(Benzophenone imine-κN)­chlorido(hydrido­tripyrazolyl­borato)­(triphenyl­phosphine)ruthenium(II) diethyl ether solvate

The reaction of RuCl(Tp)(Ph3P)2, where Tp is [(CH)3N2]3BH, with benzophenone imine leads to the formation of the title compound, [Ru(C9H10BN6)Cl(C13H11N)(C18H15P)]·C4H10O. The environment about the Ru atom corresponds to a slightly distorted octa­hedron and the bite angle of the Tp ligand produces an average N—Ru—N angle of 86.3 (9)°. The three Ru—N(Tp) bond lengths [2.117 (2), 2.079 (2) and 2.084 (2) Å] are slightly longer than the average distance (2.038 Å) in other ruthenium–Tp complexes

Establishment of the Controlled Low-Strength Desulfurization Slag Prediction Model for Compressive Strength and Surface Resistivity

In this study, the desulfurization slag used the volume method to replace fine natural aggregates in controllable low-strength materials (CLSM); the desulfurization slag content (DS) and curing time (t) were used as variables to test the compressive strength and surface resistivity of CLSM and simulated a prediction model on the results. The test results showed during that the compressive strength on the 28th day, the average desulfurization slag replacement amount increased by 10%, and the compressive strength decreased by 0.9 MPa. The surface resistivity increases with age, and each ratio increases from seven days to 28 days, and the surface resistivity value increases from 9.3% to 20.6%. After that, a hyperbolic function and exponential function with multiple variables were used to establish a simulation model of the effects of the DS content and curing time on the compressive strength and surface resistivity of CLSM. Compared with the test results, the statistical analysis shows that the average absolute percentage error (MAPE) of the compressive strength is 9.17%, and the surface resistivity is 10.67%. From the results, the predictive analysis model developed in this paper provides good predictive results in terms of compressive strength and surface resistivity

Polyethylene (PE) Waste Minimization Study of Cement Mortar with Adding PE Content under Different W/B Ratios

Wastes can be effectively used in concrete and the characteristics of concrete can be maintained or enhanced, the economy of waste management can be greatly increased, and the pollution of the earth can be reduced. This study aimed to research the durability of cement mortar prepared using different W/B ratios and different percentages of waste PE content. The cement mortar was mixed with 0%, 1%, 2%, 3%, and 4% waste PE and 20% ground-granulated blast-furnace slag (GGBFS) in W/B ratios of 0.4, 0.5, and 0.6. The results sw that the slump and flow decrease as the waste PE content is increased and increase with increasing W/B ratio, and the setting time is shortened as the waste PE content is increased. In terms of hardened properties, the specimen strength is slightly decreased as the waste PE content is increased, but the hardened properties are better at a later age due to the pozzolanic reaction of slag, which can be verified by microscopic SEM

Influence of Fluorine-Containing Monomer Content on the Hydrophobic and Transparent Properties of Nanohybrid Silica Polyacrylate Coating Materials

Nanosilica-modified, fluorine-containing polyacrylate hybrid coating materials, consisting of dodecafluoroheptyl methacrylate (DFMA), methyl methacrylate (MMA), 2-ethyl hexyl acrylate (2-EHA), 3-(trimethoxysilyl) propyl methacrylate (KH-570), and tetraethylorthosilicate (TEOS), are synthesized successfully by free radical polymerization and the sol–gel process. It is revealed that the content of the fluorine-containing polyacrylate hybrid coating materials from DFMA monomers significantly improves the properties of the films. The polyacrylate coating film prepared with a weight ratio of DFMA/MMA at 1:5 exhibits the largest water contact angle of 105.4°, which demonstrates that DFMA can effectively improve the hydrophobicity of the coating film. Moreover, the silicon coupling agent (KH-570) is used to graft silica with acrylate. Spherical in shape, the surface morphology of the nanohybrid film exhibits a core–shell structure, which increases the surface roughness and enhances the hydrophobic properties. The as-prepared fluorine-containing nanohybrid silica polyacrylate film possesses a high transmittance of 89–97% in the visible light region, indicating its potential as a very attractive solution in many practical areas

Polyethylene (PE) Waste Minimization Study of Cement Mortar with Adding PE Content under Different W/B Ratios

Wastes can be effectively used in concrete and the characteristics of concrete can be maintained or enhanced, the economy of waste management can be greatly increased, and the pollution of the earth can be reduced. This study aimed to research the durability of cement mortar prepared using different W/B ratios and different percentages of waste PE content. The cement mortar was mixed with 0%, 1%, 2%, 3%, and 4% waste PE and 20% ground-granulated blast-furnace slag (GGBFS) in W/B ratios of 0.4, 0.5, and 0.6. The results sw that the slump and flow decrease as the waste PE content is increased and increase with increasing W/B ratio, and the setting time is shortened as the waste PE content is increased. In terms of hardened properties, the specimen strength is slightly decreased as the waste PE content is increased, but the hardened properties are better at a later age due to the pozzolanic reaction of slag, which can be verified by microscopic SEM