2,564 research outputs found
Anti-Corrosive Properties of Alkaloids on Metals
Numerous organic inhibitors have been reported to be used for the corrosion inhibition of various metals, especially, the heterogeneous ring compounds bearing larger electronegativity atoms (i.e., N, O, S, and P), polar functional groups, and conjugated double bonds are the most effective inhibitors. Based on the concept of green chemistry, in recent years, the research of corrosion inhibitor has gradually extracted new environment-friendly corrosion inhibitor from natural animals and plants, because of its advantages in wide source, low cost, low toxicity and subsequent treatment. Alkaloids such as papaverine, strychnine, quinine, nicotine, etc., have been studied as inhibitors for metals corrosion in corrosive media. This chapter aims to review the application of alkaloids for the corrosion inhibition of metals in corrosive media, and the development trend in this field is prospected
Successfully Applying Lottery Ticket Hypothesis to Diffusion Model
Despite the success of diffusion models, the training and inference of
diffusion models are notoriously expensive due to the long chain of the reverse
process. In parallel, the Lottery Ticket Hypothesis (LTH) claims that there
exists winning tickets (i.e., aproperly pruned sub-network together with
original weight initialization) that can achieve performance competitive to the
original dense neural network when trained in isolation. In this work, we for
the first time apply LTH to diffusion models. We empirically find subnetworks
at sparsity 90%-99% without compromising performance for denoising diffusion
probabilistic models on benchmarks (CIFAR-10, CIFAR-100, MNIST). Moreover,
existing LTH works identify the subnetworks with a unified sparsity along
different layers. We observe that the similarity between two winning tickets of
a model varies from block to block. Specifically, the upstream layers from two
winning tickets for a model tend to be more similar than the downstream layers.
Therefore, we propose to find the winning ticket with varying sparsity along
different layers in the model. Experimental results demonstrate that our method
can find sparser sub-models that require less memory for storage and reduce the
necessary number of FLOPs. Codes are available at
https://github.com/osier0524/Lottery-Ticket-to-DDPM
Approaches to the Total Synthesis of Puupehenone-Type Marine Natural Products
Puupehenones have been isolated from the marine sponge Chondrosia chucalla, which belong to a growing family of natural products with more than 100 members. These marine natural products have attracted increasing attention mainly due to their wide variety of biological activities such as antitumor, antiviral, and anti-HIV, and thus offer promising opportunities for new drug development. This chapter covers the approaches to the total synthesis of puupehenone-type marine natural products including puupehenol, puupehenone, puupehedione, and halopuupehenones. The routes begin with the construction of their basic skeletons, followed by the modification of their C- and D-rings. The contents are divided into two sections in terms of the key strategies employed to construct the basic skeleton. One is the convergent synthesis route with two synthons coupled by nucleophilic or electrophilic reaction, and the other is the linear synthesis route with polyene series cyclization as a key reaction
Antioxidant Properties of Polysaccharide from the Brown Seaweed Sargassum graminifolium (Turn.), and Its Effects on Calcium Oxalate Crystallization
We investigated the effects of polysaccharides from the brown seaweed Sargassum graminifolium (Turn.) (SGP) on calcium oxalate crystallization, and determined its antioxidant activities. To examine the effects of SGP on calcium oxalate crystallization, we monitored nucleation and aggregation of calcium oxalate monohydrate crystals, using trisodium citrate as a positive control. We assessed antioxidant activities of SGP by determining its reducing power, its ability to scavenge superoxide radicals, and its activity in the 1,1-diphenyl-2-picrylhydrazyl (DPPH) assay. The nucleation inhibition ratio of trisodium citrate and SGP was 58.5 and 69.2%, respectively, and crystal aggregation was inhibited by 71.4 and 76.8%, respectively. Increasing concentrations of SGP resulted in increased scavenging of superoxide anions and DPPH radicals (IC50 = 1.9 and 0.6 mg/mL, respectively). These results suggest that SGP could be a candidate for treating urinary stones because of its ability to inhibit calcium oxalate crystallization and its antioxidant properties
Neurological abnormalities and neurocognitive functions in healthy elder people: A structural equation modeling analysis
Background/Aims: Neurological abnormalities have been reported in normal aging population. However, most of them were limited to extrapyramidal signs and soft signs such as motor coordination and sensory integration have received much less attention. Very little is known about the relationship between neurological soft signs and neurocognitive function in healthy elder people. The current study aimed to examine the underlying relationships between neurological soft signs and neurocognition in a group of healthy elderly
Data Processing Pipeline for Pointing Observations of Lunar-based Ultraviolet Telescope
We describe the data processing pipeline developed to reduce the pointing
observation data of Lunar-based Ultraviolet Telescope (LUT), which belongs to
the Chang'e-3 mission of the Chinese Lunar Exploration Program. The pointing
observation program of LUT is dedicated to monitor variable objects in a
near-ultraviolet (245-345 nm) band. LUT works in lunar daytime for sufficient
power supply, so some special data processing strategies have been developed
for the pipeline. The procedures of the pipeline include stray light removing,
astrometry, flat fielding employing superflat technique, source extraction and
cosmic rays rejection, aperture and PSF photometry, aperture correction, and
catalogues archiving, etc. It has been intensively tested and works smoothly
with observation data. The photometric accuracy is typically ~0.02 mag for LUT
10 mag stars (30 s exposure), with errors come from background noises,
residuals of stray light removing, and flat fielding related errors. The
accuracy degrades to be ~0.2 mag for stars of 13.5 mag which is the 5{\sigma}
detection limit of LUT.Comment: 10 pages, 7 figures, 4 tables. Minor changes and some expounding
words added. Version accepted for publication in Astrophysics and Space
Science (Ap&SS
- …