Evolutionary Algorithms for

Many real-world problems involve two types of problem difficulty: i) multiple, conflicting objectives and ii) a highly complex search space. On the one hand, instead of a single optimal solution competing goals give rise to a set of compromise solutions, generally denoted as Pareto-optimal. In the absence of preference information, none of the corresponding trade-offs can be said to be better than the others. On the other hand, the search space can be too large and too complex to be solved by exact methods. Thus, efficient optimization strategies are required that are able to deal with both difficulties. Evolutionary algorithms possess several characteristics that are desirable for this kind of problem and make them preferable to classical optimization methods. In fact, various evolutionary approaches to multiobjective optimization have been proposed since 1985, capable of searching for multiple Paretooptimal solutions concurrently in a single simulation run. However, in spite of this variety, there is a lack of extensive comparative studies in the literature. Therefore, it has remained open up to now

Iron isotope fractionation during pedogenesis in redoximorphic soils

Stable Fe isotopes provide a potential new tool for tracing the biogeochemical cycle of Fe in soils. Iron isotope ratios in two redoximorphic soils were measured by multicollector inductively coupled plasma mass spectrometry to study the relationships between pedogenic Fe transformation and redistribution processes, and mass-dependent fractionation of Fe isotopes. Redoximorphic Fe depletion and enrichment zones were sampled in addition to the bulk soil samples. A three-step sequential extraction procedure was used to separate different Fe pools, which were examined in addition to total soil digests. Significant enrichments of heavy Fe isotopes of about 0.3¿ in d57Fe were found in total soil digests of Fe-depleted zones compared with bulk soil samples and were explained by the preferential removal of light isotopes, presumably during microbially mediated Fe oxide dissolution under anoxic conditions. Accordingly, pedogenic Fe enrichment zones were found to be slightly enriched in light Fe isotopes. Distinct Fe isotope variations of >1¿ in d57Fe were found between different Fe pools within soil samples, specifically enrichments of light isotopes in pedogenic oxides contrasting with heavy isotope signatures of residual silicate-bound Fe. Our data demonstrate that pedogenic Fe transformations in redoximorphic soils are linked to isotope fractionation, revealing greater mobility of lighter Fe isotopes compared with heavier isotopes during pedogenesis. No simple quantitative relationship between Fe depletion and isotope fractionation could be inferred, however. Our findings provide new insights into the behavior of Fe isotopes in soils and contribute to the development of Fe isotopes as a tracer for the biogeochemical Fe cycle

[Diplom von Ernst Gloor]

Es handelt sich um das Diplom als technischer Chemiker der Eidgenössischen Technischen Hochschule Zürich an Ernst Gloor von Basel; ohne UnterschriftenDie Eidgenössische Technische Hochschul

Aufnahmen der Bauschule am Genfersee und in St.Gallen

unter Leitung von Karl MoserAm Kopf des Titelblattes: Eidgen. Techn. Hochschul

Tessinkorrektion : Gegenwärtiger Stand der künstlichen und natürlichen Bewaldung des ehemaligen Flussbettes

Reproduktion nach dem Original des Geobot. Institutes, Bl. VK 1