4,4′-Bipyridine–4-(p-toluene­sulfonamido)­benzoic acid (1/2)

In the title compound, C14H13NO4S·0.5C10H8N2, the two benzene rings are nearly perpendicular to each other [dihedral angle = 83.21 (10)°]. The bipyridine mol­ecule is centrosymmetric, the mid-point of the C—C bond linking the pyridine rings being located on an inversion center. Inter­molecular N—H⋯O and O—H⋯N hydrogen bonds and weak inter­molecular C—H⋯O hydrogen bonds are present in the crystal structure

Bis(4-amino­benzoato)-κ2 O,O′;κO-(2,2′-bipyridine-κ2 N,N′)zinc

In the title complex, [Zn(C7H6NO2)2(C10H8N2)], the ZnII cation is coordinated by two amino­benzoate anions and one 2,2′-bipyridine ligand in a distorted trigonal–bipyramidal geometry. The carboxyl­ate group of one aminobenzoate anion coordinates to the ZnII cation in a monodentate manner, whereas the carboxyl­ate group of the other amino­benzoate anion chelates the Zn cation with different Zn—O bond lengths. Inter­molecular N—H⋯N and N—H⋯O hydrogen bonding is present in the crystal structure

catena-Poly[[(2,2′-bipyridine)copper(II)]-μ-5-tert-butyl­isophthalato]

In the crystal structure of the title polymeric compound, [Cu(C12H12O4)(C10H8N2)]n, the asymmetric unit consists of one CuII ion, one 5-tert-butyl­isophthalate (tbip) and one 2,2′-bipyridine (bpy) ligand. The copper(II) ion is four-coordin­ated by two N atoms from bipy and two O atoms from two tbip ligands, leading to a distorted tetrahedral coordination. Each tbip ligand adopts a bis-monodentate coordination mode to connect two symmetry-related copper(II) ions, so forming a zigzag polymer chain parallel to [001]. The tert-butyl methyl groups are disordered over two positions with occupancies of 0.506 (6)/0.494 (6

catena-Poly[{di-μ-isonicotinato-bis[di­aqua­isonicotinatoeuropium(III)]}-μ-isonicotinato-[diisonicotinatocopper(II)]-μ-isonicotinato]

The title compound, [CuEu2(C6H4NO2)8(H2O)4]n, displays a one-dimensional chain structure. The four-coordinate CuII ion (site symmetry ) adopts a trans-CuN2O2 geometry and is bridged by two carboxyl­ate groups from two isonicotinate ligands. The EuIII ion adopts a distorted square-anti­prismatic geometry, being coordinated by four O atoms from bridging carboxyl­ate groups of four isonicotinate ligands, two O atoms from chelating carboxyl­ate groups of one isonicotinate ligand and two O atoms from coordinated water mol­ecules; adjacent EuIII ions in the chain are related by inversion. The water mol­ecules interact with the ligands via O—H⋯N hydrogen bonds [O⋯O = 2.782 (3)–2.881 (3) Å], which link the chains into a three-dimensional structure

(2,2′-Bipyridine-κ2 N,N′)hydroxido[N-(4-tolyl­sulfonyl)­alaninato-κ2 N,O 1]copper(II) hemihydrate

In the title complex, [Cu(C10H12NO4S)(OH)(C10H8N2)]·0.5H2O, the Cu(II) ion shows a distorted square-pyramidal coordination geometry with two N atoms from the 2,2′-bipyridine ligand and one N and one O atom from the N-tosyl-α-alaninato ligand forming the basis of the coordination polyhedron and another O atom of the hydroxo group acting as the apex of the pyramid. The solvent water mol­ecule is statistically disordered over two positions

Aqua­{N-[(4-methyl­phen­yl)sulfon­yl]glycinato(2−)-κ2 N,O}(1,10-phenan­throline)copper(II)

In the title complex, [Cu(C9H9NO4S)(C12H8N2)(H2O)], the CuII ion is coordinated in a distorted square-pyramidal geometry by the two N atoms from a 1,10-phenanthroline ligand, one N atom from the deprotonated amino group of an N-tosyl­glycinate ligand, one O atom from the carboxyl­ate part of the N-tosyl­glycinate ligand and a water O atom. Inter­molecular O—H⋯O hydrogen bonds involving the water H atoms link neighboring mol­ecules into supra­molecular chains along [010]. Weak π–π stacking inter­actions [centroid–centroid distances of 3.456 (1) and 3.691 (1) Å] between the benzene rings of 1,10-phenanthroline ligands of adjacent mol­ecules extend the chains into a layer structure parallel to (001)

Bis{μ-1,3-bis­[2-(5-bromo-2-oxidobenzyl­idene­amino)ethyl]-2-(5-bromo-2-oxido­phenyl)-1,3-imidazolidine}dineo­dymium(III) N,N-dimethyl­formamide hexa­solvate

In the title centrosymmetric dinuclear complex, [Nd2(C27H24Br3N4O3)2]·6C3H7NO, the NdIII ion is coordinated in a slightly distorted square-anti­prismatic geometry by four N atoms and four O atoms from two centrosymmetrically-related 1,3-bis­[2-(5-bromo-2-oxidobenzyl­amino)eth­yl]-2-(5-bromo-2-oxidophen­yl)-1,3-imidazolidine ligands. The Nd⋯Nd separation is 4.5012 (12) Å

4-(4-Methylbenzenesulfonamido)benzoic acid N,N-dimethyl­formamide mono­solvate

In the title compound, C14H13NO4S·C3H7NO, the C—S—N—C torsion angle of −64.55 (17)° defines the folded conformation of the mol­ecule. The dihedral angle between the benzene rings is 83.367 (6)°. In a crystal, mol­ecules are linked into a chain along a axis through inter­molecular N—H⋯O and O—H⋯O hydrogen bonds. There is also an intra­molecular C—H⋯π inter­action

Bis(4-aminobenzenesulfonato)tri­aqua­bis(1,10-phenanthroline)neodymium(III) nitrate tetrahydrate

The title complex, [Nd(C6H6NO3S)2(C12H8N2)2(H2O)3]NO3·4H2O, comprises a mononuclear cation, an NO3 − anion and two uncoordinated water mol­ecules; the NdIII cation, one coordinated water mol­ecule, and the NO3 − anion each lie on a twofold axis of symmetry. The NdIII ion exhibits an NdN4O5 coordination environment comprising two O atoms of two monodentate 4-amino­benzene­sulfonato ligands, four N atoms of the bidentate 1,10-phenanthroline ligands, and three water-O atoms. The coordination geometry is based on a tricapped triangular-prismatic arrangement. The components are consolidated into a three-dimensional network via O—H⋯O, O—H⋯N and N—H⋯O hydrogen-bonding inter­action

Bis(4-aminobenzenesulfonato)tri­aqua­bis(1,10-phenanthroline)neodymium(III) nitrate tetrahydrate

The title complex, [Nd(C6H6NO3S)2(C12H8N2)2(H2O)3]NO3·4H2O, comprises a mononuclear cation, an NO3 − anion and two uncoordinated water mol­ecules; the NdIII cation, one coordinated water mol­ecule, and the NO3 − anion each lie on a twofold axis of symmetry. The NdIII ion exhibits an NdN4O5 coordination environment comprising two O atoms of two monodentate 4-amino­benzene­sulfonato ligands, four N atoms of the bidentate 1,10-phenanthroline ligands, and three water-O atoms. The coordination geometry is based on a tricapped triangular-prismatic arrangement. The components are consolidated into a three-dimensional network via O—H⋯O, O—H⋯N and N—H⋯O hydrogen-bonding inter­action