Temporal variations of petrological characteristics of Tangkil and Rajabasa volcanic rocks, Indonesia

Tangkil and Rajabasa Volcanoes are neighbouring subduction-zone volcanoes located on the southeast tip of Sumatra Island (Sunda Strait, Indonesia). Stratigraphic correlation of lavas in Tangkil-Rajabasa volcanic area was established from field observations, morphological analysis, and K-Ar dating analysis. Detailed petrography and geochemical data of two and eleven lava units from Tangkil and Rajabasa, respectively, were then integrated with the stratigraphy to show the temporal variations. Early stage (> 4.3 Ma) effusives of Tangkil Volcano are dacitic to rhyolitic (67-71 wt. % SiO2; Tklf), whereas the later (c. 4.3 Ma) rocks are basalt to basaltic andesite (c. 52 wt. % SiO2; Tklm). Tangkil shows bimodal magmatism, of which the felsic endmember is > 71 wt. % SiO2 and < 0.1 wt. % MgO. Lavas of Rajabasa Volcano are comparatively younger (c. 0.3 to 0.1 Ma) with compositions ranging from basalt to andesite (51-62 wt. % SiO2; Rbs). Chemical variations of Rajabasa accounts for the interactions of at least three endmembers: Mg-rich medium-K basalt magma, low-Mg medium-K basalt magma, and high-K andesitic magma. During the long evolution of Rbs magma system, the temporal chemistry shows rising-falling variation in SiO2 and MgO indicating the three magmas were active. The felsic endmember magma of Rajabasa is fixed in composition (at ~62 wt. % SiO2; ~2.2 wt. % MgO). The rocks from the last Tklf and Rbs indicate open system processes by containing plagioclase and pyroxene phenocrysts that show resorption of evolved core and overgrowth of less evolved mantle. The multiple zones of dissolution-overgrowth in plagioclase crystals and the fluctuating trend in temporal whole-rock variation suggest that the changes of magmatic condition in temperature, H2O, or chemical composition were repetitive

Characteristics of ash particles from the maar complex of Lamongan Volcanic Field (LVF), East Java, Indonesia: How textural features and magma composition control ash morphology

The Lamongan Volcanic Field (LVF), East Java, Indonesia, has experienced numerous maar eruptions, producing varied properties and morphologies of ash particles. This study conducted textural, morphometric, and geochemical analyses of the juvenile particles to elucidate the factors governing their heterogeneous characteristics. Two distinct types of juvenile ash were identified: A (black and brown ash) and B (orange-brown ash), reflecting different fragmentation processes. The blocky to slightly elongate shapes of juvenile A across heterogenous basaltic compositions (resulting in variable textures, rheological properties, and/or cooling histories) highlight the phreatomagmatic process as the primary control of their shape. In contrast, the irregular-fluidal shapes of juvenile B particles indicate magmatic fragmentation of basaltic andesite magma. This study reveals that variable magma properties yield diverse ash components, yet fragmentation dynamics govern pyroclast shapes in the LVF maar complex. Our integrated approach emphasizes the importance of considering multiple variables when interpreting heterogeneous volcanic ash deposits

Genesis of magmatic ilmenite ores associated with the Mazua ultramafic intrusion, NE Mozambique

The Mazua ultramafic intrusion is among the most promising intrusions hosting Fe-Ti oxide ores in Mozambique. Fe-Ti oxide ores are mainly composed of ilmenite occurring as lenses, veins and layers, either massive or disseminated in hornblende pyroxenite. This study discusses the nature and origin of the intrusion and related ilmenite ore body on the basis of whole-rock and mineral chemistry. Textural and structural evidences support a cumulate origin for these rocks, including the occurrence of relict cumulate textures, layering of alternating oxides and silicate-rich rocks, and size-grading of silicate-rich layers. Primary magmatic features have, however, largely been overprinted by subsolidus processes. The occurrence of the cumulate assemblage (Fe-Ti oxides and clinopyroxene), without plagioclase and olivine, suggests that the magma underwent differentiation before its emplacement. The evolved magmatic nature of the intrusion is consistent with the calculated Mg-number of approximately 50 for the melt in equilibrium with clinopyroxene crystals. The high TiO2 concentrations (>4 wt%) of the evolved magma, by differentiation, are interpreted as the main factors controlling the crystallization of Fe-Ti oxides. We propose that the ores formed from crystallization and settling of Fe-Ti oxide minerals from an evolved basaltic magma. This model is consistent with (1) the occurrence of Fe-Ti oxides and clinopyroxene as cumulates in relation to the coexisting amphibole, (2) the layering structures of alternating oxides and silicate matrix, (3) the scarcity of apatite supported by the extremely low whole-rock P2O5 concentrations and (4) the restricted occurrence of ore veins, excluding the formation from immiscible oxide melts

Primitive layered gabbros from fast-spreading lower oceanic crust

Three-quarters of the oceanic crust formed at fast-spreading ridges is composed of plutonic rocks whose mineral assemblages, textures and compositions record the history of melt transport and crystallization between the mantle and the sea floor. Despite the importance of these rocks, sampling them in situ is extremely challenging owing to the overlying dykes and lavas. This means that models for understanding the formation of the lower crust are based largely on geophysical studies and ancient analogues (ophiolites) that did not form at typical mid-ocean ridges. Here we describe cored intervals of primitive, modally layered gabbroic rocks from the lower plutonic crust formed at a fast-spreading ridge, sampled by the Integrated Ocean Drilling Program at the Hess Deep rift. Centimetre-scale, modally layered rocks, some of which have a strong layering-parallel foliation, confirm a long-held belief that such rocks are a key constituent of the lower oceanic crust formed at fast-spreading ridges. Geochemical analysis of these primitive lower plutonic rocks-in combination with previous geochemical data for shallow-level plutonic rocks, sheeted dykes and lavas-provides the most completely constrained estimate of the bulk composition of fast-spreading oceanic crust so far. Simple crystallization models using this bulk crustal composition as the parental melt accurately predict the bulk composition of both the lavas and the plutonic rocks. However, the recovered plutonic rocks show early crystallization of orthopyroxene, which is not predicted by current models of melt extraction from the mantle and mid-ocean-ridge basalt differentiation. The simplest explanation of this observation is that compositionally diverse melts are extracted from the mantle and partly crystallize before mixing to produce the more homogeneous magmas that erupt

室戸岬斑れい岩体の層状構造の起源 - 固液境界層内での流体相の移動によるクリスタルマッシュの再融解 -

京都大学0048新制・課程博士博士(理学)甲第15159号理博第3524号新制||理||1514(附属図書館)27637京都大学大学院理学研究科地球惑星科学専攻(主査)教授 小畑 正明, 教授 平島 崇男, 准教授 下林 典正学位規則第4条第1項該当Doctor of ScienceKyoto UniversityDA

Petrogenesis of the Morobe Granodiorite and their shoshonitic mafic microgranular enclaves in Maramuni arc, Papua New Guinea

The Miocene tectonics of Papua New Guinea, where subduction, arc-continent collision, and changes in subduction direction are considered to have occurred, is very complex and various tectonic models have been proposed. The Maramuni arc, active in the Miocene, is composed of a chain of granitoid bodies. As the chain-like distribution indicates the generation of igneous activities in a wide range of the same tectonic settings, the study of the Maramuni arc magmatism is important for elucidating the geologic events of the time. We provide data on the petrological and geochemical characteristics of the Morobe Granodiorite that form part of the Maramuni arc. The Morobe Granodiorite consists of metaluminous I-type granitoids, belonging to the medium-K to high-K series. The whole-rock major element variations in the granitoids can be explained by the fractionation of hornblende and plagioclase. They are generally within the composition range of experimental partial melts of amphibolites, and the whole-rock trace element compositions have characteristics of slab failure magma rather than arc. This suggests that the granitoids were generated by partial melting of the torn slab after slab failure. The mafic microgranular enclaves (MMEs) in the granitoids are classified as shoshonite, and their trace element compositions suggest that they were formed by partial melting of phlogopite-bearing mantle. The occurrences of native gold and barite within the MME show that MMEs transport Au from the mantle metasomatized by slab-derived sediment melt and/or fluid to the crustal magma chamber

Zoning and resorption of plagioclase in a layered gabbro, as a petrographic indicator of magmatic differentiation

The Murotomisaki Gabbroic Intrusion is a sill-like layered gabbro emplaced in sedimentary strata of Tertiary age in southwest Japan. The zoning (including resorption structures) and the compositional variations of plagioclase from throughout the intrusion were studied, and it was found that the zoning pattern may be classified into four types, which may well correlated with the hosting rock types, the mode of occurrences and their stratigraphic positions in the intrusion. The plagioclase zoning was successfully decoded, and the sequence of events that took place during the magmatic differentiation was deduced and further interpreted in the context of a stratified basal boundary layer slowly ascending in a solidifying magma body. It was shown that various layered structures – modal layering, podiform gabbroic pegmatites and anorthositic layers – observed in the Murotomisaki Gabbro were formed within the moving basal boundary layer by flushing of H2O-rich fluid and fractionated silicate melts from below. By the fluxing of hydrous fluids, plagioclase crystals preferentially dissolved and then melt fraction increased in the basal boundary layer. Under these circumstances, plagioclase-rich fractionated melts diapirically segregated from the crystal pile. Calcic plagioclases, which are out of equilibrium in the central part of the intrusion, may have originated from the basal boundary layer in this manner