Towards a Rigorous Proof of Magnetism on the Edges of Graphene Nano-ribbons

A zigzag edge of a graphene nanoribbon supports localized zero modes, ignoring interactions. Based mainly on mean field arguments and numerical approaches, it has been suggested that interactions can produce a large magnetic moment on the edges. By considering the Hubbard model in the weak coupling limit, U<<t, for bearded as well as zigzag edges, we argue for such a magnetic state, based on Lieb's theorem. Projecting the Hubbard interactions onto the flat edge band, we then prove that resulting 1 dimensional model has a fully polarized ferromagnetic ground state. We also study excitons and the effects of second neighbor hopping as well as a potential energy term acting on the edge only, proposing a simple and possibly exact phase diagram with the magnetic moment varying smoothly to zero. Finally, we consider corrections of second order in U arising from integrating out the gapless bulk Dirac excitations.Comment: A rigorous proof of ferromagnetism is given in the small U limit, using a projected one dimensional Hamiltonia