One-step vapour-phase formation of patternable, electrically conductive, superamphiphobic coatings on fibrous materials

Patternable, electrically conductive coatings having a superhydrophobic and superoleophobic surface have been prepared by one-step vapour-phase polymerisation of polypyrrole in the presence of a fluorinated alkyl silane directly on fibrous substrates. The coated fabrics showed a surface resistance of 0.5-0.8 k&Omega; □-1 with water and hexadecane contact angles of 165&deg; and 154&deg;, respectively.<br /

Directional water-transport fabrics achieved by wettablity gradient from superhydrophobicity to hydrophilicity

In this study, we demonstrate that fabrics having a wettability gradient from superhydrophobic to hydrophilic through the thickness direction show a novel directional water transfer effect: water can transfer only from the superhydrophobic to the hydrophilic side, but not in the opposite direction unless an external force is applied. A sol-gel technology was used to prepare a superhydrophobic coating on fabrics, and the coated fabrics showed water contact-angle as high as 165&deg;. When the coated fabric was subjected to a photochemistry treatment from one fabric side, the irradiated surface turned hydrophilic permanently, while the back side still maintained the superhydrophobicity. The treated fabric can transfer water droplet rapidly from hydrophobic to hydrophilic side, and the pressure allowing water breakthrough the fabric is different considerably between the two fabric sides. The directional water transfer effect is also affected by the wettability gradient. Such a directional water transfer coating may be useful to develop new functional fabrics for defence applications

Superphobicity/philicity janus fabrics with Switchable, spontaneous, directional transport ability to water and oil fluids

Herein we demonstrate that switchable, spontaneous, directional-transport ability to both water and oil fluids can be created on fabric materials through wet-chemistry coating and successive UV irradiation treatment. When the fabric showed directional transport to a liquid, it prevented liquids of higher surface tension from penetration, but allowed liquids of lower surface tension to permeate, from either side. The directional transport ability can be switched from one fluid to another simply by heating the fabric at an elevated temperature and then re-irradiating the fabric with UV light for required period of time. By attaching liquid drops vertically upwards to a horizontally-laid fabric, we further demonstrated that this novel directional fluid transport was an automatic process driven by surface property alone, irrespective of gravity's effect. This novel fabric may be useful for development of “smart” textiles and functional membranes for various applications