285 research outputs found
Improved LeRoy-Bernstein near-dissociation expansion formula. Tutorial application to photoassociation spectroscopy of long-range states
NDE (Near-dissociation expansion) including LeRoy-Bernstein formulas are
improved by taking into account the multipole expansion coefficients and the
non asymptotic part of the potential curve. Applying these new simple
analytical formulas to photoassociation spectra of cold alkali atoms, we
improve the determination of the asymptotic coefficient, reaching a 1%
accuracy, for long-range relativistic potential curve of diatomic molecules.Comment: This article is part of Daniel Comparat's PhD thesis available at
http://tel.ccsd.cnrs.fr
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Notations and conventions in molecular spectroscopy: part 2. Symmetry notation
The field of Molecular Spectroscopy was surveyed in order to determine a set of
conventions and symbols which are in common use in the spectroscopic literature. This
document, which is Part 2 in a series, establishes the notations and conventions used for the
description of symmetry in rigid molecules, using the Schoenflies notation. It deals firstly
with the symmetry operators of the molecular point groups (also drawing attention to the
difference between symmetry operators and elements). The conventions and notations of the
molecular point groups are then established, followed by those of the representations of these
groups as used in molecular spectroscopy. Further parts will follow, dealing inter alia with
permutation and permutation-inversion symmetry notation, vibration-rotation spectroscopy
and electronic spectroscopy
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Notations and conventions in molecular spectroscopy: part 1. General spectroscopic notation
The field of Molecular Spectroscopy was surveyed in order to determine a set of
conventions and symbols which are in common use in the spectroscopic literature. This
document, which is Part I in a series, establishes the notations and conventions used for
general spectroscopic notations and deals with quantum mechanics, quantum numbers
(vibrational states, angular momentum and energy levels), spectroscopic transitions, and
miscellaneous notations (e.g. spectroscopic terms). Further parts will follow, dealing inter
alia with symmetry notation, permutation and permutation-inversion symmetry notation,
vibration-rotation spectroscopy and electronic spectroscopy
Torsion–rotation global analysis of the first three torsional states (νt = 0, 1, 2) and terahertz database for methanol
Stimulated by recent THz measurements of the methanol spectrum in one of our laboratories, undertaken in support of NASA programs related to the Herschel Space Observatory (HSO) and the Atacama Large Millimeter Array (ALMA), we have carried out a global analysis of available microwave and high-resolution infrared data for the first three torsional states (νt = 0, 1, 2), and for J values up to 30. This global fit of approximately 5600 frequency measurements and 19 000 Fourier transform far infrared (FTFIR) wavenumber measurements to 119 parameters reaches the estimated experimental measurement accuracy for the FTFIR transitions, and about twice the estimated experimental measurement accuracy for the microwave, submillimeter-wave, and terahertz transitions. The present fit is essentially a continuation of our earlier work, but we have greatly expanded our previous data set and have added a large number of new torsion–rotation interaction terms to the Hamiltonian in our previously used computer program. The results, together with a number of calculated (but unmeasured) transitions, including their line strength, estimated uncertainty, and lower state energy, are made available in the supplementary material as a database formatted to be useful for astronomical searches. Some discussion of several open spectroscopic problems, e.g., (i) an improved notation for the numerous parameters in the torsion–rotation Hamiltonian, (ii) possible causes of the failure to fit frequency measurements to the estimated measurement uncertainty, and (iii) pitfalls to be avoided when intercomparing apparently identical parameters from the internal axis method and the rho axis method are also given
Rotationally induced Penning ionization of ultracold photoassociated helium dimers
We have studied photoassociation of metastable \tripS helium atoms near the
\tripS-\tripP asymptote by both ion detection in a magneto-optical trap and
trap-loss measurements in a magnetic trap. A detailed comparison between the
results of the two experiments gives insight into the mechanism of the Penning
ionization process. We have identified four series of resonances corresponding
to vibrational molecular levels belonging to different rotational states in two
potentials. The corresponding spin states become quasi-purely quintet at small
interatomic distance, and Penning ionization is inhibited by spin conservation
rules. Only a weak rotational coupling is responsible for the contamination by
singlet spin states leading to a detectable ion signal. However, for one of
these series Bose statistics does not enable the rotational coupling and the
series detected through trap-loss does not give rise to sufficient ionization
for detection.Comment: 7 pages, 4 figures, submitted to EuroPhysics Letter
Mechanism, dynamics, and biological existence of multistability in a large class of bursting neurons
Multistability, the coexistence of multiple attractors in a dynamical system,
is explored in bursting nerve cells. A modeling study is performed to show that
a large class of bursting systems, as defined by a shared topology when
represented as dynamical systems, is inherently suited to support
multistability. We derive the bifurcation structure and parametric trends
leading to multistability in these systems. Evidence for the existence of
multirhythmic behavior in neurons of the aquatic mollusc Aplysia californica
that is consistent with our proposed mechanism is presented. Although these
experimental results are preliminary, they indicate that single neurons may be
capable of dynamically storing information for longer time scales than
typically attributed to nonsynaptic mechanisms.Comment: 24 pages, 8 figure
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