酸化物ガラスの塩基度と XPS による O1s 化学シフトの相関に関する考察

O1s binding energy measured by X-ray photoelectron spectroscopy (XPS) is candidate as a new tool to determine a new scale of Lewis basicity of oxide ions in glass. Some mathematical expressions for the basicity or XPS chemical shift, such as charge parameter and optical basicity, were compared with the experimental O1s binding energy in binary alkali oxide glasses. The expressions so far in use needed some modification in parameters. A new empirical expression introduced in this paper gives a new concept and universal scale of basicity

Extension of a Simplified Calculational Method for Sigma Bonded Systems to Hydrogen Bonding among Elements of the Second and Third Rows

Physic

Theoretical Investigation of the Bond-Bond Interaction Force Constant in XF2 Molecules

Chemistr