Kinetics and Mechanisms of Phosphorus Adsorption in Soils from Diverse Ecological Zones in the Source Area of a Drinking-Water Reservoir.

On-site soils are increasingly used in the treatment and restoration of ecosystems to harmonize with the local landscape and minimize costs. Eight natural soils from diverse ecological zones in the source area of a drinking-water reservoir in central China are used as adsorbents for the uptake of phosphorus from aqueous solutions. The X-ray fluorescence (XRF) spectrometric and BET (Brunauer-Emmett-Teller) tests and the Scanning Electron Microscopy (SEM) and Fourier Transform Infrared (FTIR) spectral analyses are carried out to investigate the soils' chemical properties and their potential changes with adsorbed phosphorous from aqueous solutions. The intra-particle diffusion, pseudo-first-order, and pseudo-second-order kinetic models describe the adsorption kinetic processes. Our results indicate that the adsorption processes of phosphorus in soils occurred in three stages and that the rate-controlling steps are not solely dependent on intra-particle diffusion. A quantitative comparison of two kinetics models based on their linear and non-linear representations, and using the chi-square (χ2) test and the coefficient of determination (r2), indicates that the adsorptive properties of the soils are best described by the non-linear pseudo-second-order kinetic model. The adsorption characteristics of aqueous phosphorous are determined along with the essential kinetic parameters

International Water Comprehensive Organization (IWCO): Creating alliances for improved water management and solving water conflicts

International organizations constitute the basis to increase water co-operation, prevent or reduce the possibility of conflicts between countries, and, were they to occur, achieve co-operation to resolve them. The proliferation of water-related conflicts, especially involving transboundary watersheds, the need for stakeholder co-operation, and the necessity of creating alliances between water organizations call for the formation of an organization to tackle the resolution of such conflicts. River Basin Organizations (RBOs) have been created in the water field in recent years, which have addressed a variety of water-related problems. Yet, there is no holistic agency at present tasked with the comprehensive review and resolution of water conflicts worldwide. This paper presents a plan to create an International Water Comprehensive Organization (IWCO) under the auspices of the United Nations that would address water conflicts worldwide, which would integrate other existing organizations with jurisdiction in the realm of water management. Furthermore, this work describes the objectives and needs for creating the IWCO, defines its structure, and outlines its main tasks and authorities. The IWCO would integrate existing water-related organizations for solving hydropolitical issues, and would provide logistic support leading to scientific and legal advances in the water field. HIGHLIGHTS Outlining for International Water Comprehensive Organization (IWCO) under the auspices of the UN.; Identifying the need for the IWCO and its objectives, structure, tasks, and authority.; Integrating existing organizations with jurisdiction in the realm of water management.; Monitoring the hydropolitics, water law, water policy, and water economy at the global level.; Creating alliances for water management and solving conflicts.

Developing a novel parameter-free optimization framework for flood routing

The Muskingum model is a popular hydrologic flood routing technique; however, the accurate estimation of model parameters challenges the effective, precise, and rapid-response operation of flood routing. Evolutionary and metaheuristic optimization algorithms (EMOAs) are well suited for parameter estimation task associated with a wide range of complex models including the nonlinear Muskingum model. However, more proficient frameworks requiring less computational effort are substantially advantageous. Among the EMOAs teaching-learning-based optimization (TLBO) is a relatively new, parameter-free, and efficient metaheuristic optimization algorithm, inspired by the teacher-student interactions in a classroom to upgrade the overall knowledge of a topic through a teaching-learning procedure. The novelty of this study originates from (1) coupling TLBO and the nonlinear Muskingum routing model to estimate the Muskingum parameters by outflow predictability enhancement, and (2) evaluating a parameter-free algorithm's functionality and accuracy involving complex Muskingum model's parameter determination. TLBO, unlike previous EMOAs linked to the Muskingum model, is free of algorithmic parameters which makes it ideal for prediction without optimizing EMOAs parameters. The hypothesis herein entertained is that TLBO is effective in estimating the nonlinear Muskingum parameters efficiently and accurately. This hypothesis is evaluated with two popular benchmark examples, the Wilson and Wye River case studies. The results show the excellent performance of the "TLBO-Muskingum" for estimating accurately the Muskingum parameters based on the Nash-Sutcliffe Efficiency (NSE) to evaluate the TLBO's predictive skill using benchmark problems. The NSE index is calculated 0.99 and 0.94 for the Wilson and Wye River benchmarks, respectively

Assessment of global hydro-social indicators in water resources management

Water is a vital element that plays a central role in human life. This study assesses the status of indicators based on water resources availability relying on hydro-social analysis. The assessment involves countries exhibiting decreasing trends in per capita renewable water during 2005-2017. Africa, America, Asia, Europe, and Oceania encompass respectively 48, 35, 43, 20, and 5 countries with distinct climatic conditions. Four hydro-social indicators associated with rural society, urban society, technology and communication, and knowledge were estimated with soft-computing methods [i.e., artificial neural networks, adaptive neuro-fuzzy inference system, and gene expression programming (GEP)] for the world's continents. The GEP model's performance was the best among the computing methods in estimating hydro-social indicators for all the world's continents based on statistical criteria [correlation coefficient (R), root mean square error (RMSE), and mean absolute error]. The values of RMSE for GEP models for the ratio of rural to urban population (PRUP), population density, number of internet users and education index parameters equaled (0.084, 0.029, 0.178, 0.135), (0.197, 0.056, 0.152, 0.163), (0.151, 0.036, 0.123, 0.210), (0.182, 0.039, 0.148, 0.204) and (0.141, 0.030, 0.226, 0.082) for Africa, America, Asia, Europe and Oceania, respectively. Scalable equations for hydro-social indicators are developed with applicability at variable spatial and temporal scales worldwide. This paper's results show the patterns of association between social parameters and water resources vary across continents. This study's findings contribute to improving water-resources planning and management considering hydro-social indicators

Integrated strategic planning and multi-criteria decision-making framework with its application to agricultural water management

Sustainable water resources management involves social, economic, environmental, water use, and resources factors. This study proposes a new framework of strategic planning with multi-criteria decision-making to develop sustainable water management alternatives for large scale water resources systems. A fuzzy multi-criteria decision-making model is developed to rank regional management alternatives for agricultural water management considering water-resources sustainability criteria. The decision-making model combines hierarchical analysis and the fuzzy Technique for Order of Preference by Similarity to Ideal Solution (TOPSIS). The management alternatives were presented spatially in the form of zoning maps at the level of irrigation zones of the study area. The results show that the irrigation management zone No.3 (alternative A3) was ranked first based on agricultural water demand and supply management in five among seven available scenarios, in which the scenarios represents a possible combination of weights assigned to the weighing criteria. Specifically, the results show that irrigation management zone No.3 (alternative A3) achieved the best ranking values of 0.151, 0.169, 0.152, 0.174 and 0.164 with respect to scenarios 1, 4, 5, 6 and 7, respectively. However, irrigation management zone No.2 (alternative A2) achieved the best values of 0.152 and 0.150 with respect to the second and third scenarios, respectively. The model results identify the best management alternatives for agricultural water management in large-scale irrigation and drainage networks

Evaluation of cooperative and non-cooperative game theoretic approaches for water allocation of transboundary rivers

Efficient water allocation in a transboundary river basin is a complex issue in water resources management. This work develops a framework for the allocation of transboundary river water between the countries located in the river basin to evaluate the characteristics of allocation approaches. The allocation of river water is obtained based on initial-water conditions, cooperative, and non-cooperative game-theoretic approaches. The initial-conditions water allocation approach assigns 34, 40, and 26% of the Harirud River flow to Afghanistan, Iran, and Turkmenistan, respectively. The game-theoretic cooperative approach assigns 36, 42, and 22% of the river flow to Afghanistan, Iran, and Turkmenistan, respectively. The non-cooperative game-theoretic approach establishes that the most stable water allocation was 42, 38, and 20% of the Harirud River flow for Afghanistan, Iran, and Turkmenistan, respectively. Human and agricultural water-stress criteria are used to evaluate the water allocations in the Harirud River basin. The criterion of human water stress has the largest influence in Iran, and the criterion of agricultural water stress has the smallest influence in Afghanistan. This work's results indicate the initial-conditions water allocation approach favors Turkmenistan, whereas the cooperative and the non-cooperative game-theoretic approaches favors Iran and Afghanistan, respectively. The results show that the priorities of each country governs water allocation, and cooperation is shown to be necessary to achieve sustainable development

Assessment of Seawater Intrusion Potential From Sea-level Rise in Coastal Aquifers of California

The California Department of Water Resources (2006) estimated a rise in mean sea level along California’s coastline ranging from 10 to 90 cm over the 21st century due to rising global mean surface temperature. This range of sea-level rise is consistent with the Intergovernmental Panel for Climate Change (2007) estimates. The rise in sea level threatens coastal aquifers by exacerbating the risk of saline intrusion. This study simulated the effect of sea-level rise on the Seaside Area sub-basin near the City of Monterey, California. The simulation was carried out with a state-of-art, finite-element, variable-density, numerical model that accounts for the effects of salinity on groundwater density and viscosity. Seawater intrusion was simulated for various scenarios of sea-level rise, varying from 0 m to 1 m assuming a linear increase of sea level through the 21st century. Each scenario contemplated the same level of predicted groundwater extraction through the 21st century in the study aquifers. The numerical simulations of seawater intrusion indicate that one meter of sea-level rise would contribute an additional 10 to 15 meters of inland spread of the 1,000 mg/L saline front and 20 to 30 meters of the 10,000 mg/L saline front. The effect of sea-level rise on seawater intrusion in the Seaside Area sub-basin, therefore, appears minor when compared with historical measurements of seawater intrusion caused primarily by groundwater pumping since the early 1900s. Other aquifers with less topographical relief and more complex hydrostratigraphy could be more vulnerable to sea-level rise, however. One such possibility is posed by the Oxnard Plain groundwater sub-basin, in Ventura County, California. This study compiled a hydrogeologic database and structured the basic elements of a sea-water intrusion numerical simulation model for the Oxnard Plain aquifer. The Oxnard Plain sub-basin is a complex, multi-formation, aquifer that has undergone several decades of groundwater extraction, and, which is known to experience seawater intrusion in several of its coastal areas. The Oxnard Plain sub-basin features an important offshore hydrogeologic section that encompasses its boundary under seawater. Time limitations prevented calibration and validation of the numerical simulation model for seawater intrusion in the Oxnard Plain sub-basin. Nevertheless, the elements needed to complete the Oxnard Plain sub-basin’s seawater-intrusion simulation model in the near future (with additional funding) have been assembled and are presented in this report. The approach presented in this report for the relatively assessment of groundwater extraction and sea-level rise effects on seawater intrusion into coastal aquifers holds potential for wide-ranging applicability in a variety of hydrogeologic settings. In particular, the finite-element spatial grid provides distinct capabilities to represent accurately the geographical layout of an aquifer

Developing water, energy, and food sustainability performance indicators for agricultural systems

Water use by the agricultural sector along with inefficient irrigation methods and climate change has led to the depletion and insecurity of water resources and consequent instability of the agricultural system. Defining benchmarks and comparing them is essential for sustainable system management performance. The sustainability performance of an agricultural system depends on various factors related to water, energy, and food. This study selects and ranks sustainability performance indicators (SPIs) of agricultural systems with the analytical hierarchy process (AHP). Expert opinions on agricultural sustainability were obtained from Iran's Regional Water Organization. The factors and variables affecting the management of water resources in agricultural systems in a basin area are evaluated with 17 SPIs (10 indicators of water resources sustainability, 3 energy sustainability indicators, and 4 food sustainability indicators) that measure the sustainability of agricultural systems. The AHP reduced the number of indicators to a small number of effective indicators. Results of pairwise comparison and the subsequent determination of the weight of each indicator show that the indicators of water consumption, groundwater level stability, vulnerability of water resources, and water stress have the largest weights (i.e., importance) for agricultural system sustainability at the basin scale. These selected indicators can be applied to agricultural water systems (AWSs)

Kinetics and Mechanisms of Phosphorus Adsorption in Soils from Diverse Ecological Zones in the Source Area of a Drinking-Water Reservoir.

On-site soils are increasingly used in the treatment and restoration of ecosystems to harmonize with the local landscape and minimize costs. Eight natural soils from diverse ecological zones in the source area of a drinking-water reservoir in central China are used as adsorbents for the uptake of phosphorus from aqueous solutions. The X-ray fluorescence (XRF) spectrometric and BET (Brunauer-Emmett-Teller) tests and the Scanning Electron Microscopy (SEM) and Fourier Transform Infrared (FTIR) spectral analyses are carried out to investigate the soils' chemical properties and their potential changes with adsorbed phosphorous from aqueous solutions. The intra-particle diffusion, pseudo-first-order, and pseudo-second-order kinetic models describe the adsorption kinetic processes. Our results indicate that the adsorption processes of phosphorus in soils occurred in three stages and that the rate-controlling steps are not solely dependent on intra-particle diffusion. A quantitative comparison of two kinetics models based on their linear and non-linear representations, and using the chi-square (χ2) test and the coefficient of determination (r2), indicates that the adsorptive properties of the soils are best described by the non-linear pseudo-second-order kinetic model. The adsorption characteristics of aqueous phosphorous are determined along with the essential kinetic parameters