162 research outputs found
Quasi L₂/L₂ Hankel Norms and L₂/L₂ Hankel Norm/Operator of Sampled-Data Systems
This article is relevant to appropriately defining the L₂/L₂ Hankel norm of sampled-data systems through setting a general time instant Θ at which past and future are to be separated and introducing the associated quasi L₂/L₂ Hankel operator/norm at Θ . We first provide a method for computing the quasi L₂/L₂ Hankel norm for each Θ , which is carried out by introducing a shifted variant of the standard lifting technique for sampled-data systems. In particular, it is shown that the quasi L₂/L₂ Hankel norm can be represented as the l₂/l₂ Hankel norm of a Θ -dependent discrete-time system. It is further shown that an equivalent discretization of the generalized plant exists, which means that the aforementioned discrete-time system can be represented as the feedback connection of the discretized plant and the same discrete-time controller as the one in the sampled-data system. It is also shown that the supremum of the quasi L₂/L₂ Hankel norms at Θ belonging to a sampling interval is actually attained as the maximum, which means that what is called a critical instant always exists and the L₂/L₂ Hankel operator is always definable (as the quasi L₂/L₂ Hankel operator at the critical instant). Finally, we illustrate those theoretical developments through a numerical example
Deoxofluorination of Activated Carbon Electrode with Sulfur Tetrafluoride for Electric Double Layer Capacitor
Electric double layer capacitors are energy storage devices with advantages of fast charge-discharge and long life span. Surface modification of activated carbon electrodes is an effective way to improve their performance. For this purpose, deoxofluorination of activated carbon with sulfur tetrafluoride was attempted in this study. Successful introduction of fluorine atom on the surface of activated carbon resulted in the increased capacitance and improved coulombic efficiencies in electrochemical tests for electric double layer capacitors
Deoxofluorination of graphite oxide with sulfur tetrafluoride
In this study, deoxofluorination of graphite oxide (GO) using sulfur tetrafluoride (SF₄) at a temperature below the decomposition temperature of GO (∼200 °C) was investigated for the first time with and without HF catalysis. At 25 °C, the reaction proceeds only at high SF₄ pressures (≥8 atm) when not catalyzed by HF and at 1 atm SF₄ under the catalysis of HF. The degree of fluorination increases at higher temperatures and SF₄ pressures. Hydroxy and carbonyl groups are replaced by fluorine following this reaction, and SF₄ and SOF₂ are introduced into the product, while the epoxy groups do not react. SF₄ and SOF₂ in the products are removed by washing with water. The obtained product is less hygroscopic than pristine GO owing to the hydrophobicity of the fluorine atom. The interlayer separation of the product is increased after deoxofluorination despite the smaller size of fluorine than the sizes of the oxygen-containing functional groups. When compared with direct fluorination using elemental fluorine, deoxofluorination using SF₄ has the advantages of high reactivity with hydroxy groups and the preservation of the carbon skeleton, and the reaction results in the formation of graphite oxyfluoride
Discharge Characteristic of Fluorinated Graphene-like Graphite as a Cathode of Lithium Primary Battery
The 64th special issue "Frontiers of Carbon Materials"Graphene-like graphite prepared by heating graphite oxide under vacuum at 800 degrees C was fluorinated by elemental fluorine in the presence of HF at room temperature. The interlayer spacing of the resulting material was 0.639 nm and it showed CxF type characteristics. The fluorine content of it (x = 1.7) was higher than that obtained from natural graphite (x = 2.3). The discharge capacity of it as a cathode of lithium primary battery reached 940 mAhg(-1) at a low current density, which was 50% larger than the theoretical capacity based on the 100% discharge of fluorine
Potassium single cation ionic liquid electrolyte for potassium-ion batteries
Potassium-ion batteries (PIBs) are a promising post-lithium-ion battery (LIB), as their resources are abundant and low-cost and may have a higher voltage than LIBs. However, the high operating voltage and extremely high reactivity of potassium metal require a chemically safe electrolyte with oxidative and reductive stabilities. In this study, a potassium single cation ionic liquid (K-SCIL), which contains only K⁺ as the cationic species and has a high electrochemical stability, low flammability, and low vapor pressure, is developed as an electrolyte for PIBs. The mixture of potassium bis(fluorosulfonyl)amide and potassium (fluorosulfonyl)(trifluoromethylsulfonyl)amide at a molar ratio of 55:45 had the lowest melting point of 67 °C. The K⁺ concentration in this K-SCIL is high (8.5 mol dm⁻³ at 90 °C) due to the absence of solvents and bulky organic cations. In addition, the electrochemical window is as wide as 5.6 V, which enables the construction of PIBs with a high energy density. A high current density can be achieved with this K-SCIL, owing to the absence of a K⁺ concentration gradient. The electrolyte was successfully used with a graphite negative electrode, enabling the reversible intercalation/deintercalation of K⁺, as confirmed by X-ray diffraction
Bone marrow transplantation improves outcome in a mouse model of congenital muscular dystrophy
AbstractWe examined whether pathogenesis in dystrophin-deficient (mdx) mice and laminin-α2-deficient (dy) mice is ameliorated by bone marrow transplantation (BMT). Green fluorescent protein (GFP) mice were used as donors. In mdx mice, BMT failed to produce any significant differences in muscle pathology, although some GFP-positive fibers with restored dystrophin expression were observed. In contrast, in the dy mice, BMT led to a significant increase in lifespan and an increase in growth rate, muscle strength, and respiratory function. We conclude that BMT improved outcome in dy mice but not mdx mice
Improvement of Electrochemical Stability Using the Eutectic Composition of a Ternary Molten Salt System for Highly Concentrated Electrolytes for Na-Ion Batteries
The increase in the concentration of electrolytes for secondary batteries has significant advantages in terms of physicochemical and electrochemical performance. This study aims to explore a highly concentrated electrolyte for Na-ion batteries using a ternary salt system. The eutectic composition of the Na[N(SO₂F₂]–Na[N(SO₂F)(SO₂CF₃)]–Na[SO₃CF₃] ternary molten salt system increases solubility into an organic solvent, enabling the use of highly concentrated electrolytes for Na-ion batteries. The ternary salt system achieved concentrations of 5.0 m (m = mol kg⁻¹) with propylene carbonate (PC), 2.9 m with dimethoxyethane, 2.0 m with ethylene carbonate/dimethyl carbonate, and 3.9 m with ethylene carbonate/diethyl carbonate. The highly concentrated electrolyte of 5.0 m in PC suppressed Al corrosion and exhibited better oxidative stability. Stable electrochemical performance using hard carbon/NaCrO₂ in the full-cell configuration introduces a new strategy to explore highly concentrated electrolytes for secondary batteries
Near-optimal stochastic MIMO signal detection with a mixture of t-distribution prior
Multiple-input multiple-output (MIMO) systems will play a crucial role in
future wireless communication, but improving their signal detection performance
to increase transmission efficiency remains a challenge. To address this issue,
we propose extending the discrete signal detection problem in MIMO systems to a
continuous one and applying the Hamiltonian Monte Carlo method, an efficient
Markov chain Monte Carlo algorithm. In our previous studies, we have used a
mixture of normal distributions for the prior distribution. In this study, we
propose using a mixture of t-distributions, which further improves detection
performance. Based on our theoretical analysis and computer simulations, the
proposed method can achieve near-optimal signal detection with polynomial
computational complexity. This high-performance and practical MIMO signal
detection could contribute to the development of the 6th-generation mobile
network.Comment: to be published in the 2023 IEEE Global Communications Conference
(GLOBECOM
Efficacy of tension-free vaginal tape compared with transobturator tape in the treatment of stress urinary incontinence in women: analysis of learning curve, perioperative changes of voiding function
<p>Abstract</p> <p>Background</p> <p>In this study, by comparing TVT surgery and TOT surgery for stress urinary incontinence in women, the characteristics and learning curves of both operative methods were studied.</p> <p>Methods</p> <p>A total of 83 women with stress urinary incontinence treated with tension-free vaginal tape (TVT) (n = 38) or transobturator tape (TOT) (n = 45) at Saiseikai Central Hospital between April 2004 and September 2009 were included. We compare the outcomes and learning curves between TVT surgery and TOT surgery. In statistical analysis, Student's t test, Fisher's exact test, and Mann-Whitney's U test were used.</p> <p>Results</p> <p>The surgical durations were 37.4 ± 15.7 minutes with TVT surgery and 31.0 ± 8.3 minutes with TOT surgery. A longer period of time was required for TVT surgery (p = 0.025). The residual urine at post-operative day 1 was higher in TVT surgery (25.9 ± 44.2 ml) than in TOT surgery (10.6 ± 19.2 ml) (p = 0.0452). The surgical duration of TVT surgery was shortened after the operator had performed 15 operations (p = 0.019).</p> <p>Conclusions</p> <p>In comparison of TVT surgery and TOT surgery, the surgical duration of TVT surgery was longer and the residual urine of TVT surgery was higher at post-operative day 1. Surgical experience could shorten the duration of TVT surgery.</p
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