Thermal analysis of wood fuel pyrolysis process

The paper presents the results of studies of conversion process on the laboratory pyrolysis reactor and the results are compared with data, obtained in model experiments by thermogravimetric analysis (TGA). The heating rates were compared in the pyrolysis reactor and in the laboratory furnace of TGA in the pyrolysis process of wood biomass conversion. The laboratory pyrolysis reactor, as a part of the multistage gasification facility of low-grade solid fuel, was launched in several modes. Three experimental modes of the device operation with different screw speeds and fuel flow rates through the reaction shaft were tested. The temperature profile of fuel and wall along the length of the pyrolysis reactor was shown. The temperature up to 600 °C was recorded in a mode with a low fuel flow rate, and in the end of the reaction zone the fuel temperature was close to that of the wall. The kinetic coefficients and conversion rates for the wood biomass pyrolysis were calculated from the obtained equation. Therefore, the calculated data of the conversion rate and the pyrolysis parameters, based on the TGA data, can be used to further develop the pyrolysis reactor and evaluate the parameters of its operation. © 2018 Institute of Physics Publishing. All rights reserved.The research was performed at Melentiev Energy Systems Institute SB RAS under the support of Russian Science Foundation (Grant № 16-19-10227) and by using the Unique Scientific Plant “High‐temperature circuit”.Russian Foundation for Basic Research (RFBR

Interplay Between Time-Temperature-Transformation and the Liquid-Liquid Phase Transition in Water

We study the TIP5P water model proposed by Mahoney and Jorgensen, which is closer to real water than previously-proposed classical pairwise additive potentials. We simulate the model in a wide range of deeply supercooled states and find (i) the existence of a non-monotonic ``nose-shaped'' temperature of maximum density line and a non-reentrant spinodal, (ii) the presence of a low temperature phase transition, (iii) the free evolution of bulk water to ice, and (iv) the time-temperature-transformation curves at different densities.Comment: RevTeX4, 4 pages, 4 eps figure

Segue Between Favorable and Unfavorable Solvation

Solvation of small and large clusters are studied by simulation, considering a range of solvent-solute attractive energy strengths. Over a wide range of conditions, both for solvation in the Lennard-Jones liquid and in the SPC model of water, it is shown that the mean solvent density varies linearly with changes in solvent-solute adhesion or attractive energy strength. This behavior is understood from the perspective of Weeks' theory of solvation [Ann. Rev. Phys. Chem. 2002, 53, 533] and supports theories based upon that perspective.Comment: 8 pages, 7 figure

Structure in liquid water: A study of spatial distribution functions

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Structure in liquid methanol from spatial distribution functions

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NONEQUILIBRIUM MOLECULAR DYNAMICS OF A DENSE IONIC FLUID

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