21,300 research outputs found
Ribosome recycling induces optimal translation rate at low ribosomal availability
Funding statement The authors thank BBSRC (BB/F00513/X1, BB/I020926/1 and DTG) and SULSA for funding. Acknowledgement The authors thank R. Allen, L. Ciandrini, B. Gorgoni and P. Greulich for very helpful discussions and careful reading of the manuscript.Peer reviewedPublisher PD
The relaxation of OH (v = 1) and OD (v = 1) by H2O and D2O at temperatures from 251 to 390 K
We report rate coefficients for the relaxation of OH(v = 1) and OD(v = 1) by H2O and D2O as a function of temperature between 251 and 390 K. All four rate coefficients exhibit a negative dependence on temperature. In Arrhenius form, the rate coefficients for relaxation (in units of 10–12 cm3 molecule–1 s–1) can be expressed as: for OH(v = 1) + H2O between 263 and 390 K: k = (2.4 ± 0.9) exp((460 ± 115)/T); for OH(v = 1) + D2O between 256 and 371 K: k = (0.49 ± 0.16) exp((610 ± 90)/T); for OD(v = 1) + H2O between 251 and 371 K: k = (0.92 ± 0.16) exp((485 ± 48)/T); for OD(v = 1) + D2O between 253 and 366 K: k = (2.57 ± 0.09) exp((342 ± 10)/T). Rate coefficients at (297 ± 1 K) are also reported for the relaxation of OH(v = 2) by D2O and the relaxation of OD(v = 2) by H2O and D2O. The results are discussed in terms of a mechanism involving the formation of hydrogen-bonded complexes in which intramolecular vibrational energy redistribution can occur at rates competitive with re-dissociation to the initial collision partners in their original vibrational states. New ab initio calculations on the H2O–HO system have been performed which, inter alia, yield vibrational frequencies for all four complexes: H2O–HO, D2O–HO, H2O–DO and D2O–DO. These data are then employed, adapting a formalism due to Troe (J. Troe, J. Chem. Phys., 1977, 66, 4758), in order to estimate the rates of intramolecular energy transfer from the OH (OD) vibration to other modes in the complexes in order to explain the measured relaxation rates—assuming that relaxation proceeds via the hydrogen-bonded complexes
Radiative Properties of the Stueckelberg Mechanism
We examine the mechanism for generating a mass for a U(1) vector field
introduced by Stueckelberg. First, it is shown that renormalization of the
vector mass is identical to the renormalization of the vector field on account
of gauge invariance. We then consider how the vector mass affects the effective
potential in scalar quantum electrodynamics at one-loop order. The possibility
of extending this mechanism to couple, in a gauge invariant way, a charged
vector field to the photon is discussed.Comment: 8 pages, new Introduction, added Reference
Exploring the impact of child maltreatment and interparental violence on violent delinquency in an international sample
An exploration of ebook selection behavior in academic library collections
Academic libraries have offered ebooks for some time, however little is known about how readers interact with them while making relevance decisions. In this paper we seek to address that gap by analyzing ebook transaction logs for books in a university library
Bending-wave Instability of a Vortex Ring in a Trapped Bose-Einstein Condensate
Based on a velocity formula derived by matched asymptotic expansion, we
investigate the dynamics of a circular vortex ring in an axisymmetric
Bose-Einstein condensate in the Thomas-Fermi limit. The trajectory for an
axisymmetrically placed and oriented vortex ring is entirely determined,
revealing that the vortex ring generally precesses in condensate. The linear
instability due to bending waves is investigated both numerically and
analytically. General stability boundaries for various perturbed wavenumbers
are computed. In particular, the excitation spectrum and the absolutely stable
region for the static ring are analytically determined.Comment: 4 pages, 4 figure
Cultural differences in intimacy: The influence of gender-role ideology and individualism-collectivism
Two studies examined emotional intimacy in European Canadian and Chinese Canadian dating relationships. Cultural differences in gender-role ideology and individualism–collectivism
were hypothesized to differentially contribute to selfdisclosure and responsiveness, and in turn, intimacy. Study 1 revealed that Chinese Canadians’ lower intimacy relative to European Canadians was mediated by their greater gender-role traditionalism but not by their individualism or collectivism. Study 2 further linked greater gender-role traditionalism to
lower self-disclosure, and in turn, lower intimacy. Results also revealed that Chinese Canadians’ lower intimacy mediated their lower relationship satisfaction and higher rate of relationship termination in Study 1, but that Chinese Canadians were not any more likely to terminate their relationships in Study 2
- …