U–Th–Pb zircon geochronology by ID-TIMS, SIMS, and laser ablation ICP-MS: recipes, interpretations, and opportunities

The chronologic record encoded in accessory minerals, based on the radioactive decay of U and Th, is indispensable to extract quantitative process rates over timescales encompassing Earth's evolution from the Hadean to the Holocene, and extending from terrestrial to extra-terrestrial realms. We have essentially three different U–Pb dating tools at hand, a high-precision, whole-grain bulk technique (isotope-dilution thermal ionization mass spectrometry, ID-TIMS), and two high-spatial resolution but less precise in-situ techniques (secondary ion mass spectrometry, SIMS, and laser ablation inductively-coupled plasma mass spectrometry, LA-ICP-MS), all of which are predominantly applied to the mineral zircon. All three have reached a technological and methodological maturity in data quality and quantity, but interpretational differences, which are often common (albeit at different temporal and spatial scales) to all isotopic dating techniques, remain largely unresolved. The choice to use one of these techniques should be governed by the scientific question posed, such as (1) the duration of the geological process to be resolved; (2) the size and abundance of the material to be analyzed; (3) the complexity of the sample material and of the geological history to be resolved; and (4) the number of dates needed to address the question. Our compilation demonstrates that, ultimately, the highest confidence geochronological data will not only result from the optimal choice of appropriate analysis technique and the accurate treatment of analytical and interpretational complexities, but also require comprehensive sample characterization that employs the full gamut of textural (e.g., cathodoluminescence, charge contrast imaging, electron backscatter diffraction) and compositional (e.g., trace element, stable and radiogenic isotope) analysis

Synchronous N-S and E-W extension at the Tibet-to-Himalaya transition in NW Bhutan

Despite ~50 Myr of continuous continent-continent collision, contractional structures in the Himalayan-Tibetan orogen are today limited to the northern and southern margins of the system, while extension dominates much of the interior. On the Tibetan Plateau, Cenozoic E-W extension has been accommodated by strike-slip faults and extensional grabens, while N-S extension at the Tibet-to-Himalaya transition has been accommodated by the South Tibetan fault system (STFS). The genetic relationship between N-S and E-W extension is disputed, although age constraints indicate temporal overlap of at least 7 Myr. In NW Bhutan the two intersect where the STFS basal detachment is cut by the Yadong cross structure (YCS), an extensional half graben that provides a rare opportunity to constrain relative timings. We report U-Pb zircon dates from four STFS footwall leucogranites consistent with episodic magmatism during the middle-late Miocene and in situ U(-Th)-Pb monazite and xenotime dates from three metasedimentary rocks ranging from late Oligocene to middle Miocene. We suggest that amphibolite facies footwall metamorphism was ongoing at the time the basal STFS detachment initiated as a ductile structure in the middle-late Miocene. Late-stage granitic intrusions may reflect footwall melting during extensional exhumation along the STFS, but post-metamorphic and post-intrusion fabrics suggest that most displacement occurred after emplacement of the youngest granites. Some of the oldest YCS-related fabrics are found in a deformed 14 Ma leucogranite, implying middle Miocene ductile deformation. This observation, along with evidence for subsequent brittle YCS deformation, suggests that N-S and E-W extensional structures in the area had protracted and overlapping deformation histories

Petrogenesis of rare-metal pegmatites in high-grade metamorphic terranes: a case study from the Lewisian Gneiss Complex of north-west Scotland

Many rare metals used today are derived from granitic pegmatites, but debate continues about the origin of these rocks. It is clear that some pegmatites represent the most highly fractionated products of a parental granite body, whilst others have formed by anatexis of local crust. However, the importance of these two processes in the formation of rare-metal pegmatites is not always evident. The Lewisian Gneiss Complex of NW Scotland comprises Archaean meta-igneous gneisses which were highly reworked during accretional and collisional events in the Palaeoproterozoic (Laxfordian orogeny). Crustal thickening and subsequent decompression led to melting and the formation of abundant granitic and pegmatitic sheets in many parts of the Lewisian Gneiss Complex. This paper presents new petrological, geochemical and age data for those pegmatites and shows that, whilst the majority are barren biotite-magnetite granitic pegmatites, a few muscovite-garnet (rare-metal) pegmatites are present. These are mainly intruded into a belt of Palaeoproterozoic metasedimentary and meta-igneous rocks known as the Harris Granulite Belt. The rare-metal pegmatites are distinct in their mineralogy, containing garnet and muscovite, with local tourmaline and a range of accessory minerals including columbite and tantalite. In contrast, the biotite-magnetite pegmatites have biotite and magnetite as their main mafic components. The rare-metal pegmatites are also distinguished by their bulk-rock and mineral chemistry, including a more peraluminous character and enrichments in Rb, Li, Cs, Be, Nb and Ta. New U-Pb ages (c. 1690–1710 Ma) suggest that these rare-metal pegmatites are within the age range of nearby biotite-magnetite pegmatites, indicating that similar genetic processes could have been responsible for their formation. The peraluminous nature of the rare-metal pegmatites strongly points towards a metasedimentary source. Notably, within the Lewisian Gneiss Complex, such pegmatites are only found in areas where a metasedimentary source is available. The evidence thus points towards all the Laxfordian pegmatites being formed by a process of crustal anatexis, with the formation of rare-metal pegmatites being largely controlled by source composition rather than solely by genetic process. This is in keeping with previous studies that have also challenged the widely accepted model that all rare-metal pegmatites are formed by fractionation from a parental granite, and raises questions about the origin of other mineralised pegmatites worldwide

The 1.23 Ga Fjellhovdane rhyolite, Grøssæ-Totak; a new age within the Telemark supracrustals, southern Norway

The Grøssæ-Totak supracrustal belt is part of the several-kilometre thick Telemark supracrustal sequences that are exposed in southern Norway. Deposition of the Telemark supracrustals spans the period between Telemarkian continental growth at ~1.52-1.48 Ga and Sveconorwegian orogenesis associated with continental collision at ~1.1-0.9 Ga. The timing of deposition is largely constrained by U-Pb geochronology of detrital zircons in sedimentary units, and igneous zircons within felsic volcanics. A younger Supergroup that has been referred to as the Sveconorwegian Supergroup comprises depositional ages younger than 1.16 Ga; units of the Grøssae-Totak belt have been mapped as part of this Supergroup. This study presents a new U-Pb age of 1233 ± 29 Ma for the Fjellhovdane rhyolite, one of the lowermost units within the Grøssæ-Totak belt; this age suggests that at least the lower part of this sequence is not part of the Sveconorwegian Supergroup, but formed in an earlier volcano-sedimentary basin that is correlative in age to the Sæsvatn-Valldal and Setesdal supracrustal belts that occur to the west and south respectively. The geochemistry of the Fjellhovdane rhyolite is compatible with crustal melting of previously-formed supra-subduction rocks, as has been advocated for the Sæsvatn-Valldal rhyolites

Geochemical evidence of Milankovitch cycles in Atlantic Ocean ferromanganese crusts

Hydrogenetic ferromanganese crusts are considered a faithful record of the isotopic composition of seawater influenced by weathering processes of continental masses. Given their ubiquitous presence in all oceans of the planet at depths of 400–7000 meters, they form one of the most well-distributed and accessible records of water-mass mixing and climate. However, their slow accumulation rate and poor age constraints have to date limited their use to explore 100 ka paleoclimatic phenomena. Here it is shown how the Pb isotope signature and major element content of a Fe-Mn crust from the north-east Atlantic responded to changes in the intensity and geographic extent of monsoonal rainfall over West Africa, as controlled by climatic precession during the Paleocene. The studied high-spatial resolution (4 μm) laser-ablation multi-collector inductively coupled plasma mass spectrometer (LA-MC-ICP-MS) Pb isotope data is a nearly 2 order of magnitude improvement in spatial and temporal resolution compared to micro-drill subsamples. The record demonstrates cyclicity of the 206Pb/204Pb and 208, 207Pb/206Pb ratios at the scale of single Fe-Mn oxide laminae, in conjunction with variations in the Fe/Mn ratio, Al, Si and Ti content. Time-frequency analysis and astronomical tuning of the Pb isotope data demonstrates the imprint of climatic precession (∼20 ka) modulated by eccentricity (∼100 and 405 ka), yielding growth rates of 1.5–3.5 mm/Ma consistent with previous chemostratigraphic age models. In this context, boreal summer at the perihelion causes stronger insolation over West Africa, resulting in more intense and geographically extended monsoonal rainfalls compared to aphelion boreal summer conditions. This, in turn, influences the balance between the weathering endmembers feeding the north-east Atlantic basin. These results provide a new approach for calibrating Fe-Mn crust records to astronomical solutions, and allow their isotopic and chemical archive to be exploited with an improved temporal resolution of 1000–5000 years

Development of a correlated Fe‐Mn Crust stratigraphy using Pb and Nd isotopes and its application to paleoceanographic reconstruction in the Atlantic

Eight ferromanganese crust samples spanning the complete depth range of Tropic Seamount in the north‐east Atlantic were analysed for Pb and Nd isotopes to reconstruct water mass origin and mixing over the last 75 Ma. Pb isotopes were determined by LA‐MC‐ICP‐MS, which enables the rapid production of large, high spatial‐resolution datasets. This makes it possible to precisely correlate stratigraphy between different samples, compare contemporaneous layers, and create a composite record given the abundance of hiatuses in crusts. Pb and Nd isotope data show the influence of various oceanic and continental end‐members in the north‐east Atlantic Ocean. This reflects its evolution from a restricted, isolated basins in the Late Cretaceous with influxes from the Tethys Ocean, to an increasingly well‐mixed, large‐scale basin, with a dominant Southern Ocean signature until the Miocene. Less‐radiogenic Nd isotope signatures suggest Labrador Sea Water influenced the north‐east Atlantic basin as early as 17‐15 Ma, flowing through a northern route such as the Charlie‐Gibbs Fracture Zone. Pb and Nd isotopes highlight the increasing influence of Saharan aeolian dust input about 7 Ma, imparting a less‐radiogenic excursion to the binary mixing between North Atlantic water masses and riverine discharge from West and Central Africa. This highlights the influence of aeolian dust input on the open ocean Pb and Nd budget, and supports an early stage of North African aridification in the Late Miocene. This signature is overprinted about 3 Ma to the present by a strong North Atlantic Deep Water signature following the onset of Northern Hemisphere glaciation

Geology, geochemistry and geochronology of the Songwe Hill carbonatite, Malawi

This is the author accepted manuscript. The final version is available from Elsevier via the DOI in this record.Songwe Hill, Malawi, is one of the least studied carbonatites but has now become particularly important as it hosts a relatively large rare earth deposit. The results of new mapping, petrography, geochemistry and geochronology indicate that the 0.8 km diameter Songwe Hill is distinct from the other Chilwa Alkaline Province carbonatites in that it intruded the side of the much larger (4 x 6 km) and slightly older (134.6 ± 4.4 Ma) Mauze nepheline syenite and then evolved through three different carbonatite compositions (C1–C3). Early C1 carbonatite is scarce and is composed of medium–coarse-grained calcite carbonatite containing zircons with a U–Pb age of 132.9 ± 6.7 Ma. It is similar to magmatic carbonatite in other carbonatite complexes at Chilwa Island and Tundulu in the Chilwa Alkaline Province and others worldwide. The fine-grained calcite carbonatite (C2) is the most abundant stage at Songwe Hill, followed by a more REE- and Sr-rich ferroan calcite carbonatite (C3). Both stages C2 and C3 display evidence of extensive (carbo)-hydrothermal overprinting that has produced apatite enriched in HREE (<2000 ppm Y) and, in C3, synchysite-(Ce). The final stages comprise HREE-rich apatite fluorite veins and Mn-Fe-rich veins. Widespread brecciation and incorporation of fenite into carbonatite, brittle fracturing, rounded clasts and a fenite carapace at the top of the hill indicate a shallow level of emplacement into the crust. This shallow intrusion level acted as a reservoir for multiple stages of carbonatite-derived fluid and HREE-enriched apatite mineralisation as well as LREE-enriched synchysite-(Ce). The close proximity and similar age of the large Mauze nepheline syenite suggests it may have acted as a heat source driving a hydrothermal system that has differentiated Songwe Hill from other Chilwa carbonatites.Thanks are due to A. Lemon, A. Zabula, C. Mcheka, I. Nkukumila (Mkango Resources Ltd.), É. Deady (BGS) and P. Armitage (Paul Armitage Consulting Ltd.) for logistical support and enthusiastic discussions in the field. This contribution benefitted from reviews by Jindřich Kynický and Ray Macdonald, as well as anonymous reviewers, who we thank for their time and insightful comments. This work was funded by a NERC BGS studentship to SBF (NEE/J50318/1; S208), the NERC SoS RARE consortium (NE/M011429/1) and by Mkango Resources Ltd. AGG publishes with the permission of the Executive Director of the British Geological Survey (NERC)

Geochronology and structure of the eastern margin of the Tanzania Craton east of Dodoma

The precise position, nature and U-Pb zircon geochronology of the eastern margin of the Tanzania Craton has been studied in the Mpwapwa area, some 60 km east of Dodoma, central Tanzania, in a number of field transects over a ca. 45 km strike length of the craton margin. The rocks to the east of the Tanzania Craton in this area either belong to the Palaeoproterozoic Usagaran belt, or the “Western Granulite” terrane of the Neoproterozoic East African Orogen, according to different authors. The eastern part of the craton is underlain by typical Neoarchaean migmatitic grey granodioritic orthogneisses dated by ICP-MS at 2674 ± 73 Ma. There is a gradual increase in strain eastwards in these rocks, culminating in a 1 to 2 km wide, locally imbricated, ductile thrust/shear zone with mylonites indicating an oblique top-to-the-NW, transpressional sense of movement. East of the craton-edge shear zone, a series of high-grade supracrustal rocks are termed the “Mpwapwa Group”, in view of uncertain age and regional lithostratigraphic correlations. There is an apparent east-west lithological zonation of Mpwapwa Group parallel to the craton margin shear zone. In the west, immediately adjacent to the craton, the group consists of typical “shelf facies” metasediments (marbles, calc-silicates, quartzites etc.). U-Pb dating of detrital zircons from two Mpwapwa Group quartzite samples from this marginal zone contain only Archaean detritus, constraining their maximum depositional age to > ca. 2.6 Ga and suggesting that the group is Neoarchaean in age. The shelf rocks pass eastwards into garnet and kyanite-bearing semi-pelitic gneisses interlayered with bimodal mafic-felsic gneisses, where the mafic amphibolite gneisses may represent meta-basalts and the felsic rocks may have meta-rhyolite, -granite or –psammite protoliths. Massive garnet-clinopyroxene amphibolite layers in the Mpwapwa Group gneisses may have been intrusive mafic sills and possibly correlate with the Palaeoproterozoic Isimani Suite, which outcrops south of the study area and includes 2 Ga eclogites. Zircons from a quartzo-feldsapthic gneiss sample from the bimodal gneisses were dated and showed it to be a probable Neoarchaean rock which underwent metamorphism during the Palaeoproterozoic Usagaran event at ca. 1950 Ma. This event was broadly coeval with subduction, closure of an ocean basin and eclogite formation further south and led to the initial juxtaposition of the two Archaean blocks. The metamorphism probably dates the tectonic event when the Archaean Mpwapwa Group rocks were juxtaposed against the orthogneissic Tanzania Craton. The Mpwapwa Group was intruded by weakly foliated biotite granite at 1871 ± 35 Ma. Zircons in the granite have metamorphic rims dated between 550 and 650 Ma that grew during the East African orogenic event

Using zircon in mafic migmatites to disentangle complex high-grade gneiss terrains – Terrane spotting in the Lewisian complex, NW Scotland

This research was part of SF’s PhD studies, and he acknowledges a 600 Year Anniversary Scholarship from the University of St Andrews. Analyses were funded through grants with EIMF (IMF545/1114) and NIGL (IP-1473-1114). Fieldwork was funded by NERC grant NE/J021822/1 to PAC. TEJ acknowledges funding from Australian Research Council Discovery Project DP200101104 and support from the State Key Laboratory for Geological Processes and Mineral Resources, China University of Geosciences, Wuhan (Open Fund GPMR201903). PAC acknowledges support from Australian Research Council grant FL160100168. CJH acknowledges support from Leverhulme Trust grants RPG-2015-422 and EM-2017-047\4.The zircon record of complex high-grade gneiss terrains is key to interpreting their tectonothermal evolution. Typically, such studies focus on zircon-rich, felsic rocks, which commonly have a complicated (partial melting, inheritance, partial dissolution, and reprecipitation) zircon record. Here we show that metamorphosed mafic rocks and their retained partial melts (i.e. in situ leucosomes) provide a record of the evolution of crustal blocks that is simpler and easier to interpret. We apply our method to the Archaean high-grade gneisses of the iconic Lewisian complex of NW Scotland and use it to test the proposed terrane model that is based largely on zircon geochronology. Our work focusses on the mafic migmatites of the central region, where we identified the long-established metamorphic age clusters of ca. 2.75 Ga and 2.5 Ga, as well as ca. 2.85 Ga protolith ages. A key finding is that these ages are recognised across both putative terrane blocks of the central region previously proposed to record different tectonothermal histories. Our oldest (inherited) ages are similar to those within other blocks outside the central region. Thus, all these blocks likely share a common pre-metamorphic history, questioning the validity of the terrane model for the Lewisian complex. We demonstrate that mafic lithologies provide a powerful tool for identifying key stages in the polyphase evolution of metamorphic complexes that typify Earth’s earliest rock records and offer additional context for assessing Earth’s geodynamic evolution.PostprintPeer reviewe