Gas chromatograph injection system

An injection system for a gas chromatograph is described which uses a small injector chamber (available in various configurations). The sample is placed in the chamber while the chamber is not under pressure and is not heated, and there is no chance of leakage caused by either pressure or heat. It is injected into the apparatus by changing the position of a valve and heating the chamber, and is volatilized and swept by a carrier gas into the analysis apparatus

Long-range-corrected hybrids including RPA correlation

We recently demonstrated a connection between the random phase approximation (RPA) and coupled cluster theory [J. Chem. Phys. 129, 231101 (2008)]. Based on this result, we here propose and test a simple scheme for introducing long-range RPA correlation into density functional theory. Our method provides good thermochemical results and models van derWaals interactions accurately.Comment: Accepted version of the manuscrip

Charge exchange contribution to the decay of the ring current, measured by energetic neutral atoms (ENAs)

In this paper we calculate the contribution of charge exchange to the decay of the ring current. Past works have suggested that charge exchange of ring current protons is primarily responsible for the decay of the ring current during the late recovery phase, but there is still much debate about the fast decay of the early recovery phase. We use energetic neutral atom (ENA) measurements from Polar to calculate the total ENA energy escape. To get the total ENA escape we apply a forward modeling technique, and to estimate the total ring current energy escape we use the Dessler-Parker-Sckopke relationship. We find that during the late recovery phase of the March 10, 1998 storm ENAs with energies greater than 17.5 keV can account for 75% of the estimated energy loss from the ring current. During the fast recovery the measured ENAs can only account for a small portion of the total energy loss. We also find that the lifetime of the trapped ions is significantly shorter during the fast recovery phase than during the late recovery phase, suggesting that different processes are operating during the two phases

Heat sink capability of jet A fuel - Heat transfer and coking studies

Heat sink capabilities of Jet-A fuel - heat transfer and coking studie

Global energetic neutral atom (ENA) measurements and their association with the Dst index

We present a new global magnetospheric index that measures the intensity of the Earth\u27s ring current through energetic neutral atoms (ENAs). We have named it the Global Energetic Neutral Index (GENI), and it is derived from ENA measurements obtained by the Imaging Proton Spectrometer (IPS), part of the Comprehensive Energetic Particle and Pitch Angle Distribution (CEPPAD) experiment on the POLAR satellite. GENI provides a simple orbit-independent global sum of ENAs measured with IPS. Actual ENA measurements for the same magnetospheric state look different when seen from different points in the POLAR orbit. In addition, the instrument is sensitive to weak ion populations in the polar cap, as well as cosmic rays. We have devised a method for removing the effects of cosmic rays and weak ion fluxes, in order to produce an image of “pure” ENA counts. We then devised a method of normalizing the ENA measurements to remove the orbital bias effect. The normalized data were then used to produce the GENI. We show, both experimentally and theoretically the approximate proportionality between the GENI and the Dst index. In addition we discuss possible implications of this relation. Owing to the high sensitivity of IPS to ENAs, we can use these data to explore the ENA/Dst relationship not only during all phases of moderate geomagnetic storms, but also during quiescent ring current periods

Fabrication of Nano-Gapped Single-Electron Transistors for Transport Studies of Individual Single-Molecule Magnets

Three terminal single-electron transistor devices utilizing Al/Al2O3 gate electrodes were developed for the study of electron transport through individual single-molecule magnets. The devices were patterned via multiple layers of optical and electron beam lithography. Electromigration induced breaking of the nanowires reliably produces 1-3 nm gaps between which the SMM can be situated. Conductance through a single Mn12(3-thiophenecarboxylate) displays the coulomb blockade effect with several excitations within +/- 40 meV.Comment: 10 pages, 5 figure

A general low frequency acoustic radiation capability for NASTRAN

A new capability called NASHUA is described for calculating the radiated acoustic sound pressure field exterior to a harmonically-excited arbitrary submerged 3-D elastic structure. The surface fluid pressures and velocities are first calculated by coupling a NASTRAN finite element model of the structure with a discretized form of the Helmholtz surface integral equation for the exterior fluid. After the fluid impedance is calculated, most of the required matrix operations are performed using the general matrix manipulation package (DMAP) available in NASTRAN. Far field radiated pressures are then calculated from the surface solution using the Helmholtz exterior integral equation. Other output quantities include the maximum sound pressure levels in each of the three coordinate planes, the rms and average surface pressures and normal velocities, the total radiated power and the radiation efficiency. The overall approach is illustrated and validated using known analytic solutions for submerged spherical shells subjected to both uniform and nonuniform applied loads

Earth orbital teleoperator systems evaluation

The mechanical extension of the human operator to remote and specialized environments poses a series of complex operational questions. A technical and scientific team was organized to investigate these questions through conducting specific laboratory and analytical studies. The intent of the studies was to determine the human operator requirements for remotely manned systems and to determine the particular effects that various system parameters have on human operator performance. In so doing, certain design criteria based on empirically derived data concerning the ultimate control system, the human operator, were added to the Teleoperator Development Program