Numerical study of vug effects on acid-rock reactive flow in carbonate reservoirs

     Matrix acidizing is one of the most practical stimulation technologies for carbonate reservoirs, which effectively improve the region permeability near the wellbore. In addition to solid matrix, vugs are also very common in carbonate reservoirs. However, a few studies have been addressed with existence of vugs on carbonate acidizing process. In this work, a two-scale model is developed using dual domain method and discrete vugs model to study effect of vugs on acidizing process. Darcy equation is employed in solid matrix region. Navier Stokes equation is adopted for free flow region in vugs. The two regions are coupled by modified Beavers-Joseph-Saffman boundary condition. Numerical cases are conducted to present the effect of vug characteristics on acid-rock reaction process. The results show that acid solution has the largest effective reducing distance and the smallest breakthrough volume in circular vugs. Dominant wormhole is created when acid injection direction is parallel or vertical to the azimuth angle of vugs. Increasing amount of vugs in horizontal effectively reduces the flow distance and breakthrough volume of acid solution. Vugs with random distribution increases effective flow distance and breakthrough volume of acid solution compared to vugs with orderly distribution.Cited as: Huang, Z., Xing, H., Zhou, X., You, H. Numerical study of vug effects on acid-rock reactive flow in carbonate reservoirs. Advances in Geo-Energy Research, 2020, 4(4): 448-459, doi: 10.46690/ager.2020.04.0

Comparison of multi-field coupling numerical simulation in hot dry rock thermal exploitation of enhanced geothermal systems

 In order to alleviate the environmental crisis and improve energy structure, countries from all over the world have focused on the hot dry rock geothermal resources with great potential and with little pollution. The geothermal heat production from Enhanced Geothermal System (EGS) comes with complex multi-field coupling process, and it is of great significance to study the temporal and spatial evolution of geothermal reservoir. In this work, a practical numerical model is established to simulate the heat production process in EGS, and the comparison of thermal-hydraulic (TH), thermal-hydraulic-mechanical (THM) and thermal-hydraulic-mechanical-chemical (THMC) coupling in geothermal reservoir is analyzed. The results show that the stable production stage of the three cases is approximately 5 years; however, compared with TH and THMC coupling, the service-life for THM coupling decreased by 1140 days and 332 days, respectively. The mechanical enhanced effects are offset by the chemical precipitation, and the precipitation from SiO2 is much larger than the dissolution of calcite.Cited as: Chen, S., Ding, B., Gong, L., Huang, Z., Yu, B., Sun, S. Comparison of multi-field coupling numerical simulation in hot dry rock thermal exploitation of enhanced geothermal systems. Advances in Geo-Energy Research, 2019, 3(4): 396-409, doi: 10.26804/ager.2019.04.0

Non-Darcy displacement by a non-Newtonian fluid in porous media according to the Barree-Conway model

An analytical solution for describing the non-Darcy displacement of a Newtonian fluid by a non-Newtonian fluid in porous media has been developed. The two-phase non-Darcy flow is described using the Barree-Conway model under multi- phase conditions. A power-law non-Newtonian fluid, whose viscosity is a function of the flow potential gradient and the phase saturation, is considered. The analytical solution is similar to the Buckley-Leverett theoretical solution, which can be regarded as an extension of the Buckley-Leverett theory to the non-Darcy flow of non-Newtonian fluids. The analytical results revel how non-Darcy displacement by a non-Newtonian fluid is controlled not only by relative permeabilities but also by non-Darcy flow coefficients as well as non-Newtonian rheological constitutive parameters and injection rates. The comparison among Darcy, Forchheimer and Barree-Conway models is also discussed. For application, the analytical solution is then applied to verify a numerical simulator for modeling multi-phase non-Darcy flow of non-Newtonian fluids.Cited as: Huang, Z., Zhang, X., Yao, J., et al. Non-Darcy displacement by a non-Newtonian fluid in porous media according to the Barree-Conway model. Advances in Geo-Energy Research, 2017, 1(2): 74-85, doi: 10.26804/ager.2017.02.0

Epidemiology and clinical course of COVID-19 in Shanghai, China.

Background: Novel coronavirus pneumonia (COVID-19) is prevalent around the world. We aimed to describe epidemiological features and clinical course in Shanghai. Methods: We retrospectively analysed 325 cases admitted at Shanghai Public Health Clinical Center, between January 20 and February 29, 2020. Results: 47.4% (154/325) had visited Wuhan within 2 weeks of illness onset. 57.2% occurred in 67 clusters; 40% were situated within 53 family clusters. 83.7% developed fever during the disease course. Median times from onset to first medical care, hospitalization and negative detection of nucleic acid by nasopharyngeal swab were 1, 4 and 8 days. Patients with mild disease using glucocorticoid tended to have longer viral shedding in blood and feces. At admission, 69.8% presented with lymphopenia and 38.8% had elevated D-dimers. Pneumonia was identified in 97.5% (314/322) of cases by chest CT scan. Severe-critical patients were 8% with a median time from onset to critical disease of 10.5 days. Half required oxygen therapy and 7.1% high-flow nasal oxygen. The case fatality rate was 0.92% with median time from onset to death of 16 days. Conclusion: COVID-19 cases in Shanghai were imported. Rapid identification, and effective control measures helped to contain the outbreak and prevent community transmission

Synthesis of CoFe2O4/Peanut Shell Powder Composites and the Associated Magnetic Solid Phase Extraction of Phenoxy Carboxylic Acid Herbicides in Water

The magnetic biochar material CoFe2O4/PCPS (peanut shell powder) was prepared based on the hybrid calcination method. The properties of prepared composites and the extraction effect of magnetic solid phase extraction on phenoxy carboxylic acid herbicides were assessed. The morphology, crystal structure, specific surface area, and pore size distribution of the material were analysed using a transmission electron microscope (TEM), infrared Fourier transform infrared spectroscopy (FTIR), X-ray powder diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and N2 absorption surface analysis (BET). The results of the magnetic solid phase extraction of a variety of phenoxy carboxylic acid herbicides in water using CoFe2O4/PCPS composites showed that, when the mass ratio of CoFe2O4 and PCPS was 1:1, 40 mg of the composite was used, and the adsorption time was 10 min at pH 8.50. Methanol was used as the eluent, and the recovery rates of the three phenoxy carboxylic acid herbicides were maintained at 81.95–99.07%. Furthermore, the actual water sample analysis results showed that the established method had good accuracy, stability, and reliability

Effects of ageing on the surface characteristics and Cu(ii) adsorption behaviour of rice husk biochar in soil

The properties of rice husk biochar during the ageing process in soil and the resulting impacts on sorption capacity with respect to Cu(ii) were assessed. Rice husk-derived biochar was placed in fabric bags and buried in a plastic incubator filled with soil for 0–240 d. The aged biochar was then characterised and its sorption capacity compared with control (unaged) biochar in batch sorption experiments. The structural composition and morphology of the biochar before and after ageing were analysed based on element composition, scanning electron microscopy (SEM) coupled with energy X-ray dispersive spectroscopy (EDS), diffuse reflectance infrared Fourier transform infrared spectroscopy (DRIFTS), and X-ray photoelectron spectroscopy (XPS). The concentration of O, atomic O/C ratios, and carboxyl and hydroxyl functional groups increased at the surface of the biochar during ageing, which together indicated oxidation. Within the biochar particles, O/C ratios progressively increased towards their outer surfaces. Furthermore, ageing for more than 120 d facilitated Cu(ii) sorption as oxygen-containing groups were able to develop. The maximum adsorption capacity (qm) of biochar increased by 1.24 ∼ 1.32 times after ageing in the soil for 240 d. It is suggested that biochar surface properties were gradually altered during environmental exposure and the aged rice husk biochar showed increased performance in Cu(ii) adsorption. However, the performance of aged biochar as a soil remediator or conditioner will be affected by the ageing process and interactions among different soil components. As such, further research is required to evaluate these complex effects

Parameter Effect Analysis of Non-Darcy Flow and a Method for Choosing a Fluid Flow Equation in Fractured Karstic Carbonate Reservoirs

Fractured karstic carbonate reservoirs have obvious multi-scale characteristics and severe heterogeneity due to the development of abundant karst caves and fractures with different scales. Darcy and non-Darcy flows coexist due to this property. Therefore, selecting the appropriate flow equations for different regions in the numerical simulation of fluid flows, particularly two-phase and multiphase flows, is a critical topic. This paper compares and analyses the displacement distance differences of waterfront travel using the Darcy, Forchheimer and Barree–Conway equations, as well as analyzes the influence of the Forchheimer constant, fluid viscosity, flow rate and absolute permeability on inertia action based on the Buckley–Leverett theory. The results show that the Forchheimer number/Reynolds number of water/oil two-phase flow is not a constant value and varies with water saturation, making it difficult to determine whether the inertial action should be considered solely based on these values; the influence of inertial action can be measured well by comparing the difference between the displacement distances of the waterflood front, and the quantitative standard is given for the selection of the flow equation of different regions by calculating the allowable error of the displacement distance of the waterflood front. The magnitude of the inertial effect is affected by the physical properties of the fluid and reservoir medium and the fluid velocity. The smaller the difference in the viscosity of the oil/water fluid, the smaller the inertial effect is. This technique was used a preliminary attempt to analyze the fractured karstic carbonate reservoirs at Tarim, and the results confirmed the validity of the method described in this article