controlled Combustion Ignition (RCCI) dual fuel engine and subsequent emissions formation, are numerically addressed. Five spray cone angles ranging between 5° and 25° with an advanced injection timing of 22° Before Top Dead Center (BTDC) are considered. The objective of this paper is twofold: (a) to enhance engine behaviors in terms of performances and consequent emissions by adjusting spray cone angle and (b) to outcome the exergy efficiency for each case. The simulations are conducted using the Ansys-forte tool. The turbulence model is the Renormalization Group (RNG) K-epsilon, which is selected for its effectiveness in strongly sheared flows. The spray breakup is governed by the hybrid model Kelvin–Helmholtz and Rayleigh–Taylor spray models. A surrogate of n-heptane, which contains 425 species and 3128 reactions, is used for diesel combustion modeling. The obtained results for methane/diesel engine combustion, under low load operating conditions, include the distribution of heat transfer flux, pressure, temperature, Heat Release Rate (HRR), and Sauter Mean Diameter (SMD). An exergy balance analysis is conducted to quantify the engine performances. Output emissions at the outlet of the combustion chamber are also monitored in this work. Investigations show a pressure decrease for a cone angle θ = 5° of roughly 8%, compared to experimental measurement (θ = 10°). A broader cone angle produces a higher mass of NOx. The optimum spray cone angle, in terms of exergy efficiency, performance, and consequent emissions is found to lie at 15° ≤ θ ≤ 20°

Impact of Spray Cone Angle on the Performances of Methane/Diesel RCCI Engine Combustion under Low Load Operating Conditions

The behaviors of spray, in Reactivity Controlled Combustion Ignition (RCCI) dual fuel engine and subsequent emissions formation, are numerically addressed. Five spray cone angles ranging between 5° and 25° with an advanced injection timing of 22° Before Top Dead Center (BTDC) are considered. The objective of this paper is twofold: (a) to enhance engine behaviors in terms of performances and consequent emissions by adjusting spray cone angle and (b) to outcome the exergy efficiency for each case. The simulations are conducted using the Ansys-forte tool. The turbulence model is the Renormalization Group (RNG) K-epsilon, which is selected for its effectiveness in strongly sheared flows. The spray breakup is governed by the hybrid model Kelvin–Helmholtz and Rayleigh–Taylor spray models. A surrogate of n-heptane, which contains 425 species and 3128 reactions, is used for diesel combustion modeling. The obtained results for methane/diesel engine combustion, under low load operating conditions, include the distribution of heat transfer flux, pressure, temperature, Heat Release Rate (HRR), and Sauter Mean Diameter (SMD). An exergy balance analysis is conducted to quantify the engine performances. Output emissions at the outlet of the combustion chamber are also monitored in this work. Investigations show a pressure decrease for a cone angle θ = 5° of roughly 8%, compared to experimental measurement (θ = 10°). A broader cone angle produces a higher mass of NOₓ. The optimum spray cone angle, in terms of exergy efficiency, performance, and consequent emissions is found to lie at 15° ≤ θ ≤ 20°

Recent advances in the treatment of wastewater contaminated with pharmaceutical pollutants: a critical review

Over the last decade, the pharmaceutical industry has driven considerable development, raising the standard of living and health care in Morocco and the world. However, humanity has seen an explosion of industrialization throughout the health sector as the population has grown. This growth leads to the generation of substantial waste, such as pharmaceuticals and personal care products. These discharges pose severe problems for the environment. This situation requires efforts to treat this waste. Extensive research has resulted in the development of various methods to minimize or completely detoxify the debris, including physical and chemical methods. Wastewater treatment plants can use physical and chemical processes alone or in combination. Since both types of technologies have inflated costs and require enormous amounts of energy, chemicals, and the disposal of the sludge produced by the processes, interest has turned to combined technologies because they are less expensive and the resulting end products are less toxic. Therefore, in the above context, this review discusses various treatment strategies that have been developed to achieve the goals of a clean environment. The work analyzes the different physicochemical treatment techniques for pharmaceutical wastewater to find the least expensive and most effective techniques for eliminating emerging contaminants. This study examines the different techniques for treating pollutant-laden discharges, such as coagulation–flocculation, membrane filtration, advanced oxidation, adsorption, flotation, and hybrid treatments combining physicochemical and biological processes