Bis(2-benzamido­benzimidazolato-κ2 N 1,O)(N,N-dimethyl­formamide-κO)copper(II)

In the title compound, [Cu(C14H10N3O)2(C3H7NO)], the CuII atom is five-coordinated by two N,O-bidentate 2-benzamido­benzimidazolate anions and one O-coordinated dimethyl­formamide (DMF) mol­ecule, resulting in a distorted square-based pyramidal CuN2O3 geometry for the metal atom, with the DMF O atom at the apical site. In the crystal structure, inter­molecular N—H⋯N hydrogen bonds result in chains of mol­ecules propagating along [100]

1,2-Bis(N′-benzoyl­thio­ureido)benzene

The title compound, C22H18N4O2S2, was characterized by 1H and 13C NMR, solid-state IR spectroscopy and X-ray crystallographic techniques. The crystal structure determination reveals that the twisting modes of the two side arms are different [C—N—C—O and C—N—C—N torsion angles = −1.2 (3) and 1.1 (3)°, respectively, in one arm and 24.1 (3) and −5.1 (3)°, respectively, in the other]. The crystal structure involves N—H⋯O and N—H⋯S hydrogen bonds

Bis(2-{[2-(2-hy­droxy­benzyl­amino)­eth­yl]amino­meth­yl}phenolato-κ3 N,N′,O 1)cobalt(III) nitrate monohydrate

In the title compound, [Co(C16H19N2O2)2]NO3·H2O, the CoIII ion is located on an inversion center and is six-coordinated by two phenolate O atoms and four amino N atoms from two diamine ligands, forming an octa­hedral geometry. The water mol­ecule and the nitrate anion are located close to an inversion center, and are thus equally disordered by symmetry. The crystal packing is stabilized by inter­molecular O—H⋯O hydrogen bonds involving the uncoordinated water mol­ecule and the free phenol hydroxyl group with the nitrate anion. N—H⋯O hydrogen bonds involving the amino groups and the nitrate anions connect the complex mol­ecules along the c axis

Bis(N,N′-dimethyl­ethylenediammonium) tris­(oxalato-κ2 O 1,O 2)cobaltate(II) dihydrate: an ion-pair complex

The CoII ion in the title complex, (C4H14N2)2[Co(C2O4)3]·2H2O, is coordinated by three oxalate ions, resulting in a distorted octa­hedral geometry. Two uncoordinated water mol­ecules are present in asymmetric unit. Inter­molecular N—H⋯O and O—H⋯O hydrogen bonds between the different entities stabilize the crystal structure

Bis{2-amino-2-oxo-N-[(1E)-1-(pyridin-2-yl-κN)ethyl­idene]acetohydrazidato-κ2 N′,O 1}nickel(II)

In the title compound, [Ni(C9H9N4O2)2], the NiII ion is situated on a twofold rotation axis and is coordinated by two O and four N atoms from two tridentate {2-amino-2-oxo-N-[(1E)-1-(pyridin-2-yl-κN)ethyl­idene]acetohydrazidate ligands in a distorted octa­hedral geometry. In the crystal, N—H⋯O and N—H⋯N hydrogen bonds link the mol­ecules into columns in [001]. The porous crystal packing is further stabilized via π–π inter­actions between the pyridine rings of neighbouring mol­ecules [centroid–centroid distance = 3.746 (3) Å] with voids of 270 Å3

Bis(benzohydrazide-κ2 O,N′)bis­(nitrato-κO)copper(II)

In the title compound, [Cu(NO3)2(C7H8N2O)2], the CuII atom is located on a centre of inversion, and is coordinated by two bidentate benzohydrazide ligands and two monodentate nitrate anions in an axially distorted octa­hedral geometry within an N2O4 donor set. The crystal structure is stabilized by N—H⋯O and weak N—H⋯N hydrogen bonds

Dichlorido[2-(pyridin-2-yl)-N-(pyridin-2-ylmethylidene)ethanamine-κ3N,N′,N′′]manganese(II) monohydrate

In the title complex, [MnCl2(C13H13N3)]·H2O, the MnII atom is in a distorted square-pyramidal environment, with an Addison τ parameter of 0.037. The coordination geometry is defined by three N-atom donors from the tridentate 2-(pyridin-2-yl)-N-(pyridin-2-ylmethylidene)ethanamine ligand and two terminal Cl atoms. Although the H atoms of the lattice water molecule were not located, O...O distances of 3.103 (7) Å and O...Cl distances of 3.240 (3) and 3.482 (4) Å suggest that hydrogen bonding is responsible for the stabilization of the crystal packing

(S,E)-3-[(2-Hydroxybenzylidene)amino]-2-(2-hydroxyphenyl)-2,3-dihydroquinazolin-4(1H)-one

In the title compound, C21H17N3O3, the dihydroquinazoline ring adopts a screw-boat conformation and its stereogenic C atom has an S configuration. The dihedral angle between the mean planes of the two hydroxyphenyl rings is 86.61 (12)°. The amino H atom forms an intramolecular hydrogen bond with a phenol O atom, while the hydrazine N atom acts as an acceptor for the H atom of the other phenol group. In the crystal, O—H...N and O—H...O hydrogen bonds and weak C—H...centroid(π-ring) intermolecular interactions are observed, forming chains along [1-10] and [110]

{1-[1-(2-Hydroxyphenyl)ethylidene]-2-(pyridin-2-yl-κN)hydrazine-κ2N′,O}{1-[1-(2-oxidophenyl)ethylidene]-2-(pyridin-2-yl-κN)hydrazine-κ2N′,O}nickelate(II) nitrate hemihydrate

The 2-hydrazinopyridine precursor has been widely used to prepare ligands of various kinds by condensation with carbonyl compounds. These types of ligands are suitable for synthesizing novel transition metal (II) complexes with interesting magnetic properties. In this context we have synthesized the ligand 1-(2-hydroxyphenyl-2-ethylidene)-2-(pyridin-2-yl)hydrazine (HL) which was used in the preparation of the mononuclear title complex, [Ni(C13H12N3O)(C13H13N3O)]NO3·0.5H2O. As a result of the presence of HL and L in the [{Ni(HL)(L)}]+ unit, the complex appears to be a supramolecular dimer composed of the Δ(−) and Λ(−) optical isomers, which are linked by strong hydrogen-bonds. As well as the dimer generated by two mononuclear [{Ni(HL)(L)}]+ cations, the asymmetric unit also contains two nitrate anions and one water molecule. Each Ni atom is coordinated to two ligand molecules by a nitrogen atom of the pyridine ring, an imine nitrogen atom and a phenolic oxygen atom of one of the ligand molecules and a phenolate oxygen atom of the other organic molecules. The environment around the cation is a distorted octahedron. The basal planes are defined by the two nitrogen atoms of the pyridine rings and the two phenolic oxygen atoms of the ligand, the apical positions being occupied by the azomethine atoms. The O atoms of one of the nitrate ions are disordered over two sets of sites in a 0.745 (9):0.255 (9) ratio. In the crystal, the dimers are linked by numerous hydrogen bonds, forming a three-dimensional framework