1,389 research outputs found

    Photoionization of Co+^{+} and electron-impact excitation of Co2+^{2+} using the Dirac R-matrix method

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    Modelling of massive stars and supernovae (SNe) plays a crucial role in understanding galaxies. From this modelling we can derive fundamental constraints on stellar evolution, mass-loss processes, mixing, and the products of nucleosynthesis. Proper account must be taken of all important processes that populate and depopulate the levels (collisional excitation, de-excitation, ionization, recombination, photoionization, bound-bound processes). For the analysis of Type Ia SNe and core collapse SNe (Types Ib, Ic and II) Fe group elements are particularly important. Unfortunately little data is currently available and most noticeably absent are the photoionization cross-sections for the Fe-peaks which have high abundances in SNe. Important interactions for both photoionization and electron-impact excitation are calculated using the relativistic Dirac Atomic RR-matrix Codes (DARC) for low ionization stages of cobalt. All results are calculated up to photon energies of 45 eV and electron energies up to 20 eV. The wavefunction representation of Co III has been generated using GRASP0 by including the dominant 3d7^7, 3d6^6[4s, 4p], 3p4^43d9^9 and 3p6^63d9^9 configurations, resulting in 292 fine structure levels. Electron-impact collision strengths and Maxwellian averaged effective collision strengths across a wide range of astrophysically relevant temperatures are computed for Co III. In addition, statistically weighted level-resolved ground and metastable photoionization cross-sections are presented for Co II and compared directly with existing work.Comment: 11 pages, 8 figures and 4 table

    Zinc - 1,10-phenanthroline complexes and their analytical application

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    The use of ultraviolet spectrophotometry for quantitative inorganic analytical purposes has long remained unexploited. An extremely large number of complexes of metals have characteristic absorption properties in the visible portion of the spectrum and many colorimetric methods of analysis depend upon this fact. With the present availability of ultraviolet spectrophotometric equipment the charachteristic absorption properties of many colorless metallic complexes in the ultraviolet region of the spectrum should as conveniently be capable of similar utilization

    pH electrode performance under automated management conditions

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    pH is frequently measured in laboratories, but to have confidence in the results it is necessary to know that it was measured properly. For an electrode to give accurate results it must be treated well and calibrated correctly. In this paper, an automated system for pH measurement is described; the system uses the operational pH scale and calibrates using two or three buffer solutions, taking proper account of the effects of temperature on the system. The system can be programmed with standard methods and procedures to ensure that the electrode gives the best possible performance. Calibrations and measurements within the system are reproducible, and the automated system is more robust than the manual pH meter, and requires less operator time
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