166 research outputs found
Testing the consistency of the MaxwellâStefan formulation when predicting self-diffusion in zeolites with strong adsorption sites
Full text linkReductive electrosynthesis of crystalline metal-organic frameworks
Get PDFElectroreduction of oxoanions affords hydroxide equivalents that induce selective deposition of crystalline metalâorganic frameworks (MOFs) on conductive surfaces. The method is illustrated by cathodic electrodeposition of Zn[subscript 4]O(BDC)[subscript 3] (MOF-5; BDC = 1,4-benzenedicarboxylate), which is deposited at room temperature in only 15 min under cathodic potential. Although many crystalline phases are known in the Zn[superscript 2+]/BDCsuperscript 2â] system, MOF-5 is the only observed crystalline MOF phase under these conditions. This fast and mild method of synthesizing MOFs is amenable to direct surface functionalization and could impact applications requiring conformal coatings of microporous MOFs, such as gas separation membranes and electrochemical sensors.Massachusetts Institute of Technology. Energy Initiative (Seed Fund Program)National Science Foundation (U.S.) (Grant CHE-9808061)National Science Foundation (U.S.) (Grant DBI-9729592)National Science Foundation (U.S.) (Grant DMR- 0819762
Flexural wave propagation in fluid-conveying carbon nanotubes with system uncertainties
Full text linkMolecular Dynamics Simulations of Gas Diffusion in MetalâOrganic Frameworks:Â Argon in CuBTC
No full textMolecular Dynamics Simulations of Self-Diffusivities, Corrected Diffusivities, and Transport Diffusivities of Light Gases in Four Silica Zeolites To Assess Influences of Pore Shape and Connectivity
No full textOn the Inflection in the Concentration Dependence of the MaxwellâStefan Diffusivity of CF 4
No full textAdsorption of gases in metal organic materials: comparison of simulations and experiments.
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