Geomagnetic Field Variations from some Equatorial Electrojet Stations

Abstract.Quiet day variations of the equatorial electrojet along the dip equator from 10 MAGDAS stations show that there could be substantial day to day variability in the electrojet (EEJ) strength. Variations of greater than 80 nT are found in pairs of stations on the same day. The analyses show that the correlation between pairs of stations decreases as a function of increasing distance between them. The results confirm the presence of counter electrojet occurring mainly in the morning and evening hours with strengths of up to 30 nT in certain instances. The data show a longitudinal variability in the EEJ, with results showing strongest EEJ current in the South American sector and weakest in the Malaysian sector

Latitudinal and Seasonal Investigations of Storm-Time TEC Variation

The ionosphere responds markedly and unpredictably to varying magnetospheric energy inputs caused by solar disturbances on the geospace. Knowledge of the impact of the space weather events on the ionosphere is important to assess the environmental effect on the operations of ground- and space-based technologies. Thus, global positioning system (GPS) measurements from the international GNSS service (IGS) database were used to investigate the ionospheric response to 56 geomagnetic storm events at six different latitudes comprising the northern and southern hemispheres in the Afro-European sector. Statistical distributions of total electron content (TEC) response show that during the main phase of the storms, enhancement of TEC is more pronounced in most of the seasons, regardless of the latitude and hemisphere. However, a strong seasonal dependence appears in the TEC response during the recovery phase. Depletion of TEC is majorly observed at the high latitude stations, and its appearance at lower latitudes is seasonally dependent. In summer hemisphere, the depletion of TEC is more pronounced in nearly all the latitudinal bands. In winter hemisphere, enhancement as well as depletion of TEC is observed over the high latitude, while enhancement is majorly observed over the mid and low latitudes. In equinoxes, the storm-time TEC distribution shows a fairly consistent characteristic with the summer distribution, particularly in the northern hemisphere

Pattern of Ionization Gradient, Solar Quiet Magnetic Element, and F2-Layer Bottomside Thickness Parameter at African Equatorial Location

The study of ionization gradient (dN/dh) profile in the description of ionospheric dynamics is not common. This is the first attempt at finding the dependence of ionization gradient, solar quiet component (Sq (BH)), and bottomside thickness parameter (B0) in the African equatorial sector. Digisonde and Magnetic Data Acquisition System data collocated at an equatorial location were employed. Result was presented for sunrise (00 LT), midday (12 LT), sunset (18 LT), and midnight (00 LT) hours. The ionization gradient peak height remains unchanged at midday across all months. A percentage correlation of 93% existed in the inverse and direct linear relationship of dN/dh‐B0 at sunrise, and of Sq (BH)‐B0 at midday, respectively. Significant relationship between dN/dh and Sq (BH) was at sunset; for other hours, the relationship is poor. The multiple linear relationship of dN/dh‐Sq (BH)‐B0 parameters revealed that the dependence of dN/dh on Sq (BH) and B0 is highest at midday, and a model equation was presented. The dependence of dN/dh on the solar activity index (F10.7) holds at all the selected hours, and distinct only at midday and midnight for the Sq (BH)‐F10.7 and B0‐F10.7 patterns. Both the peak ionization gradient and the height it occurs maximizes/minimizes at 18 LT/06 LT. The importance of the F region dynamo at heights above 150 km was reported

Synthesis, structural and DFT investigation of Zn(nba)2(meim)2 for adsorptive removal of eosin yellow dye from aqueous solution

A novel Zn(II) mixed-ligand complex, Zn(nba)2(meim)2 (1), synthesized from Zn(NO3)2.6H2O, nitrobenzoic acid (Hnba) and 1-methylimidazole (meim) is reported. The complex was characterized by elemental analysis, FT-IR, powder and single crystal X-ray crystallography and TGA/DSC. 1 exhibits a tetrahedral geometry for Zn(II), which is coordinated to two carboxylate oxygen atoms from two nba anions and two imidazole nitrogen atoms from two meim molecules. Thermal analysis shows the stability of 1 up to 260°C. The adsorption of eosin yellow (EY) dye on 1 was investigated. The adsorption capacity of 1 for EY amounted to 65.32 mg/g, fitting best into Langmuir isotherm and pseudo second order kinetic models. From DFT studies, it was determined that adsorption is predominantly due to electrostatic, hydrogen bonding and π-π interactions