20 research outputs found
An Origin of Complicated Infrared Spectra of Perfluoroalkyl Compounds Involving a Normal Alkyl Group
Perfluoroalkyl (Rf) compounds containing a normal alkyl group often yield highly complicated infrared (IR) spectra especially in the CāF stretching vibration (Ī½CāF) region. To reveal the reason behind this, the IR p-polarized multiple-angle incidence resolution spectrometry (pMAIRS) is employed to measure a monolayer of CF3(CF2)9(CH2)3COOH deposited on a silicon substrate. The compound is known to spontaneously aggregate to form a molecular assembly with the closest packing, in which the molecules are oriented perpendicular to the substrate. The IR pMAIRS spectra apparently prove that the complexity of the Ī½CāF region is due to the normal alkyl part directly connected to the Rf group because the carbons in the Rf group are vibrated as a coupled oscillator, and the oscillation of the alkyl part propagates to the Rf part along the molecular axis
Carbonācarbon bond cleavage for Cu-mediated aromatic trifluoromethylations and pentafluoroethylations
This short review highlights the copper-mediated fluoroalkylation using perfluoroalkylated carboxylic acid derivatives. Carbonācarbon bond cleavage of perfluoroalkylated carboxylic acid derivatives takes place in fluoroalkylation reactions at high temperature (150ā200 Ā°C) or under basic conditions to generate fluoroalkyl anion sources for the formation of fluoroalkylcopper species. The fluoroalkylation reactions, which proceed through decarboxylation or tetrahedral intermediates, are useful protocols for the synthesis of fluoroalkylated aromatics
Copper-Promoted Cross-Coupling Reactions for the Synthesis of Aryl(difluoromethyl)phosphonates Using Trimethylsilyl(difluoromethyl)phosphonate
A convenient and effective route for the synthesis of aryl(difluoromethyl)phosphonates has been developed based on cross-coupling reactions. Upon treatment with a stoichiometric amount (or a catalytic amount in some cases) of CuI and CsF, aryl iodides reacted smoothly with (silyldifluoromethyl)phosphonates to give the corresponding aryl(difluoromethyl)phosphonates in good yields
A Trial toward the Synthesis of Ī³-Fluorinated Ī²-Amino-Ī±-thiohydroxyamino Acid:Ā A Finding of Desulfurizative CāC Bond Formation in Thio-Wittig-Type Rearrangement of S
Rhodium(I)-Catalyzed Successive Double Cleavage of CarbonāCarbon Bonds of Strained Spiro Cyclobutanones
Fluorous Property of a Short Perfluoroalkyl-Containing Compound Realized by Self-Assembled Monolayer Technique on a Silicon Substrate
Fluorous properties represented by water-and-oil repellency are perfluoroalkyl (Rf) compound-specific characteristics, which are widely used for surface coating of glass, electronic devices and textiles for preventing water and grease fouling. According to the stratified dipole-arrays (SDA) theory, the minimum Rf length of (CFā)ā is theoretically necessary for realizing fluorous properties. Unfortunately, however, production of compounds involving this chemical unit is strictly banned because of concerns of environmental pollution, which is a big dilemma. Here, we show that the fluorous properties can be realized by self-assembled monolayer (SAM) even with a short Rf-containing compound, since the SAM technique makes the best use of the self-aggregation property of the Rf groups, and it readily makes the molecules immobile