Age of the Rotoehu Ash. Comment.

Suggests that the article by Whitehead & Ditchburn (1994), although presenting useful new data on 230Th/232Th analyses, is flawed and misleading in suggesting that the Rotoiti Tephra is considerably younger than c. 50 ka

Parent materials of Yellow-brown loams in the Waikato-Coromandel district.

The yellow-brown loams of the Waikato-Coromandel region are derived from weathered airfall volcanic materials. These materials may be either direct airfall deposits, or erosion products of these deposits, described as reworked ash in some publications. In the erosion products small amounts of other rocks may be included in the parent materials, and these additions may modify to a slight degree the chemical and physical properties of the soil as a yellow-brown loam. In larger amounts these additions result in the formation of intergrades to yellow-brown earths or gley soils

¹⁴C dating of modern marine and estuarine shellfish

We measured the ¹⁴C content of 36 living marine molluscs from Tairua Harbour and the rocky coast on the Coromandel Peninsula of New Zealand. We identified species suitable for radiocarbon dating and show that the open marine intertidal zone is enriched in ¹⁴C compared to the open marine subtidal zone or estuary. We also found a uniform ¹⁴C distribution in the Tairua Harbour, by analyzing samples of the estuarine bivalveAustrovenus stutchburyi collected up to 5 km from the harbor entrance

Single-Step Quantum Search Using Problem Structure

The structure of satisfiability problems is used to improve search algorithms for quantum computers and reduce their required coherence times by using only a single coherent evaluation of problem properties. The structure of random k-SAT allows determining the asymptotic average behavior of these algorithms, showing they improve on quantum algorithms, such as amplitude amplification, that ignore detailed problem structure but remain exponential for hard problem instances. Compared to good classical methods, the algorithm performs better, on average, for weakly and highly constrained problems but worse for hard cases. The analytic techniques introduced here also apply to other quantum algorithms, supplementing the limited evaluation possible with classical simulations and showing how quantum computing can use ensemble properties of NP search problems.Comment: 39 pages, 12 figures. Revision describes further improvement with multiple steps (section 7). See also http://www.parc.xerox.com/dynamics/www/quantum.htm

Ages of 24 widespread tephras erupted since 30,000 years ago in New Zealand, with re-evaluation of the timing and palaeoclimatic implications of the Lateglacial cool episode recorded at Kaipo bog

Tephras are important for the NZ-INTIMATE project because they link all three records comprising the composite inter-regional stratotype developed for the New Zealand climate event stratigraphy (NZ-CES). Here we firstly report new calendar ages for 24 widespread marker tephras erupted since 30,000 calendar (cal.) years ago in New Zealand to help facilitate their use as chronostratigraphic dating tools for the NZ-CES and for other palaeoenvironmental and geological applications. The selected tephras comprise 12 rhyolitic tephras from Taupo, nine rhyolitic tephras from Okataina, one peralkaline rhyolitic tephra from Tuhua, and one andesitic tephra each from Tongariro and Egmont/Taranaki volcanic centres. Age models for the tephras were obtained using three methods: (i) 14C-based wiggle-match dating of wood from trees killed by volcanic eruptions (these dates published previously); (ii) flexible depositional modelling of a high-resolution 14C-dated age-depth sequence at Kaipo bog using two Bayesian-based modelling programs, Bacon and OxCal's P_Sequence function, and the IntCal09 data set (with SH offset correction -44 ± 17 yr); and (iii) calibration of 14C ages using OxCal's Tau_Boundary function and the SHCal04 and IntCal09 data sets. Our preferred dates or calibrated ages for the 24 tephras are as follows (youngest to oldest, all mid-point or mean ages of 95% probability ranges): Kaharoa AD 1314 ± 12; Taupo (Unit Y) AD 232 ± 10; Mapara (Unit X) 2059 ± 118 cal. yr BP; Whakaipo (Unit V) 2800 ± 60 cal. yr BP; Waimihia (Unit S) 3401 ± 108 cal. yr BP; Stent (Unit Q) 4322 ± 112 cal. yr BP; Unit K 5111 ± 210 cal. yr BP; Whakatane 5526 ± 145 cal. yr BP; Tuhua 6577 ± 547 cal. yr BP; Mamaku 7940 ± 257 cal. yr BP; Rotoma 9423 ± 120 cal. yr BP; Opepe (Unit E) 9991 ± 160 cal. yr BP; Poronui (Unit C) 11,170 ± 115 cal. yr BP; Karapiti (Unit B) 11,460 ± 172 cal. yr BP; Okupata 11,767 ± 192 cal. yr BP; Konini (bed b) 11,880 ± 183 cal. yr BP; Waiohau 14,009 ± 155 cal. yr BP; Rotorua 15,635 ± 412 cal. yr BP; Rerewhakaaitu 17,496 ± 462 cal. yr BP; Okareka 21,858 ± 290 cal. yr BP; Te Rere 25,171 ± 964 cal. yr BP; Kawakawa/Oruanui 25,358 ± 162 cal. yr BP; Poihipi 28,446 ± 670 cal. yr BP; and Okaia 28,621 ± 1428 cal. yr BP. Secondly, we have re-dated the start and end of the Lateglacial cool episode (climate event NZce-3 in the NZ-CES), previously referred to as the Lateglacial climate reversal, as defined at Kaipo bog in eastern North Island, New Zealand, using both Bacon and OxCal P_Sequence modelling with the IntCal09 data set. The ca 1200-yr-long cool episode, indicated by a lithostratigraphic change in the Kaipo peat sequence to grey mud with lowered carbon content, and a high-resolution pollen-derived cooling signal, began 13,739 ± 125 cal. yr BP and ended 12,550 ± 140 cal. yr BP (mid-point ages of the 95% highest posterior density regions, Bacon modelling). The OxCal modelling, generating almost identical ages, confirmed these ages. The Lateglacial cool episode (ca 13.8-12.6 cal. ka BP) thus overlaps a large part of the entire Antarctic Cold Reversal chronozone (ca 14.1-12.4 cal. ka BP or ca 14.6-12.8 cal. ka BP), and an early part of the Greenland Stadial-1 (Younger Dryas) chronozone (ca 12.9-11.7 cal. ka BP). The timing of the Lateglacial cool episode at Kaipo is broadly consistent with the latitudinal patterns in the Antarctic Cold Reversal signal suggested for the New Zealand archipelago from marine and terrestrial records, and with records from southern South America

Revised calendar date for the Taupo eruption derived by ¹⁴C wiggle-matching using a New Zealand kauri ¹⁴C calibration data set

Taupo volcano in central North Island, New Zealand, is the most frequently active and productive rhyolite volcano on Earth. Its latest explosive activity about 1800 years ago generated the spectacular Taupo eruption, the most violent eruption known in the world in the last 5000 years. We present here a new accurate and precise eruption date of AD 232 ± 5 (1718 ± 5 cal. BP) for the Taupo event. This date was derived by wiggle-matching 25 high-precision ¹⁴C dates from decadal samples of Phyllocladus trichomanoides from the Pureora buried forest near Lake Taupo against the high-precision, first-millennium AD subfossil Agathis australis (kauri) calibration data set constructed by the Waikato Radiocarbon Laboratory. It shows that postulated dates for the eruption estimated previously from Greenland ice-core records (AD 181 ± 2) and putative historical records of unusual atmospheric phenomena in ancient Rome and China (c. AD 186) are both untenable. However, although their conclusion of a zero north–south ¹⁴C offset is erroneous, and their data exhibit a laboratory bias of about 38 years (too young), Sparks et al. (Sparks RJ, Melhuish WH, McKee JWA, Ogden J, Palmer JG and Molloy BPJ (1995) ¹⁴C calibration in the Southern Hemisphere and the date of the last Taupo eruption: Evidence from tree-ring sequences. Radiocarbon 37: 155–163) correctly utilized the Northern Hemisphere calibration curve of Stuiver and Becker (Stuiver M and Becker B (1993) High-precision decadal calibration of the radiocarbon timescale, AD 1950–6000 BC. Radiocarbon 35: 35–65) to obtain an accurate wiggle-match date for the eruption identical to ours but less precise (AD 232 ± 15). Our results demonstrate that high-agreement levels, indicated by either agreement indices or χ² data, obtained from a ¹⁴C wiggle-match do not necessarily mean that age models are accurate. We also show that laboratory bias, if suspected, can be mitigated by applying the reservoir offset function with an appropriate error value (e.g. 0 ± 40 years). Ages for eruptives such as Taupo tephra that are based upon individual ¹⁴C dates should be considered as approximate only, and confined ideally to short-lived material (e.g. seeds, leaves, small branches or the outer rings of larger trees)

Distal occurrence of mid-Holocene Whakatane Tephra on the Chatham Islands, New Zealand, and potential for cryptotephra studies

The Whakatane Tephra, a rhyolitic tephra erupted ca. 5500 cal. BP from Okataina Volcanic Centre, central North Island, has been identified on the Chatham Islands which lie ˜900 km east of Christchurch, New Zealand. The visible tephra layer, ˜5 mm in thickness and preserved within peat on Pitt Island, was identified using both radiocarbon dating and analysis of glass shards by electron microprobe. Whakatane Tephra is the first Holocene tephra to be identified on the Chatham Islands, and it is the most distal Holocene tephra yet recorded in the New Zealand region, being ˜850 km from source. The Pitt Island occurrence extends the tephra's dispersal area markedly, by an order of magnitude, possibly to ˜300,000 km2. An estimated dispersal index (D) of approximately 105 km2 indicates that the eruption generated a very high plinian column, possibly exceeding ˜30 km in height, with strong winds blowing the ash plume southeastwards. This new discovery of distal Whakatane Tephra as a thin but visible layer strongly implies that cryptotephras are likely to be preserved on the Chatham Islands and within adjacent ocean floor sediments. Therefore the potential exists to develop enhanced cryptotephrostratigraphic records from these distal areas, which in turn would help facilitate precise correlation via tephrochronology of palaeoenvironmental records (such as NZ-INTIMATE) from mainland New Zealand, the southwest Pacific Ocean, and the Chatham Islands

Tephrostratigraphy arid chronology of the kaipo lagoon, an 11, 500 year-old montane peat bog in urewera national Park, New Zealand

Eleven well-preserved Holocene tephras occur interbedded with peat in the Kaipo Lagoon bog in Urewera National Park, North Island. They are identified chiefly by their field appearance, stratigraphy, and ferromagnesian mineralogy. Glass shards from one tephra (Hinemaiaia) were analysed by electron microprobe.The tephras originate from the Taupo, Okataina, and Tongariro Volcanic Centres and, from youngest to oldest, are: Kaharoa Ash, Taupo Pumice, Mapara Tephra, Waimihia Lapilli, Hinemaiaia Tephra, Whakatane Ash, Rotoma Ash, Opepe Tephra, Poronui Tephra, Karapiti Tephra, and Okupata Tephra. Thirteen new radiocarbon ages were obtained on six of the tephras (old TY2, years B.P.): Waimihia, 3, 250 ± 70 (Wk498), 2, 910 ± 60 (Wk499), 3, 040 ± 50 (Wk500); Hinemaiaia and Whakatane, 4, 490 ± 60 (Wk496), 4, 530 ± 60 (Wk497); Whakatane, 4, 860 ± 70 (Wk501); Rotoma, 5, 440 ± 170 (Wk493), 7, 380 ± 80 (Wk494), 7, 560 ± 100 (Wk495) (Wk493 -495 are all considered anomalously young); Opepe, 8, 7lO ± 80 (Wk492); Poronui, 10, 160 ± 130 (Wk351), 9, 960 ± 90 (Wk352), 9, 560 ± 80 (Wk491). Estimated ages, assuming constant sedimentation rates, for Karapiti Tephra and Okupata Tephra are 10, 100 and 10, 300 years, respectively. Two peat horizons below the Okupata Tephra were dated at (old TY2) 10, 600 ± 90 years B.P. (Wk263) and 11, 500 ± 80 years B.P. (Wk264) and date the initial growth of the Kaipo Lagoon bog. Peat accumulation rates have been slow (average 0.19 mm/year) but variable.The identification and dating of the tephras at Kaipo extends their known distribution in eastern North Island, and improves their potential usefulness as isochronous stratigraphic marker units

Observations of energetic low frequency current fluctuations in the Charlie-Gibbs fracture zone

Also published as: Journal of Marine Research 36 (1978): 725-734Relatively energetic low frequency fluctuations in horizontal currents are found to exist below the thermocline in the northern trough of the Charlie-Gibbs Fracture Zone. For example, deep eddy kinetic energy levels there are about twice as large as those observed at similar relative depths in the MODE-I region. Eddy kinetic energies are about 2-10 times larger than mean kinetic energies. The vertical distribution of eddy kinetic energy is frequency dependent, increasing toward the thermocline for the longer time scales and intensifying toward the bottom at higher frequencies. In addition to the expected mean westward motion of Norwegian Sea Overflow Water through the northern trough of the fracture, rather consistent mean southward flow is observed at a depth immediately above the overflow.Prepared f or the Office of Naval Research under Contract N00014-76-C-0197; NR 083- 400

SHCal04 Southern Hemisphere Calibration, 0–11.0 cal kyr BP

Recent measurements on dendrochronologically-dated wood from the Southern Hemisphere have shown that there are differences between the structural form of the radiocarbon calibration curves from each hemisphere. Thus, it is desirable, when possible, to use calibration data obtained from secure dendrochronologically-dated wood from the corresponding hemisphere. In this paper, we outline the recent work and point the reader to the internationally recommended data set that should be used for future calibration of Southern Hemisphere ¹⁴C dates