Diquaternary Ammonium Compounds in Zeolite Synthesis: Cyclic and Polycyclic N-Heterocycles Connected by Methylene Chains

An additional dimension has been added to our long-standing studies in high silica zeolite synthesis via a guest/host synergism. We have created and studied the impact of making symmetric diquaternary ammonium compounds, by varying the chain length between nitrogen charge centers, and the heterocycle size and geometry containing the nitrogen. This allows the introduction of a second spatial parameter in the use of the charged organo-cation guest in the zeolite synthesis. The series of 15 diquaternary ammonium compounds (5 heterocycles synthesized onto chain lengths of C4−C6) were tested in a total of 135 zeolite syntheses reactions. Nine screening reactions were employed for each guest molecule, and the conditions built upon past successes in finding novel high silica zeolites via introduction of boron, aluminum, or germanium as substituting tetrahedral framework atoms for silicon. Eighteen different zeolite structures emerged from the studies. The use of specific chain lengths for derivatives of the pyrrolidine ring system produced novel zeolite materials SSZ-74 and 75

Parity violation in deuteron photo-disintegration

We analyze the energy dependence for two types of parity-non-conserving (PNC) asymmetries in the reaction $\gamma D\to np$ in the near-threshold region. The first one is the asymmetry in reaction with circularly polarized photon beam and unpolarized deuteron target. The second one corresponds to those with an unpolarized photon beam and polarized target. We find that the two asymmetries have quite different energy dependence, and their shapes are sensitive to the PNC-meson exchange coupling constants. The predictions for the future possible experiments to provide definite constraints for the PNC-coupling constants are discussed.Comment: 22 pages, 12 figures. Submitted to Phys.Rev.C 10Oct.0

A conserved variable in the perturbed hydrodynamic world model

We introduce a scalar-type perturbation variable $\Phi$ which is conserved in the large-scale limit considering general sign of three-space curvature ($K$), the cosmological constant ($\Lambda$), and time varying equation of state. In a pressureless medium $\Phi$ is {\it exactly conserved} in all scales.Comment: 4 pages, no figure, To appear in Phys. Rev.

Relativistic Hydrodynamic Cosmological Perturbations

Relativistic cosmological perturbation analyses can be made based on several different fundamental gauge conditions. In the pressureless limit the variables in certain gauge conditions show the correct Newtonian behaviors. Considering the general curvature ($K$) and the cosmological constant ($\Lambda$) in the background medium, the perturbed density in the comoving gauge, and the perturbed velocity and the perturbed potential in the zero-shear gauge show the same behavior as the Newtonian ones in general scales. In the first part, we elaborate these Newtonian correspondences. In the second part, using the identified gauge-invariant variables with correct Newtonian correspondences, we present the relativistic results with general pressures in the background and perturbation. We present the general super-sound-horizon scale solutions of the above mentioned variables valid for general $K$, $\Lambda$, and generally evolving equation of state. We show that, for vanishing $K$, the super-sound-horizon scale evolution is characterised by a conserved variable which is the perturbed three-space curvature in the comoving gauge. We also present equations for the multi-component hydrodynamic situation and for the rotation and gravitational wave.Comment: 16 pages, no figure, To appear in Gen. Rel. Gra

A Most Unusual Zeolite Templating: Cage to Cage Connection of One Guest Molecule

An unusual case of a diquaternary ammonium dication, with large bulky end groups built from the tropane moiety and connected by a C4 methylene chain, is found to reside in zeolite SSZ-35 (STF). The structure of the guest/host product is such that the tropane bicylic entities reside in the shallow cavities of the cages of the STF structure and the C4 methylene chain runs through the 10-ring (~5.5 Å) window that connects the cages. This is a most unusual (and energy-intensive) templating of a zeolite structure with the guest molecule spanning two unit cells. The unusual result was found by single crystal studies with the addition of the use of the SQUEEZE program to show a consistent fit for the guest molecule following from measured electron densities in the crystal structure work. These analyses were followed with MAS NMR studies to confirm the integrity of the diquaternary guest molecule in the host sieve. A few comparative diquaternary guest molecules in MFI zeolite are also studied

Cosmological Gravitational Wave in a Gravity with Quadratic Order Curvature Couplings

We present a set of equations describing the cosmological gravitational wave in a gravity theory with quadratic order gravitational coupling terms which naturally arise in quantum correction procedures. It is known that the gravitational wave equation in the gravity theories with a general $f(R)$ term in the action leads to a second order differential equation with the only correction factor appearing in the damping term. The case for a $R^{ab} R_{ab}$ term is completely different. The gravitational wave is described by a fourth order differential equation both in time and space. However, curiously, we find that the contributions to the background evolution are qualitatively the same for both terms.Comment: 4 pages, revtex, no figure

Physicochemical Properties and Catalytic Behavior of the Molecular Sieve SSZ-70

SSZ-70 is synthesized using 1,3-bis(isobutyl)imidazolium, 1,3-bis(cyclohexyl)imidazolium, and 1,3-bis(cycloheptyl)imidazolium structure directing agents (SDAs), and the solids obtained are characterized by powder X-ray diffraction (XRD), ^(29)Si magic angle spinning nuclear magnetic resonance (MAS NMR), electron microscopy, nitrogen and hydrocarbon adsorption, and thermogravimetric analyses. The physicochemical properties of SSZ-70 show that it is a new molecular sieve that has similarities to MWW-type materials. The catalytic behavior of SSZ-70 is evaluated through the use of the constraint index (CI) test. Distinct differences in the reactivity between Al-SSZ-70 and SSZ-25 (MWW) are observed and are the consequences of the structural differences between these two molecular sieves

2D Metal-Insulator transition as a percolation transition

By carefully analyzing the low temperature density dependence of 2D conductivity in undoped high mobility n-GaAs heterostructures, we conclude that the 2D metal-insulator transition in this system is a density inhomogeneity driven percolation transition due to the breakdown of screening in the random charged impurity disorder background. In particular, our measured conductivity exponent of $\sim 1.4$ approaches the 2D percolation exponent value of 4/3 at low temperatures and our experimental data are inconsistent with there being a zero-temperature quantum critical point in our system.Comment: 5 pages, 3 figure