2,900 research outputs found

    Catalytic role of boron atoms in self-interstitial clustering in Si

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    Using density functional theory (DFT) calculations and kinetic simulations, we have investigated the influence of boron atoms on self-interstitial clustering in Si. From DFT calculations of neutral interstitial clusters with a single B atom (BsIn, nIn–1 + BsI) becomes substantially weaker than that of an interstitial (BsIn-->BsIn–1 + I) when n>=4. This implies boron can be liberated while leaving an interstitial cluster behind. Our kinetic simulations including the boron liberation explain well experimental observations reported by J. L. Benton et al., J. Appl. Phys. 82, 120 (1997)

    Shouldering in B diffusion profiles in Si: Role of di-boron diffusion

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    The role of di-boron diffusion in evolution of B diffusion profiles has been investigated. We find that boron pair (B-s-B-i) diffusion can become as important as boron-interstitial pair (B-s-Si-i) diffusion when both boron concentration and annealing temperature are very high, leading to concentration-dependent B diffusion. Our simulated B diffusion profiles with dramatic shouldering are in excellent agreement with experimental ones reported by Schroer [Appl. Phys. Lett. 74, 3996 (1999)] for high-temperature (approximate to 1200 degrees C) postimplantion annealing of ultralow-energy (approximate to500 eV) implanted high-concentration (>10(19) cm(-3)) boron in silicon

    A Student\u27s Search for Meaning: The Creation of an Existential Therapy Models Course for Clinical Psychology Graduate Students

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    This writer explores the process of creating a models course which introduces the foundations of existential therapy to graduate students in clinical psychology programs. The first section of this paper presents the rationale for developing such a course, especially in the context of the contemporary call in the field of clinical psychology for evidence-based treatment. This author discusses how this course is pertinent specifically for the Graduate School of Professional Psychology at the University of Denver as well as necessary at large for any clinical psychology program to claim and maintain competency in psychological theory. The second section of this paper delves into the present state of research on best practice for teaching at the graduate level in clinical psychology. The current literature on pedagogy informs the philosophical and practical underpinnings of the proposed curriculum for the outlined existential therapy models course. The third section delineates the projected plan for the course, including the philosophical core of the course, goals and objectives, syllabus, required readings, additional readings, and films. Finally, in the fourth section, this writer explores the limitations of the proposed course and future directions for the teaching and incorporation of existential therapy in clinical psychology. This author presents a comprehensive foundation for faculty members and clinical directors in the field of psychology who are interested in developing a similar existential therapy models course for their programs

    Chronobiology of Epilepsy

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    A fine balance between neuronal excitation and inhibition governs the physiological state of the brain. It has been hypothesized that when this balance is lost as a result of excessive excitation or reduced inhibition, pathological states such as epilepsy emerge. Decades of investigation have shown this to be true in vitro. However, in vivo evidence of the emerging imbalance during the "latent period" between the initiation of injury and the expression of the first spontaneous behavioral seizure has not been demonstrated. Here, we provide the first demonstration of this emerging imbalance between excitation and inhibition in vivo by employing long term, high temporal resolution, and continuous local field recordings from microelectrode arrays implanted in an animal model of limbic epilepsy. We were able to track both the inhibitory and excitatory postsynaptic field activity during the entire latent period, from the time of injury to the occurrence of the first spontaneous epileptic seizure. During this latent period we observe a sustained increase in the firing rate of the excitatory postsynaptic field activity, paired with a subsequent decrease in the firing rate of the inhibitory postsynaptic field activity within the CA1 region of the hippocampus. Firing rates of both excitatory and inhibitory CA1 field activities followed a circadian- like rhythm, which is locked near in-phase in controls and near anti-phase during the latent period. We think that these observed changes are implicated in the occurrence of spontaneous seizure onset following injury

    Method of removing carbon from fly ash

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    A froth flotation method is provided for removing carbon from fly ash which utilizes an environmental friendly conditioning agent. The conditioning agent preferably comprises a biodegradable oil which is added to a slurry containing raw fly ash and water. The conditioning agent renders the carbon in the fly ash hydrophobic such that upon aeration of the slurry, air bubbles attach to the carbon particles and carry\u27 them to the surface of the slurry in the form of a froth, such that the carbon may be removed.https://digitalcommons.mtu.edu/patents/1063/thumbnail.jp

    Understanding Information Behavior and the Relationship to Job Performance

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    Information behavior is an important topic area for the future Internet, Information Systems developers, and the information research community. This article shows two main factors of information behavior—information motivation and information capability—and its relationship to job performance based on the literature review of psychology, management, IS, and IT training fields. This article reviews the wide range of literature on the information behavior, provides the summarized tables of literature, and proposes the future research framework based on the literature review

    SPITZER observations of dust destruction in the Puppis A supernova remnant

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    The interaction of the Puppis A supernova remnant (SNR) with a neighboring molecular cloud provides a unique opportunity to measure the amount of grain destruction in an SNR shock. Spitzer Space Telescope MIPS imaging of the entire SNR at 24, 70, and 160 ÎŒm shows an extremely good correlation with X-ray emission, indicating that the SNR’s IR radiation is dominated by the thermal emission of swept-up interstellar dust, collisionally heated by the hot shocked gas. Spitzer IRS spectral observations targeted both the Bright Eastern Knot (BEK) of the SNR where a small cloud has been engulfed by the supernova blast wave and outlying portions of the associated molecular cloud that are yet to be hit by the shock front. Modeling the spectra from both regions reveals the composition and the grain size distribution of the interstellar dust, both in front of and behind the SNR shock front. The comparison shows that the ubiquitous polycyclic aromatic hydrocarbons of the interstellar medium are destroyed within the BEK, along with nearly 25% of the mass of graphite and silicate dust grains

    Stability and Reversibility of Lithium Borohydrides Doped by Metal Halides and Hydrides

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    In an effort to develop reversible metal borohydrides with high hydrogen storage capacities and low dehydriding temperature, doping LiBH4 with various metal halides and hydrides has been conducted. Several metal halides such as TiCl3, TiF3, and ZnF2 effectively reduced the dehydriding temperature through a cation exchange interaction. Some of the halide doped LiBH4 are partially reversible. The LiBH4 + 0.1TiF3 desorbed 3.5 wt % and 8.5 wt % hydrogen at 150 and 450 °C, respectively, with subsequent reabsorption of 6 wt % hydrogen at 500 °C and 70 bar observed. XRD and NMR analysis of the rehydrided samples confirmed the reformation of LiBH4. The existence of the (B12H12)−2 species in dehydrided and rehydrided samples gives insight into the resultant partial reversibility. A number of other halides, MgF2, MgCl2, CaCl2, SrCl2, and FeCl3, did not reduce the dehydriding temperature of LiBH4 significantly. XRD and TGA-RGA analyses indicated that an increasing proportion of halides such as TiCl3, TiF3, and ZnCl2 from 0.1 to 0.5 mol makes lithium borohydrides less stable and volatile. Although the less stable borohydrides such as LiBH4 + 0.5TiCl3, LiBH4 + 0.5TiF3, and LiBH4 + 0.5ZnCl2 release hydrogen at room temperature, they are not reversible due to unrecoverable boron loss caused by diborane emission. In most cases, doping that produced less stable borohydrides also reduced the reversible hydrogen uptake. It was also observed that halide doping changed the melting points and reduced air sensitivity of lithium borohydrides

    A KINEMATIC ANALYSIS OF THE BREASTROKE KICK

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    The study investigated the contribution of the ankle joint in the breaststroke kick using three dimensional kinematic analyses. Methodology included applying reference markers to the right leg using anatomical reference points and then videotaping twelve competitive swimmers performing the breaststroke. A Matlab script was used to calculate relative angles (between the foot and shank), angular and relative angular velocities, and linear velocities. The results of a linear regression at
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