Symmetry and the thermodynamics of currents in open quantum systems

Symmetry is a powerful concept in physics, and its recent application to understand nonequilibrium behavior is providing deep insights and groundbreaking exact results. Here we show how to harness symmetry to control transport and statistics in open quantum systems. Such control is enabled by a first-order-type dynamic phase transition in current statistics and the associated coexistence of different transport channels (or nonequilibrium steady states) classified by symmetry. Microreversibility then ensues, via the Gallavotti-Cohen fluctuation theorem, a twin dynamic phase transition for rare current fluctuations. Interestingly, the symmetry present in the initial state is spontaneously broken at the fluctuating level, where the quantum system selects the symmetry sector that maximally facilitates a given fluctuation. We illustrate these results in a qubit network model motivated by the problem of coherent energy harvesting in photosynthetic complexes, and introduce the concept of a symmetry-controlled quantum thermal switch, suggesting symmetry-based design strategies for quantum devices with controllable transport properties.Comment: 12 pages, 6 figure

Metastability and Avalanches in a Nonequilibrium Ferromagnetic System

We present preliminary results on the metastable behavior of a nonequilibrium ferromagnetic system. The metastable state mean lifetime is a non-monotonous function of temperature; it shows a maximum at certain non-zero temperature which depends on the strengh of the nonequilibrium perturbation. This is in contrast with the equilibrium case in which lifetime increases monotonously as the temperature is decreasesed. We also report on avalanches during the decay from the metastable state. Assuming both free boundaries and nonequilibrium impurities, the avalanches exhibit power-law size and lifetime distributions. Such scale free behavior is very sensible. The chances are that our observations may be observable in real (i.e. impure) ferromagnetic nanoparticles.Comment: 6 pages, 4 figures, to be published in 2002 Granada Seminar Proceeding

Relaxation dynamics in a transient network fluid with competing gel and glass phases

We use computer simulations to study the relaxation dynamics of a model for oil-in-water microemulsion droplets linked with telechelic polymers. This system exhibits both gel and glass phases and we show that the competition between these two arrest mechanisms can result in a complex, three-step decay of the time correlation functions, controlled by two different localization lengthscales. For certain combinations of the parameters, this competition gives rise to an anomalous logarithmic decay of the correlation functions and a subdiffusive particle motion, which can be understood as a simple crossover effect between the two relaxation processes. We establish a simple criterion for this logarithmic decay to be observed. We also find a further logarithmically slow relaxation related to the relaxation of floppy clusters of particles in a crowded environment, in agreement with recent findings in other models for dense chemical gels. Finally, we characterize how the competition of gel and glass arrest mechanisms affects the dynamical heterogeneities and show that for certain combination of parameters these heterogeneities can be unusually large. By measuring the four-point dynamical susceptibility, we probe the cooperativity of the motion and find that with increasing coupling this cooperativity shows a maximum before it decreases again, indicating the change in the nature of the relaxation dynamics. Our results suggest that compressing gels to large densities produces novel arrested phases that have a new and complex dynamics.Comment: 16 pages, 15 figure

When gel and glass meet: A mechanism for multistep relaxation

We use computer simulations to study the dynamics of a physical gel at high densities where gelation and the glass transition interfere. We report and provide detailed physical understanding of complex relaxation patterns for time correlation functions which generically decay in a three-step process. For certain combinations of parameters we find logarithmic decays of the correlators and subdiffusive particle motion.Comment: 4 pages, 5 figure