XPS Characterization of Friedel-Crafts Cross-Linked Polystyrene

The combination of a difunctional alkylating agent, either hydroxymethylbenzyl chloride or α,α′-dichloroxylene with polystyrene or high-impact polystyrene together with a Friedel-Crafts catalyst, 2-ethylhexyldiphenylphosphate, and an amine to react with hydrogen chloride has been studied by X-ray photoelectron spectroscopy. The results confirm what had been suggested from previous investigations using thermogravimetric analysis; cross-linking of the polymer occurs as the temperature is raised and the alcohol-containing alkylating agent gives a greater amount of cross-linking than does the dichloro compound

AnyTool: Self-Reflective, Hierarchical Agents for Large-Scale API Calls

We introduce AnyTool, a large language model agent designed to revolutionize the utilization of a vast array of tools in addressing user queries. We utilize over 16,000 APIs from Rapid API, operating under the assumption that a subset of these APIs could potentially resolve the queries. AnyTool primarily incorporates three elements: an API retriever with a hierarchical structure, a solver aimed at resolving user queries using a selected set of API candidates, and a self-reflection mechanism, which re-activates AnyTool if the initial solution proves impracticable. AnyTool is powered by the function calling feature of GPT-4, eliminating the need for training external modules. We also revisit the evaluation protocol introduced by previous works and identify a limitation in this protocol that leads to an artificially high pass rate. By revising the evaluation protocol to better reflect practical application scenarios, we introduce an additional benchmark, termed AnyToolBench. Experiments across various datasets demonstrate the superiority of our AnyTool over strong baselines such as ToolLLM and a GPT-4 variant tailored for tool utilization. For instance, AnyTool outperforms ToolLLM by +35.4% in terms of average pass rate on ToolBench. Code will be available at https://github.com/dyabel/AnyTool

Rethinking Quality of Experience for Metaverse Services: A Consumer-based Economics Perspective

The Metaverse is considered to be one prototype of the next-generation Internet, which contains people's expectations for the future world. However, the academic discussion of the Metaverse still mainly focused on the system technical design, and few research studied Metaverse challenges from the perspective of consumers, i.e., Metaverse users. One difficulty is that the analysis from the consumer's perspective requires interdisciplinary theoretical framework and quantifiable Quality of Experience (QoE) measurements. In this article, pioneering from consumers' point of view, we explore an interaction between Metaverse system design and consumer behaviors. Specifically, we rethink the QoE and propose an interdisciplinary framework that encompasses both the Metaverse service providers (MSPs) and consumer considerations. From the macro perspective, we introduce a joint optimization scheme that simultaneously considers the Metaverse system design, consumers' utility, and profitability of the MSPs. From the micro perspective, we advocate the Willingness-to-Pay (WTP) as an easy-to-implement QoE measurement for future Metaverse system studies. To illustrate the usability of the proposed integrated framework, a use case of Metaverse, i.e., virtual traveling, is presented. We show that our framework can benefit the MSPs in offering competitive and economical service design to consumers while maximizing the profit

On The Robustness of Channel Allocation in Joint Radar And Communication Systems: An Auction Approach

Joint radar and communication (JRC) is a promising technique for spectrum re-utilization, which enables radar sensing and data transmission to operate on the same frequencies and the same devices. However, due to the multi-objective property of JRC systems, channel allocation to JRC nodes should be carefully designed to maximize system performance. Additionally, because of the broadcast nature of wireless signals, a watchful adversary, i.e., a warden, can detect ongoing transmissions and attack the system. Thus, we develop a covert JRC system that minimizes the detection probability by wardens, in which friendly jammers are deployed to improve the covertness of the JRC nodes during radar sensing and data transmission operations. Furthermore, we propose a robust multi-item auction design for channel allocation for such a JRC system that considers the uncertainty in bids. The proposed auction mechanism achieves the properties of truthfulness, individual rationality, budget feasibility, and computational efficiency. The simulations clearly show the benefits of our design to support covert JRC systems and to provide incentive to the JRC nodes in obtaining spectrum, in which the auction-based channel allocation mechanism is robust against perturbations in the bids, which is highly effective for JRC nodes working in uncertain environments

Short-term interval prediction of PV power based on quantile regression-stacking model and tree-structured parzen estimator optimization algorithm

In recent years, the photovoltaic (PV) industry has grown rapidly and the scale of grid-connected PV continues to increase. The random and fluctuating nature of PV power output is beginning to threaten the safe and stable operation of the power system. PV power interval forecasting can provide more comprehensive information to power system decision makers and help to achieve risk control and risk decision. PV power interval forecasting is of great importance to power systems. Therefore, in this study, a Quantile Regression-Stacking (QR-Stacking) model is proposed to implement PV power interval prediction. This integrated model uses three models, extreme gradient boosting (Xgboost), light gradient boosting machine (LightGBM) and categorical boosting (CatBoost), as the base learners and Quantile Regression-Long and Short Term Memory (QR-LSTM) model as the meta-learner. It is worth noting that in order to determine the hyperparameters of the three base learners and one meta-learner, the optimal hyperparameters of the model are searched using a Tree-structured Parzen Estimator (TPE) optimization algorithm based on Bayesian ideas. Meanwhile, the correlation coefficient is applied to determine the input characteristics of the model. Finally, the validity of the proposed model is verified using the actual data of a PV plant in China

Vision-based Semantic Communications for Metaverse Services: A Contest Theoretic Approach

The popularity of Metaverse as an entertainment, social, and work platform has led to a great need for seamless avatar integration in the virtual world. In Metaverse, avatars must be updated and rendered to reflect users' behaviour. Achieving real-time synchronization between the virtual bilocation and the user is complex, placing high demands on the Metaverse Service Provider (MSP)'s rendering resource allocation scheme. To tackle this issue, we propose a semantic communication framework that leverages contest theory to model the interactions between users and MSPs and determine optimal resource allocation for each user. To reduce the consumption of network resources in wireless transmission, we use the semantic communication technique to reduce the amount of data to be transmitted. Under our simulation settings, the encoded semantic data only contains 51 bytes of skeleton coordinates instead of the image size of 8.243 megabytes. Moreover, we implement Deep Q-Network to optimize reward settings for maximum performance and efficient resource allocation. With the optimal reward setting, users are incentivized to select their respective suitable uploading frequency, reducing down-sampling loss due to rendering resource constraints by 66.076\% compared with the traditional average distribution method. The framework provides a novel solution to resource allocation for avatar association in VR environments, ensuring a smooth and immersive experience for all users.Comment: 6 pages,7figure