132 research outputs found

    Fracture test of a Gothic ribbed vault

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    A Gothic ribbed vault has been built at the School of Architecture of Madrid in order to investigate the construction complexities of this kind of vaults. The ribbed vault is described in the manuscript of Alonso de Vandelvira, and its shape was reconstructed making using the drawings this architect from the 16th century. The fracture test was carried on by loading the central keystone of the vault until its collapse took place. The experiment was filmed and by doing so, it was possible to observe the failure mechanism of the vault. At the same time, it was interesting to compare this collapse experience with the results obtained using two different me-thods. First, a stability calculation was carried out through graphic statics, and secondly a calcu-lation was performed using the rigid-block analysis method. The focus of this paper is to show and analyze the results of both studies

    Origin of orbital ferromagnetism and giant magnetic anisotropy at the nanoscale

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    The origin of orbital magnetism recently observed in different nanostructured films and particles is discussed as a consequence of spin-orbit coupling. It is shown that contact potentials induced at the thin film surface by broken symmetries, as domain boundaries in self-assembled monolayers, lead to orbital states that in some cases are of large radius. The component of the angular momentum normal to the surface can reach very high values that decrease the total energy by decreasing spin-orbit interaction energy. Intraorbital ferromagnetic spin correlations induce orbital momenta alignment. The estimated values of the magnetic moments per atom are in good agreement with the experimental observations in thiol capped gold films and nanoparticles

    Structural and catalytic properties of lanthanide (La, Eu, Gd) doped ceria

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    Este documento es la última versión enviada a la revista con los ajustes finales después de la revisión de los evaluadores.In this work, Ce0.9M0.1O2−δ mixed oxides (M=La, Eu and Gd) were synthesized by coprecipitation. Independent of the dopant cation, the obtained solids maintain the F-type crystalline structure, characteristic of CeO2 (fluorite structure) without phase segregation. The ceria lattice expands depending on the ionic radii of the dopant cation, as indicated by X-ray diffraction studies. This effect also agrees with the observed shift of the F2g Raman vibrational mode. The presence of the dopant cations in the ceria lattice increases the concentration of structural oxygen vacancies and the reducibility of the redox pair Ce4+/Ce3+. All synthesized materials show higher catalytic activity for the CO oxidation reaction than that of bare CeO2, being Eu-doped solid the one with the best catalytic performances despite of its lower surface area.Junta de Andalucía con su apoyo a la unidad TEP106Ministerio de Ciencia e Innovación mediante la subvención del proyecto: ENE2009-14522-C05-01 cofinanciado con fondos FEDER de la Unión EuropeaPrograma Alban a través de la beca predoctoral de W.Y. Hernández: (E06D101739CO

    Ataxia and focal dystonia in Kallmann syndrome

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    A case of Kallmann syndrome (KS) associated with rare neurological manifestations is presented. Cerebellar ataxia probably caused by a small posterior fossa and a focal dystonia affecting the left lower limb expand the spectrum of neurological manifestations occurring in KS. Further studies are needed to better understand these manifestations

    Inorganic phosphate modulates the expression of the NaPi-2a transporter in the trans -golgi network and the interaction with PIST in the proximal tubule

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    Inorganic phosphate (Pi) homeostasis is maintained by the tight regulation of renal Pi excretion versus reabsorption rates that are in turn modulated by adjusting the number of Pi transporters (mainly NaPi-2a) in the proximal tubules. In response to some hormones and a high dietary Pi content, NaPi-2a is endocytosed and degraded in the lysosomes; however, we show here that some NaPi-2amolecules are targeted to the trans-Golgi network (TGN) during the endocytosis. In the TGN, NaPi-2a interacts with PIST (PDZ-domain protein interacting specifically with TC10), a TGN-resident PDZ-domain-containing protein. The extension of the interaction is proportional to the expression of NaPi-2a in the TGN, and, consistent with that, it is increased with a high Pi diet. When overexpressed in opossum kidney (OK) cells, PIST retains NaPi-2a in the TGN and inhibits Na-dependent Pi transport. Overexpression of PIST also prevents the adaptation of OK cells to a low Pi culture medium. Our data supports the view that NaPi-2a is subjected to retrograde trafficking from the plasma membrane to the TGN using one of the machineries involved in endosomal transport and explains the reported expression of NaPi-2a in the TGN

    Improving the magnetic heating by disaggregating nanoparticles

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    Recently, potential applications of the magnetic heating for heterogeneous catalysis or organic synthesis have been reported. As these new applications are not limited by biocompatibility requirements, a wide range of possibilities for non-aqueous colloidal nanoparticles with enhanced magnetic properties is open. In this work, manganese and cobalt ferrite nanoparticles are synthesized by co-precipitation method with average particle size around 12 nm. The particles are either coated with tetramethylammonium hydroxide (TMAOH) and dispersed in water or with oleic acid (OA) and dispersed in hexane to produce aggregated or disaggregated nanoparticles, respectively. It is observed that the particle disaggregation improves significantly the heating efficiency from 12 to 96 W/g in the case of cobalt ferrite, and from 120 to 413 W/g for the manganese ferrite. The main responsible for this improvement is the reduction of hydrodynamic volume that allows a faster Brownian relaxation. This work also discusses the relevance of the size distribution

    Asymptotics of the trap-dominated Gunn effect in p-type Ge

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    We present an asymptotic analysis of the Gunn effect in a drift-diffusion model---including electric-field-dependent generation-recombination processes---for long samples of strongly compensated p-type Ge at low temperature and under dc voltage bias. During each Gunn oscillation, there are different stages corresponding to the generation, motion and annihilation of solitary waves. Each stage may be described by one evolution equation for only one degree of freedom (the current density), except for the generation of each new wave. The wave generation is a faster process that may be described by solving a semiinfinite canonical problem. As a result of our study we have found that (depending on the boundary condition) one or several solitary waves may be shed during each period of the oscillation. Examples of numerical simulations validating our analysis are included.Comment: Revtex, 25 pag., 5 fig., to appear Physica

    Strain dependence of the acoustic properties of amorphous metals below 1K: Evidence for the interaction between tunneling states

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    We have conducted a thorough study of the acoustic properties between 10^-4 and 1 Kelvin for the amorphous metal Zr_x Cu_1-x (x=0.3 and x=0.4), by measuring the relative change of sound velocity dv/v and internal friction Q^-1 as a function of temperature and also of the applied strain, in both superconducting and normal state. We have found that when plotted versus the ratio of strain energy to thermal energy, all measurements display the same behavior: a crossover from a linear regime of ``independent'' tunneling systems at very low strains and/or high enough temperatures to a nonlinear regime where dv/v and Q^-1 depend on applied strain and the tunneling systems cannot be considered as independent.Comment: 4 pages, 4 figures (submitted to PRL
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