Design and modelling of mobile thermal energy storage (M−TES) using structured composite phase change material modules

This study concerns with a modelling led-design of a novel mobile thermal energy storage (M−TES) device aimed to address off-site industrial waste heat recovery and reuse in the UK. For the first time, salt-based composite phase change material (CPCM) modules were employed as the M−TES medium, utilizing air for charging and discharging. Two-dimensional (2D) and three-dimensional (3D) computational fluid dynamics (CFD) models were initially developed and validated against experimental data. The 2D model was used for parametric study to determine critical M−TES dimensions, followed by the 3D model for a comprehensive evaluation of thermal performance of the M−TES device. Key parameters examined included temperature uniformity within CPCM modules, evolution of air temperatures at the inlet and outlet, thermal storage capacities, charging/discharging rates, and specific efficiencies defined as heat transfer efficiencies and charging/discharging efficiencies throughout a complete cycle. The results under baseline conditions demonstrated that the M−TES device stored nearly 400 MJ of heat with a TES density of 560 kJ/kg after 10 h of charging, achieving an average CPCM temperature of 662 K. Approximately 97 % of the stored heat was released with the average outlet air temperature exceeding 468 K during the subsequent 10-hour discharging period. This work preliminarily verified the feasibility of the novel M−TES concept for integrating industrial thermal processing decarbonization with domestic heat supply

Pressure Pulsation Signal Analysis for Centrifugal Compressor Blade Crack Determination

Blade is a key piece of component for centrifugal compressor. But blade crack could usually occur as blade suffers from the effect of centrifugal forces, gas pressure, friction force, and so on. It could lead to blade failure and centrifugal compressor closing down. Therefore, it is important for blade crack early warning. It is difficult to determine blade crack as the information is weak. In this research, a pressure pulsation (PP) sensor installed in vicinity to the crack area is used to determine blade crack according to blade vibration transfer process analysis. As it cannot show the blade crack information clearly, signal analysis and empirical mode decomposition (EMD) are investigated for feature extraction and early warning. Firstly, signal filter is carried on PP signal around blade passing frequency (BPF) based on working process analysis. Then, envelope analysis is carried on to filter the BPF. In the end, EMD is carried on to determine the characteristic frequency (CF) for blade crack. Dynamic strain sensor is installed on the blade to determine the crack CF. Simulation and experimental investigation are carried on to verify the effectiveness of this method. The results show that this method can be helpful for blade crack classification for centrifugal compressors

Effects of different altitudes on the structure and properties of potato starch

The main element influencing the quality of potato starch is the environment. To investigate the effects of different altitude cultivation locations on the molecular structure and physicochemical properties of starch, two potato varieties, Jiusen No.1 B1 and Qingshu No.9 B2, were planted in three different altitude zones: A1 at low altitude (Chongzhou 450 m), A2 at middle altitude (Xichang 2800 m), and A3 at high altitude (Litang 3650 m). The results showed that the average volume, number, surface area diameter, average branched polymerization degree, crystallinity, and gelatinization temperature of two potato granules in high altitude areas were significantly lower than those in middle and low altitude areas were, and the gelatinization performance of potato starch was affected according to the correlation of starch structure characteristics. Potato starch with more short-branched chains and less long branched chains resulted in a lower gelatinization temperature in high altitude areas. The results showed that Jiusen No. 1 and Qingshu No. 9 were mainly affected by accumulated radiation and accumulated rainfall in Litang, a high altitude area, and by effective accumulated temperature in Xichang, a middle altitude area. This study quantified the influence of meteorological factors on the main starch quality of potato tubers. The results can be used as a theoretical basis for the scientific planting of high-quality potatoes

Discharging behavior of a fixed-bed thermochemical reactor under different charging conditions: modelling and experimental validation

Thermochemical heat storage has attracted significant attention in recent years due to potential advantages associated with very high-energy density at the material scale and its suitability for long-duration energy storage because of almost zero loss during storage. Despite the potential, thermochemical heat storage technologies are still in the early stage of development and little has been reported on thermochemical reactors. In this paper, our recent work on the charging and discharging behavior of a fixed-bed thermochemical reactor is reported. Silica gels were used as the sorbent for the experimental work. An effective model was established to numerically study the effect of different charging conditions on the discharging behavior of the reactor, which was found to have a maximum deviation of 10.08% in terms of the root mean square error compared with the experimental results. The experimentally validated modelling also showed that the discharging temperature lift increased by 5.84 times by changing the flow direction of the air in the discharging process when the charging level was at 20%. At a charging termination temperature of 51.25 °C, the maximum discharging temperature was increased by 2.35 °C by reducing the charging flow velocity from 0.64 m/s to 0.21 m/s. An increase in the charging temperature and a decrease in the air humidity increased the maximum discharging outlet temperature lift by 3.37 and 1.89 times, respectively

Crystallization Control of N,N′-Dioctyl Perylene Diimide by Amphiphilic Block Copolymers Containing poly(3-Hexylthiophene) and Polyethylene Glycol

The preparation of micron- to nanometer-sized functional materials with well-defined shapes and packing is a key process to their applications. There are many ways to control the crystal growth of organic semiconductors. Adding polymer additives has been proven a robust strategy to optimize semiconductor crystal structure and the corresponding optoelectronic properties. We have found that poly(3-hexylthiophene) (P3HT) can effectively regulate the crystallization behavior of N,N′-dioctyl perylene diimide (C8PDI). In this study, we combined P3HT and polyethylene glycol (PEG) to amphiphilic block copolymers and studied the crystallization modification effect of these block copolymers. It is found that the crystallization modification effect of the block copolymers is retained and gradually enhanced with P3HT content. The length of C8PDI crystals were well controlled from 2 to 0.4 μm, and the width from 210 to 35 nm. On the other hand, due to the water solubility of PEG block, crystalline PEG-b-P3HT/C8PDI micelles in water were successfully prepared, and this water phase colloid could be stable for more than 2 weeks, which provides a new way to prepare pollution-free aqueous organic semiconductor inks for printing electronic devices